2022年青海省玉树州高考化学三模试卷（ 附答案详解）

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10ூJ᪆௃J*A.᪷H@¬⏚ា¯°ᐰ^ᡂNaHC2()4q´µḄpH<4.2,´µᕈ⏚ឋ¬⏚ា¯°ᐰ^ᡂNa2c2O4q´µḄpH>7,´µᕈឋᵬ¸¹Ḅ⁐¼3,1½4.4,¾¿Ḅ⁐¼8½10,ᡠÁ^Â⌱Ãᵬ¸¹G¾¿pᢣÅᑺᦑA┯B.Çজ´µ!⏚ា¯°ᐰ^ᡂNaHCzCU´µḄpH<7,´µᕈ⏚ឋÉÊHCzO£ᵯrhᜧ#ËJhC(C2஺r)>C(H2c2O4)Ì₝⏚᪷r2ËJhGᵯrhÎÏÐᡠÁÑᙠc(HC2O£)>c(C2O2-)>c(H2c2஺4)ᦑB'(C.Çঞ´µpH=7,´µᕈ!ឋᑣc(H+)=c(OH-),´µ!Ñᙠᵯ₹Ôឤc(Na+)+c(H+)=c(OH-)+C(HCO)+2C(CO1-),ᡠÁÑᙠc(Na+)=c(HC0j)+2c©஺×),222ᦑC┯*DC2஺/ÚÛËᵯrfC(CzOt)ᜧËᵯrhᜧÜÇজᑮÇট!C(C2஺*-)⌲à7ᜧᑣËᵯrh⌲à7ᜧᦑD┯ᦑ⌱:BoA.᪷H@¬⏚ា¯°ᐰ^ᡂNaHC2()4q´µḄpH<4.2,´µᕈ⏚ឋ¬⏚ា¯°ᐰ^ᡂNa2c2O4q´µḄpH>7,´µᕈឋᵬ¸¹Ḅ⁐¼3.1~4.4,¾âḄ⁐¼8½10;B.Çজ´µ!⏚ា¯°ᐰ^ᡂNaHCzO”´µḄpH<7,´µᕈ⏚ឋÉÊHC2O7ᵯrhᜧ#ËJhC.Çঞ´µpH=7,´µᕈ!ឋᑣc(H+)=c(OH-),´µ!Ñᙠᵯ₹Ôឤc(Na+)+c(H+)=c(OH-)+C(HCOJ)+2C(CO1-)22D.C2஺/ÚÛËᵯr0c(C2஺*-)ᜧËᵯrhᜧ஺L⚪ὃO⏚ãᔠ´µឋᑨWZ[ὃO¤ᑖ᪆ᑨWä@eåᔠæᵨ`aÊ(ᔜÇ´µ!´BᡂᑖäᐸឋBஹËᵯréêë=JL⚪ᐵY⚪fghiᜧ஺8.ூKᫀ௃CU(OH)ìᧅஹîᴻðஹñòᳫôõö÷ᙠC!~ᐭøËùúûü÷2ýᵨ⏀ÿ
ᴻCᨵ⍎⏀ᓾCᑁᡂᑣ"#$%Ḅ'ឋ)*Aᴻ+,⁐./⌲1234⁐,B6C11SO472⁐C89:ᮞ2<=Ca(OH)2?@ABCNaOH?@AᜧEFᐙᑖᔾᦈCO23CU(OH)-2CUCO[H£CU(OH)(CO)]235632ூ@᪆௃@N(1)P⏚R?STUឋV᪷XcᎷZ[\ᎷZa]3+,⁐^_[F3CU(0H)2ᦑaᫀ3NCU(OH)2c

11(2)fg=Shi+,⁐./◤⌕lmnoᡠ◤ᴻqᘤᨵsᧅஹvwஹᴻxᦑaᫀ3Nsᧅஹᴻxஹvwc(3)জ᪷Xqᘤ{|ᱯ~[\ᐸ3ᳫᦑaᫀ3Nᳫcঝᵨᑮ⏀ᡠ[$%ᑁ/ᩭ'ឋᐹ/3NᙠCᐭᵨ⏀
ᴻCᨵ⍎⏀ᓾCᑁᡂᑣ"#$%Ḅ'ឋ)*ᦑaᫀ3NᙠCᐭᵨ⏀
ᴻCᨵ⍎⏀ᓾCᑁᡂᑣ"#$%Ḅ'ឋ)*cঞ+,⁐^_3CuC()3,ᑣᑖ@./ᡂᓄ¢£¤ᨵCO2ᡂ¦ᨵ§ᡂᡠ¨©3NAᴻ+,⁐./⌲1234⁐B6CUSO472⁐C89:ᮞ2<=ᦑaᫀ3NAᴻ+,⁐./⌲1234⁐B6CuS0472⁐C89:ᮞ2<=cটCa(0H)2?@ABCNaOH?@AᜧEFᐙᑖᔾᦈCO?µ¶ᡂḄCO2ᐰ¸¹ᔾᦈ{|Eºµ$%BḄ»2.7g,ᓽᡂ2.7gHzO,ᡠ./Áᨵn[Cu(OH)]=n(HO)=Æ^=0.15mol,C?S»Í4.4g,ᑣ./Áᨵ22n(CuCO)=n(CO)=:=O.lmol,n[Cu(OH)]Nn(CuCO)=0.15molNO.lmol=3N32232,ᡠᓄÎÏ33CU(OH)2-2CuCO[sgCu(OH)(CO)],35632ᦑaᫀ3:Ca(OH)2?@AB,CNaOH?@Aᜧ,EFᐙᑖᔾᦈCO2c3Cu(OH)2-2CuCO[3ᡈCU5(OH)6(CC>3)2]஺$%Aᑖ@+,⁐./$%B6CUSO4[×ᔲᨵᡂµÙ+,⁐./×ᔲÁᨵCU(OH)2,ᣚᡂ6Ûᓄ┛[ݧᐰ¸ᔾᦈ᪷X$%Ḅ2ᓄµÙ./ÁᨵḄCu(OH)2Ḅ89:ᮞ[×ᔲᨵCO2ᡂµÙ×ᔲÁᨵC11CO3,ᣚᡂNaOH?S[Ýᐰ¸CO?ᔾᦈÞn$%Ḅ2ᓄµÙ./ÁᨵḄC11CO3ḄU:ᮞ[■àáḄCO2lᐭ$%C,âã{|஺ä⚪ὃçèéᱥḄëᡂìÁḄíÙ#µᱥḄឋèéḄîẠð~×ᓄÎÏḄµÙðAñᜧ஺ò12⚓ᐳ19⚓

129.ூaᫀ௃H-0-Clö⚠vøNaHCOb/úḄC^ஹC%஺¹ᐙᑖᔾᦈ■à3᡾ýᐵÿᡭKiஹK,ᔣᐭ2FeS2+15HC10+H20=22Fe3++15Cr+4S0i-+17H+2HC10+HCHO=2HC14-H0+C0T2N22Aூ%᪆௃%((l)HQOHஹQ-.ᔜ0ᡂ12ᐳ45ஹ஺-.0ᡂ22ᐳ457ᑣHQOḄ:᪀<=H—0-CL@ᘤaḄCD=E⚠GH7ᦑJᫀ=(H—0—C1LE⚠GHLফজ@ᘤCᑴᜓঞ஺R7᪷TᐗVWឤஹ-.WឤY7Z[ᜐ=NaHC()3L@ᘤBḄ^ᵨ`◀bHQ,ᵨ⛳dḄefgL@ᘤDḄ^ᵨ`◀bCl2,i᧕klᨵnkᑺpiᓄr7ᡠtBஹDuvᑖx`⛳defgஹCC1,4ᦑJᫀ=(NaHCObL3LঝCl2ஹCkO|ᐹᨵ~ᓄឋ7᡾HC10dFeS2Ḅ7ᡠt:ᐭRᵯḄḄ`ḄChஹᐙᑖᔾᦈ7■᡾7ᦑJᫀ=(ḄCl?ஹᐙᑖᔾᦈ7■᡾L(3)জEHC10kᑮFḄᐹ¢^=ᐵ¤¥ᡭKiஹK,ᔣᐭ72ᦑJᫀ=(ᐵ¤LᡭKiஹ¦7ᔣᐭLঝHQ0ᐹᨵ~ᓄឋ7:R7FḄk§ᨵḄ¨.©⌕ᨵFe3+ஹC«ஹS0tஹH+7®HC10dFes2°ᡂFe3+ஹC«ஹS0tஹH+,±Ḅ¨.²³<=2FeSz+15HC10+H0=2Fe3++15C1-+4S0g+17H+,2ᦑJᫀ=(2FeSz+15HC10+H0=2Fe3++15Cr+4sOf+17H+L2(4)জHC10·ᵨl◀bHCHO,°ᡂ¸¹º~⏚d¼¸¹º½¾¿Ḅᓄᱥ7ᓄÁ²³<=2HC10+HCHO=2HC1+H0+C0T,22ᦑJᫀ=(2HC1O+HCHO=2HC1+H2O+CC)2TLঝ᪷TÂò³<7◀bImolHCHOḄÇÈ=30g,Ḅᵯ.ᦪ=4NAᑣ15gHCH0Ḅᵯ.ᦪ=2Ê7ᦑJᫀ=(2NA஺ËZ᣸Í7AÎf⏚d⏚ឋÏ═⏚Ñk°ᡂCl?7²³<=2KMnC>4+16HC1(Î)=2KC1+2MnCl+5CIT+8HO,Îf⏚ᐹᨵᢵØឋ,ÙᑮḄ222Cl2§ᨵHQ,HC1ÚdNa2cO37ᡠtBᵨl◀bHCLC@ᘤCᑴᜓC^OR7Ø°ḄᓄÁ²³<=2cI2+2Na2cO3+H0=Cl0+2NaCl+2NaHCOLCl02232=ÝÞ⁐7᩽᧕klgáâã°ᡂHC10,iÚdg°ᡂHC1ஹHC10,Cl2᧕klᨵnkᑺ7ᡠtDᵨl◀bäåḄCl?;Edg°ᡂHC10,HC10ᐹᨵ~ᓄឋ7:R7FḄk§ᨵḄ¨.©⌕ᨵFe3+ஹQ-ஹSOtஹH+7®HC10

13dFes?°ᡂFe3+ஹC«ஹSOtஹH+»è⚪ὃëᱥÇᑴᜓìឋDzᫀíî7ïðὃë▅òஹᑖ᪆ஹᑨôì¢^Úõ7®ö-ᳮஹᐗVᓄᔠᱥḄឋÇìᐸឋÇúûឋஹ¢^üឋ`%è⚪ᐵ57Y⍝ᔜ2Ḅ^ì·ÚØ°Ḅ஺10.ூ
ᫀ௃-49Pt/AlOᓣ᳛ᜧᓫᑁὑCO2#CO2$23ᓄ᳛ᓣa>10*7P>P>Pi22.8MPa-2B32ூ1᪆௃1*(1)᪷6789:1+<=>3%@)+(*02©;(*@014@)+@0C)ᦑEH=EH+AH—(+41kJ-mol-1)+(-90kJ-mol-1)——49kJ-mol-1,2ᦑ
ᫀO*-49kJmor1Q(2)জᵫTUᨬ〉ᔠḄZPt/AkOsPt/AkO3\]ᓄᑺ]ᓄCO2$ᓄ᳛ᦑ
ᫀO*Pt/AlO23Qঝᓣ᳛ᜧᓫᑁὑCO2#CO2$ᓄ᳛ᓣᦑ
ᫀO*ᓣ᳛ᜧᓫᑁὑCO2#CO2$ᓄ᳛ᓣQ(3)©n(H)*n(C02)aᜧ,CO2$ᓄ᳛aᜧᦑ⊤c4ᵯ)*n(C0)=3*1Ḅeᓄfg22Ofga,ᦑ
ᫀO*aQঝPhiᔣklmnoi>o⌮Qqhrᵯ)*n(CO)=3*1,ns=8mol,ᑣ2n(H)=6mol,n(CO)=2mol,vwxO*223H(g)+CO(g)UCH30H(g)+HO(g)222q{/mol6200$ᓄ/mol3.61.21.21.2|⊝/mol2.40.81.21.2~n's=(2.4+0.8+1.2+1.2)mol=5.6mol,ឤឤᩩᵫpv=nRT,=UᱥḄP{*Pp=ns*n's=8*5.6=10*7,ᦑ
ᫀO*>;10*7Q(4)জᜧ|⊝iᔣCO2$ᓄ᳛ᜧᦑP3>P2>P1ᦑ
ᫀO*P>P>P321Qঝ255஺(2CO2$ᓄ᳛O60%,vwxO*CO(g)+3H2(g)=CH30H(g)+HO(g)22q{/mol240014⚓ᐳ19⚓

14$ᓄ/mol1.23.61.21.2|⊝/mol0.80.41.21.211s=(0.8+0.4+1.2+1.2)mol=3.6mol,K=+:=''FPP(CO)P3(H)P3X(ᘤPSK22364.5P3-2,P3=4MPa,ᑣKp222.8MPa""2,ᦑ
ᫀO*22.8MPa-2Q1.2mol1.2molঞ¢£OVL,K==஺¤¥¦28.12V2,§¨ᐭCO?ª«0C)ᙳ1.2mol(1.2+l)mo௃lmol,Qc=®ᘤ*¯=᧡:1g22.92>K,ᦑ|⊝ᔣ⌮±ᔣᦑ
ᫀO*B஺(1)᪷6789:ᓽ=\
Q(2)জᵫTUᨬ〉ᔠḄZPt/AkOsPt/AkO3\]ᓄᑺ]ᓄCO2$ᓄ᳛Qঝᓣ᳛ᜧᓫᑁὑCO2#CO2$ᓄ᳛ᓣQ(3)জrC)*n(C02)aᜧCO2$ᓄ᳛aᜧQঝPhiᔣklmnviுv⌮Qqh11(C)*n(CO)=3*1,ns=8mol,ᑣ2n(H)=6moLn(CO)=2mol,vwxO:223H(g)+CO(g)UCH30H(g)+HO(g)222q{/mol6200$ᓄ/mol3.61.21.21.2|⊝/mol2.40.81.21.2~n's=(2.4+0.8+1.2+1.2)mol=5.6mol,ឤឤᩩᵫPV=nRT,=UᱥḄQ(4)জᜧ|⊝iᔣCO2$ᓄ᳛ᜧQঝ255TCO2$ᓄ᳛O60%,vwxO*CO(g)+3H2(g)=CH30H(g)+HO(g)22q{/mol2400$ᓄ/mol1.23.61.21.2|⊝/mol0.80.41.21.211s=(0.8+0.4+1.2+1.2)mol=3.6mol,´ᐭKp=ᑏ¶·ᓽ=kl¸¹;ঞQc>K,|⊝ᔣ⌮±ᔣ஺º⚪¼⌕ὃ¿ᓄÀ|⊝Ḅ¸¹ᒹÂ789:ஹᓄÀ|⊝ÄᦪḄ¸¹ஹᓄÀ|⊝Ḅ

15UÆ⚪ÇÈÉÊ஺•H].11.ூ
ᫀ௃3d8PH'C|☢vÍÎ2270ஹCஹHÏᕜÑÒÓÔᦪᜧHÕᵯÖ×ᜧ6ØÙூ1᪆௃1*(l)Ni᪶᜜ᵯÓ᣸ÞxO[Ar]3d84s2,á᝱NiÒÓḄãäᵯÓOᐸ3dஹ4s×æçḄᵯÓá᝱Ni?+ḄãäᵯÓ᣸ÞxO3d8,péᒹêWAìí0ìḄᐗïA1OHIAìᐗïpéᦑ
ᫀO*3d8QpQHl*(2)জCHj"ÖÓOCH3ᜫôÉõᵯÓᑣᵯÓxOH'C:CH]ãäᵯÓöᦪO3,HÕOSp2ᩖᓄù᪀ûZ|☢vÍÎH]♦ᦑ
ᫀO*H-C;|☢vÍÎQLHÕঝNᑖÓýþÒÓÎᡂCH3ஹ-CH->H0-CHC=C,ᩖᓄᑖsp3ஹsp3.22sp2,ᩖᓄᨵ2ᓫᡂ஺ᡂ!஺"!nᑣ%!ᑖ&'(ᨵ27஺ᦑ+ᫀ-2.27-ঞNᡠ(ᐗ3Cஹ0ஹH,456ឋ0>C>H,ᵯ9ឋᵫᜧᑮ=Ḅ?@0ஹCஹH,0ḄAᵯBCᜧDCḄEFGHᕜJE&@ᦪLᜧᵯBCLᜧᦑ+ᫀ-0ஹCஹH.HᕜJE&@ᦪLᜧᵯBCLᜧ.(3)জPᔠRSTUAWxᙶ᪗ayᙶ᪗1,zᙶ᪗-ஹᑣaWḄᙶ᪗ᦑ+ᫀ-ঝ0E&`BᨬbḄNiE&6!eIJ0ᙠᨔj'ḄklᦪG6,ᦑ+ᫀ-6.ঞmᨔj(ᨵ0E&1+12x-=4.(ᨵNiE&8x:+6X.4,ᓄsNiO,mᨔjuv4xwg,yza3xl0-2%m3,~p=2=*g='75“AkVa3xl0-21cm3a3NxlO-216Acm-3,4X75ᦑ+ᫀ:a3NxiO-21°A(l)Ni᪶᜜ᵯ&᣸[Ar]3d84s2,᝱NiE&Ḅᵯ&ᐸ3dஹ4sCḄᵯ&,A16⚓ᐳ19⚓

16ᐸᵯ&᣸3d84s2.Pᒹ(AHIA0Ḅᐗ3.(2)জ᪷CHB&Ḅᵯ&ᦪᑨᩖᓄ⍝¡¢"£¤᪀¢-ঝNᑖ&'¦E&ᡂ-CH2-ஹHO-CH->-CH,C=C,ᓫᡂ§23ᡂ!஺"!TT.ঞHᕜJ©ª«¬AᵯBCᕈLᜧ®¯.(3)জPᔠRSTUAWxᙶ᪗°ஹyᙶ᪗1,zᙶ᪗±ঝ0E&`BᨬbḄNiE&6!.ঞmᨔj(ᨵ0E&1+12x°=4.(ᨵNiE&8x-+6xq=4,ᓄsNiO,mᨔjuv4x³g,yza3x10-2/3,µᐭp=?஺¸⚪ὃ»ᱥuP᪀"ឋu½¾ᵯ&᪀¢¿ÀÁឋuஹklஹᨔjP᪀¿ÂÃÄÅÆᳮÈᵯ&᪀¢ÀÁឋuÉÊÅÆᙳÌÍᙠᨔj'ḄᮣÏÐᵨ஺ᩩNH■+CHJCOOH>N-Q—OOCHᡈHCOOᔩᡈÔÕ⏚TCHCH=CHCHO3ூÈ᪆௃È-(1)Fᑖ&'ÛCÜḄÝÞ¦ßஹà.BtCḄãä¡¢åEãä,ᦑ+ᫀ-¦æஹà.åEãä;

17(4)C-DãäḄᓄsè:00\êëᩩíîAA+.AO-ï-------->NHCOCH,+CH3COOH0óíî^yOCH,COOH:NHC+CH3ᦑ+ᫀ:BḄHᑖð᪀yñᔠîᑡᩩí:জᑖ&'(ᨵôõ"ö.ঝC÷øùúãäûü(ᨵHCOO-.ঞ᪶ýᐳþÿᨵ4☢6221,ᔠᩩḄᑖ᪀ᨵᦔḄᵬ᪀ᔠᩩḄ᪀!"N-O-஺஺"

18OH,ᯠAῃC6ᡂCH3cH=CHCHO,ᔠᡂDEH3C-CH-CH2-CHOO/CuFNaOHGH0HIJ⏚2CH3cH20H->CHCHO-'->CH3cH=CHCHO'3—--UHUO/CuFNaOHGHOHIJ⏚2ᦑ&ᫀ:CH3cH20HTCH,CHOt~-CH,CH=32A3H3C-CH-CH2—CHOA3CHCHOoAMIN⏚O6PQRS6ᡂB,BNO6T-RS6ᡂCUᑣBAO~N02,CUO6PQRS6ᡂD⏒XDYZ[Ḅ\-]^_-]PQ6ᡂE,E⏒XO6`aRS6ᡂFUGMMgRS6ᡂH,HM123O6RS6ᡂb☘3d(6)*+⏣-ᧇᑴᜓ123+⏣4ᓄ6ᡂ+3+3ᙠ9ឋᩩ;6ᡂ0HI,ᯠAῃC6ᡂCH3cH=CHCHO஺H3C-CH-CH2-CHOe⚪ὃhᨵiᱥḄklMᔠᡂmnὃhஹᑖ᪆ஹklqrstᔠuᵨwxyzklᔜᱥ|Ḅ᪀!"}~e⚪ᐵᵨrsஹ⌮ᔣᔠᡂDE,⚪.