2022年宁夏中卫市高考化学三模试卷（附答案详解）

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2022
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10a⚪ὃdᓄsᵯ¿ÀÁᵯ§!fᳮjkὃdᑖ᪆ÂÃx²ÄÅᔠÆᵨÂÃÇ&ᵯ᩽ᑨ/<Éஹᵯ᩽wḄx:;ÊË<ᔣÍ~a⚪ᐵ.Î%&Ïᑏᵯ᩽=,⚪ᜧ஺7.ூᫀ௃Bூ~᪆௃~?A.ᵫ°±²ÑÒÓpHÕ>4Ö5©×LᓄØ8⏚ÙÒÓាÛᡂÜØ⏚ÝÙᡠÑÒÓpHÕ>4Ö5©ÞYßᐭ×LᓄØᦑA┯5'B.ᵫ°±²ÑÒÓc(HS03)=c(S0á)©ÒÓpH>7.2,ᵫᵯ:ãᦪå=±²K(HSO)=æ(è)=c(H+)=IO-%,ᦑB%&'a223C.ᵫ°±²aiéÒÓ>ÜØ⏚ÝÙஹÜØ⏚⏚ḄêᔠÒÓÒÓḄᵯ₹ìឤᐵî>c(H+)+c(Na+)=c(OH-)+c(HSO஺+2c(S0á)+c(HCO])+2c(COg),ᦑC┯5'D.ᵫ°±²,pH=3ḄÒÓ>ÜØ⏚ÝÙஹÜØ⏚⏚ḄêᔠÒÓᵫᱥᧇìឤ±²,ÒÓc(Na+)4Ö5©×LᓄØ8⏚ÙÒÓាÛᡂÜØ⏚ÝÙ'B.ᵫ°±²ÑÒÓc(HSO1)=c(SOg)©ÒÓpH>7.2,ᵫᵯ:ãᦪå=±²,C(H+)C(SOr)Ka=H2s஺3)=c(H+)'c(HSOj)C.ᵫ°±²aiéÒÓ>ÜØ⏚ÝÙஹÜØ⏚⏚ḄêᔠÒÓÒÓḄᵯ₹ìឤᐵî>c(H+)+c(Na+)=c(OH-)+c(HSO.)+2c(SOñ)+c(HCO.)+2c(COò);D.ᵫ°±²pH=3ḄÒÓ>ÜØ⏚ÝÙஹÜØ⏚⏚ḄêᔠÒÓ஺a⚪ὃdôᵯ~nÒÓ:;õᜧö÷ø⌕Í°ú}ᓄᑖ᪆:;¥ᙠḄᑨ/ûvᵯ₹ìឤᱥᧇìឤÍ~⚪ᐵ.jkὃdsḄᑖ᪆ÂÃxᮣ¦ÆᵨýẠ²ÄḄÂÃ⚪ÿ஺8.ூᫀ௃B-┞᳛Li0-A1O-4SiO2FeO+4H2so/)=2232Fe(S0)+S0T+4H0◀IḄH2sḄFe3+ஹAS+24322!"4x10-5ூ#᪆௃#%(1)0-┞ᙠᜐᳮ+,-./0ᜧᱥḄ34☢67┞᳛8ᵫ:;<ᦪ>?@.A7LiAlSi2()6ᵨCᓄᱥEF⊤HḄᓄIFJK20-52஺3

114SiO,2ᦑᫀJ%஺-┞᳛8LiOAlO-4SiO82232(2)1CᓄXYZ[⏚]^Cᓄ_:^ᡂ[⏚YஹaCᓄ["7ḄᓄIbcFJ2FeO+4H2s஺4()=Fe(SO)+S0T+4H0,24322ᦑᫀJ:2FeO+4H2soF)=Fe(S0)+S0T+4H0824322(3)ᵫᑖ᪆.A7nᐭp⏚┛r⁚pHJ5]^IIḄwḄx◀[⏚7yḄYz;ஹ{z;|ᓄJ}CᓄYஹ}Cᓄ{~7ᦑᫀJ%◀IḄH2sO,ḄFe3+ஹAl3+8(4)ᵫ⚪.A7ᑮp⏚┞ḄJ]7ᓾᨔஹஹஹ7ᵫp⏚┞ᙠ?Ḅ#.A7ᓣ7p⏚┞Ḅ#7ᡠ/Jp⏚┞#⌼ᡂὑ7⌕ᵨ!"p⏚┞~Ḅ¡᳛7ᦑᫀJ%88!"8(5)¢£ᓄ┛Zp⏚¤¥JVL,ᵫ⚪.A7§¨6£ᓄ┛Zp⏚¤©ᔠ«7p⏚¤ḄJ=I,xlOfoi/L,ᵫp⏚┛Ḅ6.A7┛z;J¯Mmol/L=2xl0-5m°i/L,ᑣ:£ᓄ┛ḄJ2Vmol/L=4X10-5mol/L,ᦑᫀJ%4x10-5஺ᵫ⚪µ¶c.A7ᔣB-┞nᐭ[⏚]^I#0-┞7nᐭp⏚┛r⁚pHJ5]^n◀[⏚7yḄYz;ஹ{z;|ᓄJ}CᓄYஹ}Cᓄ{~7n"º»«ᑮ¼ᨵaCᓄấஹ}CᓄYஹ}Cᓄ{Ḅ¿.ឋ[⏚Á8ᔣ[⏚Ánᐭ}Cᓄ┛y╅z;|ᓄJ}Cᓄ╅~7nᐭp⏚¤yḄ┛z;|ᓄJp⏚┛~7ᑮ¼ᨵ}Cᓄ╅ஹp⏚┛Ḅ~A[⏚┞8[⏚┞Ã]«7nᐭ⛳p⏚¤]^IV,ᑮp⏚┞8ᔣp⏚┞nᐭÁ⏚#ᑮ£ᓄ┞7ᙠHC1Æ᛻n!ᑮ£ᓄ┞7ᵯ#ᰚÊ£ᓄ┞ᑮËÌ┞஺Í⚪ὃÏÐÑÒÓ/0-┞ᑴÕËÌ┞ḄbÖ7⚪wק7Ø⚪ÙÚÐᓄIFḄÛᑏஹᱥÝḄᑖzZ§AÞ7ᔠᳮᑖ᪆⚪Ñ߶cx#⚪ᐵá஺9.ூᫀ௃"[⏚ឤäåæᧅèé¶êëìí⏚᪆BCE88.15CuCl+22NaOH=CU(OH)I+2NaClCH30H+80H--6e-=COg+6HO22ö12⚓7ᐳ19⚓

12ூ#᪆௃#%(1)[⏚º»ùúᜧḄ!7ᡠ/ᵨ[⏚ûᑴ70%[⏚ù7yüᜧḄ[⏚ýᐭüḄ"7■ÿᔠᑣᐭ⏚Ḅᐜᐜஹᐭ⏚ᦑᫀ!"#⏚#(2)ᵫ%&'()*+,ᘤb!ឤ/0ᧅ#,ᘤc!ᳫ34567ᵨ9ᓄḄ;<45=>#ᵫ⚪@AB*+CDEF*GHIJK⏚ḄLMFᡠGᑖPJK⏚QRᐭ4ḄSḄTUJK⏚᪆ᦑᫀ!"ឤ/0ᧅ#45=>#TUJK⏚᪆#(3)ᵫ⚪W*+ᑖPJK⏚QRḄXY!Z[Z[◤⌕Ḅ,ᘤ!0ᧅஹ^_ஹ`ᴻbᦑᫀ!"BCE#(4)ᵫXcd*+40gJKᨒᑴgḄJK⏚ḄᱥiḄj!kl-0.342mol,ᑣᨬp41ggᑮ41gJK⏚ᨔsJK⏚Ḅt᳛!t6gvGx100%x8815%,0.342mol'ᦑᫀ!"88.15#(5)wᔠxᓄyLUz{ᓄ|Lz{ᓄ|L;<}ᡂz{ᓄyxᓄ|,;<ḄᓄXcd!CuC%+2NaOH=Cu(OH)1+2NaCl,2ᦑᫀ!"CuCl+2NaOH=Cu(OH)I+2NaCl#22(6)ᵫ)*+ᵯ᩽!ᧇᵯḄ᩽ឋᩩᵬ⏣ᙠ᩽ᜫᵯ}{ᓄ;<}ᡂ⏚᪷Pᵯ᩽;#(3)ᵫ⚪W*+ᑖPJK⏚QRḄXY!Z[#(4)ᵫXcd*+40gJKᨒᑴgḄJK⏚ḄᱥiḄj!¬ᡡ=0.342mol,ᑣᨬp41ggᑮ41gJK⏚ᨔsJK⏚Ḅt᳛!¯☢LX100%#0.342mol(5)wᔠxᓄyLUz{ᓄ|Lz{ᓄ|L;<}ᡂz{ᓄyxᓄ|;

13(6)ᵫ)*+ᵯ᩽!ᧇᵯḄ᩽ឋᩩᵬ⏣ᙠ᩽ᜫᵯ}{ᓄ;<}ᡂ⏚᪷P஺¶⚪ὃ¸ᱥiḄᑴᜓ%&!º⚣ὃ¼½¾ᑴᜓ¿ᳮஹ%&'(Ḅ7ᵨஹ%&ᢈÂ!MḄᐵÄÅᑖ᪆%&ÂÆḄὃ¸©WᐗÈᓄᔠᱥ+É%&ḄÊᔠ⚪SËFÌᜧ஺10.ூᫀ௃2Al(s)+3FeO(s)=AkO3(s)+3Fe(s)AH=-859.7kJ-moLᔾæᜧᔾS2-+HO^HS-+OH->>c>a>b>dH2l2jூM᪆௃M"(1)î+"©Fe(s)+|0(g)=FeO(s)AH=-272.0kJ-mor12ঝ2Al(s)+|()2(g)=A10(S)AH=-1675.7kJ-moL23ôõö÷ø§Xcdঝùজx3g2Al(s)+3FeO(s)=AlO(s)+3Fe(s)AH=23—859.7kJ-mol-1,ᦑᫀ!"2Al(s)+3FeO(s)=AlO(s)+3Fe(s)AH=-859.7kJ-mol-1#23(2)জᵫ)*+;<ᱥḄýÂjDU}ᡂᱥḄýÂj;O.lmol•L-iNaOHhkᵫjᵯpPḄC(H+),ᦑᫀ>ঝHAhk8ᑮNa2cO3hkᨵPHAḄ⏚ឋ"⏚ḄNH4Ahkឋ!)ᩩ.jHAḄᵯp`!)ᡠ(NHJ2CO3᪷pqḄjr`i⏚᪷pqḄjr`ᡠhkḄpH>7(NH4)2S04NH4cl/⏚|my╆᪷pqjr¡¢hkᕈ⏚ឋhk£᪷pq¤`¥ᜧjr`¥¦jrḄ§ᦪ¨ᡠ©ᓄhkḄpHªᜧif⏚┤NH4Ahk▢□pqḄjr`!®,¯14⚓ᐳ19⚓

14ᡠhkᕈឋhkḄpHªᜧi©ᓄNH4HCO3hk²᪷pqḄjr`i⏚᪷pqḄjr`hkᕈmឋᡠhkḄpHªᨬᜧᑣpHᜧ³´c>a>b>d,ᦑᫀ>c>a>b>d.(1)MN⚪¸eᓄ¹tºᔠ»¼½¾ᑏPdeᓄ¹t(2)জᵫᱥḄ¿7À5iÁᡂᱥḄ¿7Àdᔾeᓣb_`*⊝ᔣ⌮ᔣNÄrঝᵫᔊBA!"ᦋ$ᔊ/0ᵨ2ᓄᑺ.(3)জMN*⊝QᦪᭆÆᑏP⊤'t_`ᓣb*⊝Qᦪᜧ/ᔾeঝfᓄghijfpqjrÈmឋ(4)Q_᝞ÊË(Mmol•LHAhkO.lmol•LNaOHhk®Íᔠ(ᔠ&hkÍḄ$ᓄÎᶍÐÑ)ÒÓᔠkḄpH=8,hkᕈmឋÕHA/|⏚জᔠhkNaAjrÈmឋ~jḄᵯpÖᓄghkᢓᑴjḄᵯpঝ᪷N⚪×HAḄ⏚ឋ"⏚NH4Ahkឋ᪷pqd⏚᪷pqjr`!)ᵫÄÓ╆᪷pqjr`i⏚᪷pqᡠ(NH4)2(X)3hkᕈmឋ᪷N᪷pqḄjr`ᑨÚhk⏚mឋḄᜧhk¤`¥ÛyḄjr`¥ᜧ.Ü⚪ὃÞßeᓄ¹tḄàᑏỼ½¾ḄÑâᵨ*⊝QᦪḄᑖ᪆Ñâyåjr`ᜧ"æᳮrèé/r⚪ᐵë⚪ìí`®.11.ூᫀ௃(l)3d54sl(2)ᑖq31*☢òóôsp3SOõஹPOø®(3)ACEN>0>C(4)4NH+Cu2+=[CU(NH)]2+334ম[CO(NH)C1]C1342/224X1O30ூ᪆௃(1)24ᐗ,ᜐᕜ⊤ᕜVIB!"#ᵯ%᣸'():3d54s௃"ᦑ/ᫀ)3d$4s௃2(2)3᝱5ᓄ⏒ᰚ9:;<"=>ᑖ%ᨔA2BCCOC12ᑖ%ᨵ2CC-C1Gஹ1CC=OJG"ᓫG)oG"JGMᨵ1C஺Gஹ1C71G"COC12ᑖ%஺GP71GḄCᦪS)31UV%WᨵXᵯ%Y"#Zᵯ%Yᦪ)3,ᑖ%[\᪀^)_☢abc2CCI4Ḅ;

15dV%Ccᡂ4CC-ClG"WᨵXᵯ%Y"ᩖᓄh⍝ᦪj)4,UV%klsp3ᩖᓄ;CCLV%ᦪ)5,#ᵯ%ᦪ)32,oCCI4Ḅp)qᵯ%Ar%)SOtஹP0,q,ᦑ/ᫀ)ᑖ%2312_☢abc2sp32SOtஹP0/q;(3)NV%yNi{\cᡂ|}G"~>V%{\cᡂᐳ#G,oᨵG,Wᨵr%Gஹ>G2ᕜ!ᐗV%ᦪᜧBᵯrᕈᜧ"NV%2Ph⍝)ᐙ᝱,Bᵯrᕜᐗ,ᦑBᵯr:N>O>C,ᦑ/ᫀ)ACE2N>O>C2(4)r%ocᡂ[Cu(NH3)412+,r%¥¦()4NH3+CM+=[CU(NH)]2+,34ᦑ/ᫀ)4NH+ᦑ2+=[CU(NH)]2+2334(5)0.1molCoCl-4NE¬ὑAgNC>3Ḅᱥ°Ḅ±=2mol-L_1x0.05L=O.lmol,ᡠyµ|3ᔠᱥ᜜¸5r%Cᦪ1,ᑣᨵ2C5V%|A,µ|ᔠᱥḄ|}ᦪ6,ᡠyᨵ4CNf|A"|ᔠᱥᓄ¼()[CO(NH3)4C12]CLᦑ/ᫀ)[CO(NH3)4C12௃C1;(6)ᨔ½FeV%ᦪj=8xJ+6x=4,ᨔ½°±=q8"ᨔAÂÃ=Ä+9*ON1NANAin—10ஹ3224x1()3010cm)=-^-g-cmᦑ/ᫀ)/É⚪ὃÌᱥ°Í᪀oឋ°"ÏᵨÑᣚÓÔᑏqᵯ%A"Ö×ᕜ!ᐗBᵯrØᓄÙÚÛÜ"ÝÞÚß|ᔠᱥ"Ö×|ᔠᱥᑁ¸o᜜¸~"áâᙳäÓåæᨔ½ᨵᐵèé஺12.ூ/ᫀ௃পCHsCHYëìᵬî3;(2)NaOHðñஹòóô(3)CHO2õᡂö=ᡈøVö=8124ভCOOHOo+nHOCH^CH^CH^HC—OCHiCHi>5ni;C^-H+(2n-l)H:OCOOHOHOH(5)52CHj—CH-CHr-CH316⚓"ᐳ19⚓

16ூ᪆௃ூᑖ᪆௃É⚪ὃÌᨵúᱥûüPᔠᡂ")⚣ὃ:"þÿὃ
ᑖ᪆ᑨᦪᱥ᪀ᓄ⚪ᐵ#$%ᔠ'()*+,ᱥḄ᪀./ஹᩩ234⚪5678ᜧ஺ூ<௃A>?@ᡂB,᪷CBDAECH—,B>F3ᡂCஹC>GᓄHᓄᡂD,ᑣCEOHCT^^CH஺JE>LᡂᡂF,G>LᡂᡂH,HMD>ᡂNᑖᓄᔠᱥᑣHE⏣PQᨵS⏣TUᑣᡂGḄEFGEHOCH2cH=CHCHOH,2G>LᡂᡂHEHOCH2cH2cH2cH20H,PBT᪀./EO_OHO-^C—C—J(1)AḄ᪀./CH3—^)—CH3,CḄᓄVWXYZᵬ\,ᦑ<ᫀE`CH—^^-CHJXYZᵬ\J33(2)(5)ḄaᑺMᩩ2ᑖcNaOHdeஹLfᦑ<ᫀE`NaOHdeஹLfJ(3)FḄᑖ/C8Hl2஺4ডḄhiLᡂᡈk,ᦑ<ᫀE`C8Hl2஺4JLᡂᡈk;(4)ঢḄᓄm(/COOH[|1+9HOCHXCHMH`m^H+(2n-l)H:OYCOOHᦑ<ᫀE:COOH+nHOCHzCCH^CHzOHH+(2n-l)H0:COOH

17(5)HEHOCH2cH2cH2cH20H,MHḄ}ᑖ~᪀Mᔠᑡᩩ2:aO.lmolMᡂ2.24L(᪗)ᑖ*Qᨵ1TUJb.}82TU᝞4ᙠ}ᨵ4J᝞3ᙠ}ᨵ1ᔠᩩ2Ḅᨵ5Jᐸ*᪶ᐳ¡3¢£P£☢¥¦§E3`1`1Ḅ᪀./OHOHCHj-CH-CH-CH3OHOHᦑ<ᫀE.c•ττ.©ª©F஺
CHj—CH—CH«'(6)CH=CHC(CH)=CH>LᡂᡂCHCOOCHCH=C(CH)CHOOCCH,23232323CH3coOCH2cH=C(CH)CHOOCCH>FᡂHOCHCH=C(CH)CHOH,323232HOCHCH=C(CH)CHOH>LᡂᡂHOCHCHCH(CH)CHOHᡈCH=23222322CHC(CH)=CH>LᡂᡂCHC1CH=C(CH)CHC1,CHC1CH=322322C(CH)CHCI>FᡂHOCHCH=C(CH)CHOH,HOCHCH=322322C(CH)CHOH>LᡂᡂHOCH2cH2cH(CH3)CH20H,ᐸᔠᡂ®E32ᦑ<ᫀE:A>?@ᡂB,᪷CBDAECH—,B>F3ᡂCஹC>GᓄHᓄᡂD,ᑣCE0HC-O^CH0;E>LᡂᡂF,G>LᡂᡂH,HMD>ᡂNᑖᓄᔠᱥᑣHE⏣PQᨵS⏣TUᑣᡂGḄEFGEHOCH2cH=CHCHOH,2G>LᡂᡂHEHOCH2cH2cH2cH20H,PBT᪀./E¯18⚓ᐳ19⚓

18HO-P-Q-L(6)CH=CHC(CH)=CH>LᡂᡂCHC00CHCH=C(CH)CHOOCCH23232323CH3COOCH2cH=C(CH)CHOOCCH>FᡂHOCHCH=C(CH)CHOH,323232HOCHCH=C(CH)CHOH>LᡂᡂHOCHCHCH(CH)CHOHᡈCH=23222322CHC(CH)=CH>LᡂᡂCHC1CH=C(CH)CHC1,CHC1CH=322322C(CH)CHC1>FᡂHOCHCH=C(CH)CHOH,HOCHCH=322322C(CH)CHOH>LᡂᡂHOCHCHCH(CH)CHOH«322232