广东省广州市四校联考2022-2023学年高二上学期第一次月考化学试题（含答案）

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12C.PᡂḄO*S02mH2Ḅᔠᐸᱥ-ḄW*O.lmol,PᡂḄO.lmolRSO2RH2RḄᔠ᪷ᐗmᐗḄᓄᔠ>ᓄ`ḄᵯᦪR0.2M,ᦑC!D.Na2sḄz2▢6◀S?᜜ᨵlGPᡂḄHS-mOH,ᦑ▢6ᦪᜧ801NA,ᦑD┯⚪@ᫀC஺10.AூFG௃A.ᵨ¡⏚¢z2ᔾᦈ¥W¦ᓄḄ6§¨©*2CO+SO2+HO=2HCO+SObᦑA!2B.FezChz8HIz2PᡂḄª6SLỚ6¬PᓄNOPᡂ®ª6mỚᓫ-NOḄ6§¨©*2Fe(OH)3+6H++2r=2Fe2++6H2O+l2,ᦑB┯C.±⏚◀l²¬PNOḄ6§¨©*2cH3coOH+CaCO3=Ca2++2CH3co0-+COt+HO,ᦑC┯22D.³´Ḅ⏚ឋᜧ8¡⏚᪷6f8¡⏚ᔣ³´¢z2jᐭ¥WCO2Ḅ6§¨©*C6H5O+CO2+H2O-C6H5OH+HCO3,ᦑD┯ᦑ⌱Ao11.BூFG௃A.·ᑴO.lmollTNaCl(aq)¹ºNaCl]<ᙠoW»¼½zGOᙠ¾¿zGᦑA]Àᔠ⚪ÁB.¦ᓄÂÃÄÅᜧ᧕Lᓄ¢z2NOÇ*ᦈÈSO2ÉᔾᦈÊᦑBÀᔠ⚪ÁC.ᑴËC2H4¹ÌÃÍÎNOᔠz2ḄÌÃᦑC]Àᔠ⚪ÁD.╅6lGOÐHC1ÑÒÓMgCLz2ᑴMgCL/HzO,ᦑD]Àᔠ⚪Á஺ÔÕᡠ×@ᫀ*B஺C112.Aூᑖ᪆௃p⏚¢m³)ḄÙlSÚᑭᵨqᓄÜᵯÝ◀ÞᑭᵨḄRᵯÝßàᳮ᪷ÇâãäSåA᩽çCl''௃`ᓄ*è)¬PéᵯḄNOᐸᵯ᩽NO©*41êë+8e-4H+=4Cì+41)B᩽*ᵯÝḄῳïᐸNO©*çCHCOO-8e+2HO=2CO2+7H+,ðñᔠᵯÝḄNOᳮᑖ᪆஺32

13ூFG௃A.᪷Õ×ᑖ᪆Såò`8moiᵯ¹᩽ôὑ4moiH+,ø᩽Pᡂ7moiH+,ᑣᜐᳮnḄÙlpHüýA!B.ø᩽NO©*çCH3co0-8e+2H2O=2CO2+7H+,ᡂ1molCCh,ᨵ4moleB┯C.ᵯ!"#$C┯D.A'(᩽*+,-ᵯ᩽,-.'[)/Cl+2e-+H+=Cr+[),D┯ᦑ⌱Ao13.Bூ89௃A.;ᐭ=>⏚@>⏚ᵯAB⊝(ᔣEFᵫH>⏚IJ=KLᜧᦑᐸᵯAOKPQA┯B.ᵫHNH4HSO4TNHUV9WᑮYJᵯAZḄH+ᢓᑴᦑ^_=K`c(NH)UNH4HSO>NHC1,ᡠefC(NH4C1)>C(NH4HSO4)`gὅ#$Tc(NHU)ijk^lB44(mC.᪷oᵯ₹qឤUc(NHU)+c(H+)=c(OH)+c(C1)sᔠ#$uTឋ`c(H+)=c(OH)wc(NH)=c(Cx)ᦑgὅyzlH1,c┯D.Kp}~Kᨵᐵ~#$ᐵKKD┯ᦑᫀ⌱B஺14.Dூᑖ᪆௃᪷o⚪,-ḄᓄO.'UNO+CO=CO+NO,ᵫ,-22ᱥḄkHᡂᱥḄkᑣ,-',-H=ExE2=(134-368)=-234kJ/mol,o¢ᑖ᪆9஺ூ89௃A.H=(,-Ḅ£ᓄk-⌮,-Ḅ£ᓄk<0,§¢(,-Ḅ£ᓄkQH⌮,-Ḅ£ᓄkA┯B.H=,-ᱥḄ¨k-ᡂᱥḄ¨kV0,ᑣª«1molNCMg)®1molCO(g)ᓄ¨ᔾᦈḄkQH±ᡂ1molNO(g)®1molCCHg)ᓄ¨ᡠ²ḄkB┯C.ᓄO.◤⌕µ¶ᱥ·¸᝱ᑣᓄO.-'UNO(g)+CO()=CO2(g)+NO(g)2gH=-234kJ-mol1,C┯D.ºᵨ¼ᓄᑺk¾¿À,-Ḅ£ᓄkÁÂãᓄᑖÄᑖᦪºb~aḄÈÉPQD(m

14ᫀ⌱D஺15.Aூ89௃A+B-X(ᔾ)ʶAஹBḄkQHXḄkX—C()ʶXkᜧHCḄkA+B-C()ʶAஹBḄkᜧHCḄkᦑ⌱A஺16.Bூ89௃ᑭᵨAG'H-TASÍÎᑖ᪆ÏAGVOḄ,-kYÍÎ஺A.,-2C)3(g)=3O2(g),AH<0,AS>0,,-ÐkYÍÎAᔠ⚪ÑB.,-2co(g)=2C(s)+Ch(g),AH>0,AS<0,,-ÐkYÍÎBÒᔠ⚪ÑC.,-N?(g)+3H2(g)=i2N&(g),AH<0,AS<0,,-ᙠÀÔkYÍÎCᔠ⚪ÑD.,-CaCO3(s)=CaO(s)+CO2(g),AH>0,AS>0,,-ᙠÔkYÍÎDᔠ⚪Õᦑ⌱Bo17.প(2)0.024mol/L-min(3)ºᵨ×ØᦔḄ¼ᓄᑺভKL&V஺(5)40%ac(6)ABூ9᪆௃(1)ÚÛ1T50min`ᔣÜᘤTᐙᐭÐHe,ᑣ(,-ß᳛§'ᔜᱥ·Ḅ=K(2)ÚÛ2Tâ=Kᓄ'U2mol/L-1.28mol/L=0.72mol/L,20minᑁNHஹḄ=K'U0.722mol/Lx-=0.482mol/L,v=c-?At=0.482mol/L4-20min=0.024mol/L-min(3)zäÚÛ1®2,ឤÜåæÜᘤTçèᢗᐭ^lḄᩩëÔìíK^_ÚÛ2ØîïᑮB⊝ʶÚÛ2◚ñḄᩩëòºᵨ×ØᦔḄ¼ᓄᑺ(4)K}WKóôí¢,-KõÀKÉõᜧᦑö÷'UK,=K

15(5)N(g)+3H2(g)ø^2N&(g)2ùè1030PL2L1_40=ᓄA-3xlxP2n20810-x+30-3x+2xB⊝10-x30-3x2x12mol9B⊝`ýþḄᓄ᳛a=30molkʶ,-ïᑮᓄB⊝¸᝱Ḅ:a.
ᓄᦪᘤᑁᢝᑮᓄ⊝᝱b.!"#$ឤ&#ᦑ()ᘤᑁḄ()ᢝ+ᑮᓄ⊝᝱c.,ᔠ.!/c(NH,)+ᑮᓄ⊝᝱;d.2V2(W)=v⌮(NH3)2⌮5᳛7895᳛:;ᦪᡂ2:ᑮ⊝᝱ᦑ⌱ac(6)A.>ᵨ@ᓄᑺBC5᳛D⊝EFA2GHB.I)JKJC⊝ᡠᵨMNJOP<12,ᵫ1-T2ᓣKI)⊝ᔣ⌮UᔣEFNH3Ḅ!"ᑖᦪWXB2GC.⊝Mc(N2)ஹc(H2)ஹC(NH3)[C(N2)=C(NH3)=C(H2),C┯]ᦑ⌱AB஺A18.(1)MnCh+4HCl(_)=M11CI2+2H2O+CI2T(2)abBcdeC/fgpH<7(3)C/fgᵫhi⁐ᡂkl⁐X0.158b”79b0/ভnoᡈqo(5)rstuM/+w@ᓄᑺ5᳛BCx₝⏚_){|5᳛W}c(H2c2O4)/molL-im(MnSO)/g~⁐MN/s0.050tj0.050.1t42ூᑖ᪆௃ḄḄᐜᑴ.ᯠxᓄᐭKzMnChfg/ᨬx.ᜐᳮ஺KzMnChfgᙠpH=7~7.5N᧕Chᓄᡠ◤⌕ᑴC/fgḄpH,¡¢[£¤■¦A/tuḄHC1ᐭCᑁ஺

16(1)A/MnCh§_¨⏚ᙠBcᩩª«uᡂ.ஹMnCL¬uḄᓄUsAAMnO2+4HCl(_)=MnC12+2H2O+CLT஺®ᫀHMnC)2+4HCl(_)=MnCL+2H2஺+Cl?2;(2)A/ᨬᔠ〉ḄI)80࠷,²³ᑴI)´>ᵨabᡠ◤⌕µḄU¤[HabBc/¶B_¨⏚Ḅ5)+rCᔲᑣCL/,ᨵḄHC1+ºᐰ⛳½¨aᔾᦈfÀᙠC/ÁÂ>fgᕈ⏚ឋᡠᐸÆ[HdeC/fgpHV7஺®ᫀHabBcdeC/fgpHV7(3)K2MnO4hi⁐KMnChkl⁐ÇKzMnCUºᐰCLᓄM´ÈÉᑮC/fgᵫhi⁐ᡂkl⁐஺®ᫀHC/fgᵫhi⁐ᡂkl⁐(4)ᵫ´ÊË«ᐵ;HKMnO,_5Na2s2O3,100mLfg/"(KMnO4)=g»(NaS2O3)=0.0100mol/Lx5bx10-3Lx|=bx105mol,KMnOÍḄÎ)2Ïᜐ3Ñಗ1஺஺o=4oᡈÓo஺®ᫀH&ÕoᡈÖo;aga500aa500a(5)KMnCUfg§H2c2O4×ḼḄᱥ_)WX5᳛W᠒DÛÜ5᳛BCᵫÝ´Þß´+Mn?+Ḅ@ᓄàᵨᡠᐸÆ[HrstuMr?+w@ᓄᑺ5᳛BCx₝⏚_){|5᳛W}஺£áâÞßḄÆ´wã:ᢝᱥḄ_)!"ᑖäåBᐭæç#MnSCU,:èfg~⁐ḄMN஺KMnCUfg§H2c2O4Ḅᐵ;H2KMnO—5H2C2O4,´éêc(H2c2O4ë0.05molLLᵫì´íê«ᦪîH4~⁐ïc(KMnC)4)/molV(KMnO)/V(H2c2O4)/c(H2c2C)4)/molm(MnSO4)4MðL1mLmLL1/gN/s

17I0.012.02.00.050tiII0.012.02.00.050.1t2®ᫀHrstuMM+w@ᓄᑺ5᳛BCx₝⏚_){|5᳛W};cH2c2O4ñ/molL“mMnSO
/g~⁐MN/s0.050t,0.050.1t42oூòó௃Çfg/¬uôõM´ÊËᐵ;éÀ஺0?2xOQ619,-1268II0.4-CD2NH+3NaClO=Nt+3HO+3220.44xl.4533NaCl1.5I)r|Mᓄ5᳛᠒ö◀ᦔ᳛|I)rKMBCùHC10ḄᑖÀúᡈNaClOᑖÀñNaClOḄᑭᵨ᳛{|ü.ᙠI)rKM᧕ᢵ¬஺ூþÀ௃ú1
ᵫ⚪ᡠᦪᑏ᝞ᓄজ3H2g
+N2g
U2NH(g)Y=2,ᡈ=-92kJ/mol,ঝ2H2(g)+C)2(g)=2H2O(g)3H=2A,.^,=-484kJ/mol,ᵫঝx3-জx2,4NH3(g)+3Ch(g)U32N(g)+6HO(g)A/7=3A/7.-2A/7/=-1268kJ/mol,ᦑ!ᜐ#-1268$222!(2)জᵫ%&'(ᙠ*+,(-ᡂN2/-ᡂNO0(ᦑ12ᓄᑺᙠ*+,456II⌱8ឋ:;$ঝ520࠷,(ᵫ%&ᦪᑡ᝞56I4NH+50,f4N0+6H.,0;!2,56H>ᓄ0.2mol0.25mol0.2mol0.3mol4NH+30f2N+6H032292,ᑣE⊝,,>ᓄ0.4mol0.3mol0.2mol0.6molஹ(1-0.2-0.4)mol.@ஹ(2-0.25-0.3)mol..C(NH)=-----------------=0.4mol/Lஹc(O)=--------------------=1.45mol/Lஹ32c(N2)=c(NO)=AB=0.2mol/Lஹc(HO)=(0-3+^)m°'=0.9mol/L,ᑣ56IIḄE⊝Gᦪ2H,)?62_0.22?6(C4(NH)?343$32ঞᵫL56ᵨᑮO2ᓄᑺ(ᦑ!,NOP᳛R*ᨵTUVW+XYZ[\2ᓄᑺ]ឋR(^᜜!56`ᔣWb56(ᓣZ+X(E⊝⌮ᔣef(gh[\NOP᳛R(ᦑ

18!ᜐ⌱CD$(3)জᵫ%1'(mnop56Ḅ56ᱥWNaClOஹNH3,-ᡂᱥWN2,᪷ᐗyzឤ|ᔠ⚪(o-ᡂᱥᨵH2OஹNaCl,|ᔠᜫᵯzឤᐗyzឤEp56W2NH3+3NaC10=NT+3HO+3NaCl$22ঝ◀᳛Z(*(◀ᦔᨬ(ᔠ⌕ḄᨬW1.5$ঞ+15~30࠷,¢+XY*YZ£¤¥X¦§(ᓽ+XY*,ᓄ56©᳛᠒(◀ᦔ᳛*+XYZ,(«¬OHC1OḄᑖ®(ᡈNaClOᑖ®)(NaClOḄᑭᵨ᳛R*°±²ᙠ+XYZ,᧕ᢵµ஺20.(1)C5H124C1CH2(CH3)CHCH2cH3ஹ(CH3)2CC1CH2cH3ஹ(CH3)2CHCHC1CH3^(CFhbCHCH2cH2clCH?=C(CH3)CH2cH3ஹ(CH3)2C=CH2cH3ஹ(CH)2CH-CH=CH.32(¾¿ÀÁÂÃ)HBr(2)[f^|+Br-FeBR>+HBr2P+C1____+HCI(3,02pcl2ூᑖ᪆௃ᵫÑ✏ÓKḄᓄ'KWÕ²ᙠᐝ᯿56-ᡂØÙᙠÚᓄÛ2ᓄᙠÕÜݵ-Þß56-ᡂF$(1)জ1ÓḄàáâ/W51,àáᐗyḄᱥâḄã/Wä$=512,1ÓḄᨬåWC5H12,ᨬåḄæ4ᑖâW5x12+12=72,A4á²Ḅæ4êXW36,1ìḄæ4ᑖâW36x2=72$ᡠÃ1ᨵíᱥḄᑖWC5Hফঝ1ᨵíᱥḄᑖWC5Hফ᝞1ïAḄðñᨵ4¤à(ᓽWòóô(ᐸÀÞßᱥᨵC1CH2(CH3)CHCH2cH3ஹ(CH3)2CC1CH2cH3ஹ(CH)CHCHC1CH>(CH)CHCH2CHC1323322ᐳ4Á$ঞÓAᵫ^ÀÁÓB÷Y«ᡂ56øᑴ(úBWûÓᡈᯋý(ᵫàð'þÿḄ

19cᨵC—!—CYᑣBḄ᪀CH2=CCH3CH2cH3ஹCH32C=CH2cH3ஹ123(CH)CH-CH=CHS—„;322(2)ᘤA!"#$ᡂ&!HBr,Ḅᓄ()*+Br_ḛ22Br(3)clCH23K1
জ-!./ᙠᐝ᯿3$ᡂ)*gncl2+CL____,09