2022年北京市普通高中学业水平合格性考试化学仿真模拟试卷02（解析版）

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3ூ:ᫀ௃Dூ=᪆௃A.jḄᓄᔠᓣᓄᐹᨵ,ឋᦑAB.j)b6◤ḄvwᐗᦑBC.ijdᕈ⁐ᦑCD.j⏚ᡂijG*Fe+2H+=Fe2++HtᦑD┯2ᦑ⌱Do9.ᐵ2H2+O22H2OḄ)A.¡¢H—H£¤[wB.ᡂH-O£¤[wC.¥*ᔾᦈD.ᱥḄ¨[w{ᡂᱥ¨[wூ:ᫀ௃Bூ=᪆௃A.¡©ᓄO⌕ᔾᦈ[wᦑA┯B.ᓄOḄᡂl¤q[wᦑBC.ªᙠª«¬)¤ᦑC┯D.¥*¤ᡠᱥḄ¨[wᜧᡂᱥ¨[wᦑD┯஺ᦑ⌱Bo10./ᑡᐵ°ḄḄ)HCHf^HCA.±²³´ᜧB.[µ⏚ឋKM11O4d¶⁐C.·¸¹D.Dºᱥ12*3Fᱥூ:ᫀ௃Cூ=᪆௃A.d᝱«Ḅ±²³´{°)d᝱«±²³´{ᦑA┯B.°A[µ⏚ឋKMnChd¶⁐ᦑB┯C.°[Dd¼ᡂ½°¸¹ᡠ·¸¹ᦑC

4D.°¿ºᱥ1ᑖG@3H᪀A3)3ᑖ4᪀6A)3FᱥᦑD┯஺ᦑ⌱C஺11.ÂÃᐗᕜÅÆÇÈÉ¡/ᑡ┯Ḅ)A.⏚ឋHNO>HCOB.ÒឋNaOH>MgOHÖ3232C.#ឋK>NaD.,ឋCl>Brூ:ᫀ௃Dூ=᪆௃A.$#ឋN>C,ᨬᓄᱥÜ´ᓄᱥ'ᡂ⏚Ḅ⏚ឋ*HN03>H2cO3ᦑAB.#ឋNa>Mg,ᨬᓄᱥÜ´ᓄᱥḄÒឋ*NaOH>MgOHÖ2,ᦑBC.K,ßàᜧáᨬ᜜ãᵯᦪ*1,ᜫᵯ[æK>Na,#ឋK>Na,ᦑCD.$#ᓫ1ᓄឋçèÜ▢Ḅ,ឋçêᓫ1ᓄឋCb>Br2,Ü▢,ឋ*C1-VBr,ᦑD┯ᦑ⌱D஺12./ᑡᐵîªḄḄ)A.ïð/)ñ⁐ª6B.ᵨòᩭ´ôõC.[µö÷Ḅø⁐ùᩩ¶⁐D.H2ᙠCL«¬üᯚᕈþ⁐ூ:ᫀ௃Bூ=᪆௃A.îª*þ⁐ஹᨵÿឋᕡḄᦑA┯B.ᡂ⏚⏚⏚ᐹᨵឋᵨᩭ!"ᦑB#$C.&ឋᡂḄ⏚ᐹᨵឋ'()*+Ḅ,⁐.ᩩ0⁐()12Ḅᨵ⁐.ᩩ0⁐ᦑC┯D.4ᙠ6789ᯚᕈ<⁐ᦑD┯=ᦑ⌱=Bo13.ᙠBCஹBEᨵFᓄᑺḄឤJKLJᘤ6NO=N2RgT+3H2RgT12NH3RgT஺XᑡZ[#$Ḅ\A.]ᑮ_⊝a#⌮c᳛ᙳfgB.ᙠh[ᩩiXN2(ᐰklᓄfN%C.]ᑮ_⊝an6ᔜᱥqḄrstu'vD.]ᑮ_⊝an6ᔜᱥqḄrstuwx

5ூ{ᫀ௃Cூ~᪆௃A.ᓄ_⊝᝱f᝱_⊝]ᑮ_⊝a#⌮c᳛wx'fgᦑA┯B.f⌮N2'(ᐰklᓄfᦑB┯C.]ᑮ_⊝a#⌮c᳛wxn6ᔜᱥqḄrstu'vᦑC#$D.]ᑮ_⊝a#⌮c᳛wxᔜᑖrs'vᓄn6ᔜᱥqḄrs'tuwxᦑD┯ᦑ⌱=Co14.wqḄ⏚ᑖᙠXᑡᩩiXac᳛ᨬḄ\⌱⚗T/࠷C(HSO)(mokL1)24A201B202C401D402A.AB.BC.CD.Dூ{ᫀ௃Dூ~᪆௃A.Csf20࠷,c(H2so4)=lmol/L,6c(H+)=2mol/LB.Csf20C,c(H2so4)=2mol/L,6c(H+)=4mol/LC.Csf40࠷,c(H2SO4)=lmol/L,6c(H+)=2mol/LD.Csf40࠷,c(H2SO4)=2mol/L,6c(H+)=4mol/LᵫCsBஹc(H+)ᜧc᳛ᡠ⌱⚗DḄc᳛ᨬᜧ,ᦑ⌱=D஺15.1Csᵨ¡᯿£¤஺XᑡᐵᗓCsḄ§¨#$Ḅ\A.q©ᦪf82B.6©ᦪf55C.qᦪf82D.᪶᜜ᵯ©ᦪf55ூ{ᫀ௃Dூ~᪆௃

6A.ᡈCsḄq©ᦪ=55,ᦑA┯B.^Cs6©ᦪ=137-55=82,ᦑB┯C.^Csqᦪ=137,ᦑC┯DR’CS᪶᜜ᵯ¯-ᦪ=᪶ᵯ₹ᦪ=55,ᦑD#$஺ᦑ⌱D஺16.Xᑡᐵᨵ³ᱥḄ§¨'#$Ḅ\A.´⏚ḄpHµ7B.´¶·¸ᡂC.¹()⏚ឋKMnCU0⁐D.´⏣ᙠtuᩩiX(»¼ᓄᡂ´½ூ{ᫀ௃Cூ~᪆௃A.´⏚¾-COOH,¿⏚ឋḄpHµ7,ᦑA#$B.´¶¾ÀÀÁÂøᡂᦑB#$C.¹⏚ឋBÄ⏚Å''0⁐ᦑC┯D.´⏣¾-OH,ᙠtuᩩiX(»¼ᓄᡂ´½ᦑD#$஺ᦑ⌱C஺17.ÆÇ©ḄÈ᪀ÊËÌfᐵÇ©Ḅ§¨'#$Ḅ\A.Í▢Ï©B.᪶᜜ᨵ3Ðᵯ©ÑC.᪶᜜ᵯ©ᦪf18D.ᙠᓄ6᧕Óᵯ©ூ{ᫀ௃Dூ~᪆௃A.ÔÕᑖ᪆ÖÇ©fÏ©f▢Ï©ᦑA#$B.ÔÕÇ©È᪀ÊËÌÖ᪶᜜ᨵ3Ðᵯ©ÑᦑB#$C.ÔÕÇ©È᪀ÊËÌÖ᪶᜜ᵯ©ᦪf18,ᦑC#$D.Ï©fÏ©ᨬ᜜Ñ]ᑮ8ᵯ©×uÈ᪀'(Óᵯ©6᧕ᜫÙᵯ©ᦑD┯;

7ᦑ⌱=D஺18.Xᑡᵯ©ÛÜᑏ#$Ḅ\A.=N===N=B.=(j;C-()=C.L(j=HrD.Hci==()=ூ{ᫀ௃Cூ~᪆௃A.åᑖ©Ḅᵯ©Ûf=NæN=ᦑA┯B.ç¼ᓄÀᑖ©6ḄÀ¼ÂfÀ¼ÁÂ#$Ḅᵯ©Ûf=ᦑB┯C.4¼᪷Ï©féᨵ1Ðᓫëìᵯ₹Ḅ▢Ï©◤⌕᪗ðÏ©6ᔜñ©ᨬ᜜Ñᵯ©4¼᪷Ï©Ḅᵯ©Ûf=[:O:H]-ᦑC#$D.⏚fᐳõᓄᔠᱥᑖ©6÷ᙠH-0O-C1øÐᐳõÂᵯ©Ûf=o=Cl=,ᦑD┯H=▲▲♦ᦑ⌱C஺19.Xᑡᨵ³Í¸ᡂḄ\A.2c6H6+1502ú7J2co,+6HOB.CH=CH2+HOCH3CH2OH22C.2cH3cH2OH+2Nat2cH3cH?ONa+H2TD.2CH3CH2OH+O2-7^.2cH3cHO+2H2Oூ{ᫀ௃BA.2c6H6+1502û12CO+6HO\¼ᓄᦑA'⌱;22B.CH-CH+HO^^^222CH3cH2OH,6C=CÂᡂC-CÂf¸ᡂᦑB⌱;C.2cH3cH2OH+2Na-2cH3cH2ONa+H2T\üᣚᦑC'⌱D.2cH3cHzOH+O=þ2cH=CH0+2H2஺6-OH¼ᓄᡂ-CHO,f¼ᓄᦑD'⌱஺20.ᙠÿ
ᑡᦑᡈḄᜐᳮḄA.ᨵᜧᵨ!"#$ℳ☢'()*+,-

8B./01Ḽ345ᵨ6789ᩭ;3C.<=>⏚@ᙠBCDEᓽᵨ=GHᓄ1JKD.L>⏚ḄMN᎔ᐭᢣRSᘤUVW᣸ᐭY⍝ூ\ᫀ௃Cூ_᪆௃A.Y_aឋUᔾᦈᦑAeB.13UᵨYᡈfHᓄgᩭ;hUᵨ67Ḅ89ᦑBeC.GHᓄ1iᨵiῖ⇨ឋl⏚mnoᦑ<=>⏚@ᙠBCDNEᓽᵨᜧYJKᦑC┯qeD.>⏚Uῖ⇨Y⍝⌼ᡂY9tuᦑUVW᣸ᐭY⍝N᎔ᐭᢣRSᘤᦑD஺ᦑ⌱xCo21.ᑡyᓄ0zᓄ{yᓄḄA.NO⍗}y⁐B.ឋY⁐C.SO⁐D.FeCb⍗KSCNy⁐2ூ\ᫀ௃Bூ_᪆௃A.NO⍗}y⁐ᨵᱥfHᓄᡂ0zᓄ{yᓄᦑA┯qeB.ឋY⁐ᔾ▬ᵨᨵᱥᡂᱥᳮyᓄᦑBiEeC.SCh⁐>⏚ᔠᡂ⁐ᱥᨵᱥᡂ0zᓄ{yᓄᦑC┯qeD.FeCb⍗KSCNy⁐ᨵᱥ>ᓄᡂ0zᓄ{yᓄᦑD┯q஺ᦑ⌱B஺22.ᑡḄA.36gHOḄᱥḄImol2B.ImolCLḄ22.4LC.0.5mol-L-'NaCILᨵ0.5molNa+D.ImolCChLᨵḄᑖᦪ6.02x1023ூ\ᫀ௃D

9ூ_᪆௃A.36gH2஺ḄᱥḄ2mol,ᦑA┯qeB.᪗¡¢£1molCLḄ¤22.4L,ᦑB┯qeCO5moiI-NaCl¥¦ᦑ§¨Na+ḄᱥḄ©ᦑC┯qeD.lmolC0LᨵḄᑖᦪ6.02x1()23,ᦑ஺2Dᦑ⌱D஺23.ᑡ«NḄ*¬®ḄA.g⏚┛z°⏚xCaCO+2H+=Ca2++CO2t+HO32B.±>⏚GHᓄ²«NxBa2++SO42=BaSOl4C.Hᓄ╅±>⏚«NxMgO+2H+=Mg2++HO2D.´µᱏ·ᐭ¸⏚¹xCu+Ag+=Cu2++Agூ\ᫀ௃Cூ_᪆௃A.g⏚┛z°⏚*¬®xCaCO3+2CH3COOH=Ca2++CO2T+HO+2CHCOO-,ᦑA┯q:23B.±>⏚GHᓄ²«N*¬®x2H++2OH+Ba2++SOF=BaSO4+2H2O,ᦑB┯qeC.Hᓄ╅±>⏚«N*¬®xMgO+2H+=Mg2++H2O,ᦑCeD.´µᱏ·ᐭ¸⏚¹xCu+2Ag+=CM++2Ag,ᦑD┯q஺ᦑ⌱xC«24.´»¼ᐝ¾ᓄᑺ!ᐭYᐸ⊤☢ᐝ_YḄ«N£᝞ÄᡠÆ஺ᑡḄA.ᐝ_Y´ᓄ{UÇᓄÈᵯUB.H”ᙠ»¼ᐝ¾ᓄᑺ⊤☢ÊHᓄ«NC.ᡂ02▬ËḄឋÌiÍxkÎD.ᐝ_YḄÏ«Nx2H2O^^=2H2T+O2T

10ூ\ᫀ௃Dூ_᪆௃A.ᐝ_Y´ᐝUÇᓄÈᓄ{UᦑA┯qeB.H+ᙠ»¼ᐝ¾ᓄᑺ⊤☢ÊÕÖᓄ«NᡂÈGᦑB┯qeC.ᙠᡂ஺2ḄÙÚÈG*ᓽᡂ▬ËḄ⏚ឋÌiᦑC┯qeD.ᐝ_YḄÏ«Nx2H2O^^=2H2T+O2TᦑD஺25.ᑡᐵzáâã*äḄḄA.åᐭKSCNy⁐éêëRLFe3+B.åᐭBaCLᨵñ⁐òóÚéêëRLS04ஹC.÷øᯚ⁐úûüý⁐þÿᴻ
ᑮ⁐ᯚK+,Na+D.ᐭAgNChᨵ⁐!"#crூ'ᫀ௃Aூ*᪆௃A.ᐭKSCN-./⁐ᓽ!ᡂ2Fe6SCN73,9"#Fe3+,ᦑA;<=B.ᐭBaCbᨵ⁐!@⁐ABCD⏚FGABCHᓄJᑣ9ABS0F,GABᨵAg+,ᦑB┯N=C.OPᯚ⁐QRSTUV⁐WXᴻ
ᑮ⁐ᯚK+,YZ<#CᔲNa+,ᦑC┯N=D.ᐭAgNChᨵ⁐!@⁐ABCHᓄJGABCD⏚Jஹ]⏚Jᑣ9ABChᦑD┯N=ᦑ⌱_A஺abcᑖe⌱f⚪6ᐳ50ᑖ7jcᑖᐳ9l⚪ᐳ50ᑖ஺26.63ᑖ7⊡pᱥrsᐸᵨ⌶Ḅxy஺ᵨ⌶ᱥrA.z{‷}Ḅ~ᑺa.NazCh

11B.✈ᜮḄᑺb.FezChC.84Ḅᨵᦔᡂᑖc.NaHCOsD.ᧇ9Ḅ/⁐ᧇd.NaClOூ'ᫀ௃ᵨ⌶ᱥrA.z{‷}Ḅ~ᑺ"----------------------a-Na2ChB.✈ᜮḄᑺb-FeiOsC84ḄᨵᦔᡂᑖcNaHCChD.ᧇ9Ḅ/⁐ᧇd-NaClQூ*᪆௃NaHC03ᑖ*.]⏚ஹbᓄ]ஹ{ᵨ✈ᜮḄᑺ=NaCIOBbᓄ]!ᡂH⏚NaCIOC84Ḅᨵᦔᡂᑖ=FezOsC/⁐Fez஺ஹᵨᧇ9Ḅ/⁐ᧇ=27.(3ᑖ)⌱fᡂᑡRḄ஺(1)◀¡{9Ḅ¢£ᵨ(¥¦§¨)஺(2)©ᩭ{ᑴᜓ{ᵨ஺(3)®ᑴ100mL1.00mol-L¯NaClᵨ஺ூ'ᫀ௃প±(2)0(3)0ᦈ³´௃

12(I)U¶Cᑖ·¸Ḅ¹◀¡{9Ḅ¢£ᵨU¶=(2)©ᩭ{ᑴᜓ{ᵨ¹{-.{º»¼ᡂ{ᦑ⌱±=(3)®ᑴ"#ᱥrḄ½¾¿Ḅᡠ◤ḄÂÃᨵÄÅஹƽஹ*(»ᓾ)ஹÈÉஹÊËஹ#Ìஹ᤯ᒴஹÏÐÑ=ᑣ®ᑴlOOmLLOOmolLNaCI⌱ᵨ±஺28.(6ᑖ)ᙠC+2H2s04(¾)qCO2f+2SO2T+2H2஺9_(1)ᐗáâᓄCᓄᑺCãäᱥ஺(2)åᨵ0.6molḄCæᑣâãäḄH2s஺4ḄᱥrḄ½.mol,9ÈÉḄᵯèḄᱥrḄ½.moLூ'ᫀ௃C¾H2s04SO1.22.42ூ*᪆௃@9Cᐗáᓄᔠêᵫ0ê-.+4êஹSᐗáᓄᔠêᵫ+6ê-.+4êᜫᵯèᓄᔠêᓣîḄᱥCãäᑺïᵯèᓄᔠêð³ḄᱥCᓄᑺᓄᑺñḄᱥCãäᱥòᔠᓄãäḄóôᑖ᪆*'஺(1)Cᐗáᓄᔠêᵫ0ê-.+4êCᐗáᜫᵯèâᓄSᐗáᓄᔠêᵫ+6ê-.+4êSᐗáïᑮᵯèâãäᑣH2s04.ᓄᑺñḄãäᱥ.S02,ᦑ'ᫀ.C=H2so4=SO2=24moi(2)᪷ö÷øù,0.6molḄCæ,ÈÉᵯè0.6molx4=2.4mol,ᑣâãäḄH2sO4ḄᱥrḄ½..
=1.2moLᦑ'ᫀ.1.2=2.4o29.(6ᑖ)᝞ýᡠþḄäᵯÿ
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13(1)$(2))*2H++2e=H2T(3)=>?@ABCDEᔣFூ᪆௃(1)HIJ*ᵯK>ḄM/ឋOFP*ᵯKḄ$᩽F᩽஺(2)FQ᩽2Ḅ34-Rᑮᵯ-TᡂVWX)*ᵯ᩽%&2H++2e-=H2஻(3)>ᜫ\ᵯ-ᵯ-]ḼCDEᔣFᵯ᩽2Ḅ34-ᔣ᩽./஺30.(6ᑖ)c1dᯠf2gᐗiḄjᙠlmcc2⊤lgᐗiḄopᓄᔠrstᑖᱥvwḄx&ᐵz஺{ᑡ⚪:硫元+6S03M素+4的7/᝞^Na2sO3化IIt合OIItIIIrIII价III一2III1113ᓄᓫᓄ⏚ᱥvwᱥᱥ1ᯠᐗḄᙠ2ᐗḄ(1)c12s%&TᡂP⏚ḄᱥḄᓄ+஺(2)᯼ḄTᜧS0⌼ᡂ᛻ᑡᐵS0ᳮḄ()஺22A.ᙠ᯼2Tᮞ¢gB.S02C,¦᯼TḄ§W᣸©ᑮª«D.ᵨ®ᔾᦈ±W2ḄS02(3)Cu³MḄµ%&TᡂZḄᓄ0¶+஺(4)NaSO᧕»¼½¾½¿Na2sChÁ»ḄÂóÄÅ஺23ூᫀ௃(l)SChফCAবCu+2H2so4(µÉC11SO4+SO2T+2H2O

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