浙江省普通高校2021-2022学年高考仿真模拟化学试卷含解析

《浙江省普通高校2021-2022学年高考仿真模拟化学试卷含解析》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2021-2022ὃᓄᔁὃ1.⚪ὃஹஹஹὃஹᑏᙠᔁᑁ!ᙠᔁ"#$%᪗'஺2.)*+ᑖ⌱.⚪/0⚪⌱1ᫀ3◤ᫀᑏᙠᔁᢣ6Ḅ8ᑁ)9+ᑖ:⌱.⚪ᫀᑏᙠᔁ⚪;ᢣ6Ḅ<"஺3.ὃ=>?@⚪ᓱḄ᦮C஺ὃDE3FᔁG⚪ᓱ*HIJ஺*ஹ⌱.⚪(ᐳᒹ822N0⚪஺/0⚪ᙳPᨵ*NRᔠ⚪Ḅ⌱⚗)1ஹVWXYZKa(CH3COOH)>Ka(HClO)ஹK(ACl)>K(AgBr)oZᑡᑖ᪆^_Ḅ`()spgspA.10mL0.1mol/LNa2cChab⌲ddeᑮ10mL0.1mol/Lg⏚ic(Na+)>c(Cr)>c(CO2-)>c(HCO3")3B.jᨵজ200mL0.1mol/LNaClOabঝ100mLO.lmol/LCJ^COONaablmabiḄ▢opḄᱥrḄstuvGঝ,জc
NHC.ᔣ0.1mol/LNH4CIabieᐭ{sNH4cl|}:0c
crD.AgBrGAgClḄ⛳Gab}ᔠeᐭsAgNChtabḄAgClAgBr2ஹiᦻᜧ஺Zᑡ┯Ḅ`A.ᑴ◌Ḅi¡ᓄ¢ᓄB.ᖪ¤3¥ᑴ#Ḅ¦§¨©ª«ᔠ¬ᑴC.®¯ᑴ°iḄ“°”ᢣḄ`³°D.´ᕚᕚjḄᵨ·ᶭ¹ºḄ☘¼½)ªᨵ¾ᑖpᓄᔠᱥO3ஹZᑡ¿Ài᪷ÂjÃ!1ḄDÄ┯Ḅ`()⌱⚗¿ÀjÃDÄÅÆᩩÈZᵨlmol-L”ḄCHaCOOHaACHjCOOHGImol•L1ḄHC1ᑖbÎÏḄÐÑCHjCOOH`ÔᵯÕrÉÊËᵯឋ¿ÀÒᨩ×ØᨵÙÚBᔣÖabie«Gt112so4ÝabÞßàᨵNCh-⁐Ü}ᔣÖágidetg⏚ḄäágåNa2sChᡈCÙabã⁐Ü}âᐭÙabNaHSO3

1ᔣtuᙳå0.1mol•L1ḄMgCLஹᐜ1jê⁐Ksp[Mg(OH)]>2DCuCLᔠabi⌲deᐭçèKsp[Cu(OH)]2A.AB.BC.CD.D4ஹ¿ÀᵨNHCkg⏚ஹNaClO,åÝᧇᑴᜓC1OḄ᝞ZîᡠðZᑡ^_Ḅ`42A.XiᜧsñᙠḄ▢opᨵcrGOH-B.NCLḄòóCHḄòóᜧ4C.NaCK2¢ᡂC1O2¡õᓄöÏD.ᑴ÷3molCIO2ø{◤⌕0.5molNH4cl5ஹúNAåûüeýþXᦪḄ
ᑡḄA.36gᵫ35cl37clᡂḄᡠᦪ17NAB.5.6gC3H6CHḄᔠᱥᨵᐳᵨᵯ"Ḅᦪ#1.2NA24C.4moiSi-O$Ḅ%&ᓄấᨔ*&+ᦪ4,D.ᩩ/6.4g0123Ḅ45678ᵯᦪ#0.2N,ஹ6ஹXஹYஹZஹW:;<ᕜ>?@ᐗBX1ZC@Y1ZCᕜ>W<ᕜ>?@ᐗB+DEᨬᜧḄ,+ᨬ᜜Jᵯᦪ᪶᜜ᵯJᦪḄ3LYḄᨬMN1ᨬOPNḄQᦪ6஺ᑡḄA.YḄᨬMN&ᓄᱥ"6ḄSᓄᱥ%ᐗT⏚B.+DEVX

2C.ᙠ3CLO.lmolFeᐰ78ᵯᦪ#0.3NAD.ᘤ3moiH?1ImolN2ᐙᑖ56\¢ᡂNHᑖᦪ#NA9ஹ᪷¤ᑡ¥¦§¨ᡠy©Ḅª«Ḅ⌱⚗¥¦§¨¥¦ª«A®¯ᱏᑖ±ᢗᐭ³ஹ´µ⏚¶ὅ¸¹º§¨»ὅ56ᒓ½´µ⏚Ḅ&ᓄឋc³µ⏚ḄTB¾ᨵ¿À:ḄNa2cÂÃᐭBaCkÂÃÄ⁐ÆNa£03ÂÃÇᙠStÈ⊝CÊÂþ23ËSÌ¢Í⁐ÎÏÐÑÂtÒÂÃᨵMg"DmSᐭS02,ÓSÔ⁐SO,ᐹᨵÖÍឋA.AB.BC.CD.D10ஹᑡᨵᐵᨵqᱥᵬ~ÙÑḄTA.ᵬ\ÚÛ¢ᡂஹ&ᓄlQ56B.ÜḄᑖÝC6H6ckC.ÞḄQᱥᨵ2;D.Ùᙠᩩ/\Ú7ᓄᡂo;ßpàḄᱥ11ஹ¥¦áᵨSâYÑpᡂḄ¥¦A.ᑴᜓÜäB.åæ56C.Ü⏚ÜçḄᑴᜓD.èḄµᓄ5612ஹᑡÑḄA.z{éêëìᙠ¥¦áᙢ☢ᡈð☢ñ,òó\pᦈõö÷ᳮᜐᳮB.ËùúSNHJNH.,\ᵨᓄû&ᓄᡈᵯᓄû&ᓄᜐᳮC.üýþ¥¦ñᙠýÿ
ᐭ■஺᝞ᙠᓽᓾ⊡D.ᵨpHஹᵯ#᳛%&'()*+,#ᵯ-.Ḅ0ᘤ2ᙳ45)6⏚68Ḅ9:;<13ஹ=ᑡ?@ABCḄD&2

3A.6⏣Ḅ8ᓄHI8Ḅ9:HᙳJKLMHB.6N-O⏚ឋQ═⏚S+TU⁐DWX6NᑖZ[ᨵ]]^_C.6`ᑖZaXC2Ha22b4cdeᡂ6⏣D.ghi9jᔠHlm₩o9pq⁐rsDWXgho9etᡂH14ஹuvwxyḄ□᩽|&}⌕[ᨵCwTeLvḄ'(;᝞&TeCh+K9᧕+K⏚I2=ᑡᨵ஺ᐵ?@BCḄD2ஹH2s஺4H2s஺4Na2s஺3A.“ᓄ”XOCᐗᐙᑖᐭ*Ḅ⏚B.“”ᵨᑮḄᴻ0ᘤᑖTᧅஹஹᴻ¡C.ᑨ£vC¤¥Ḅ¦@L§*ᨬ'©¤ªTᐭBaCL+T«ᨵ¬⁐eᡂD.“cd”eḄZ¦;aX2so32-+Te4++4OlT=Tel+2so4*+2H2஺15ஹ®ᩝᾦD±⌕Ḅᩈᾦ³ᓄᔠᱥᐸ¶᪀¸a᝞¹ᡠ»஺=ᑡᨵᐵ®ᩝᾦḄ?@┯½ḄD&2A.ᑖZ¾¿gÀᜐKÂ'Ã☢B.ᑖZᨵ3¿Åឋ]dZC.-hÆÇ9eLMHD.1mol®ᩝᾦhNaOH+THᨬÈÉὑ3molNaOH16ஹᵯ:@ᜐᳮCO2ISO2jᔠÌÍÎḄdᳮ᝞=ᡠ»ᵯ:ÏXᰚÑ]⏚ÒI⏚ÒÓᵯ'ÔÕNiᵯ᩽⊤☢×ᡂØᩖḄ]Úp஺=ᑡ?@┯½ḄD

4CO2ISO2jᔠ.ÌÍÎA.Niᵯ᩽⊤☢etcdHB.□᩽Ḅᵯ᩽HX2O2--4e=O2C.ᵯ:ÏeḄZHᨵ2SO2+4O"=2SO42'D.Ü;Ýtᵯ:Ï]⏚ÒI⏚ÒḄÞ⊡ᐙßÀ17ஹ=ᑡ?@BCḄDCHOH2A.ᵞá`1HOHIℍ⃔äᙳJKᓫäæXÂçᱥOIOB.2,3,5,5-éᵬë-3,3-ì6ëíîḄ_ïaX0C.QðᱥIIfOCHKHmᙳDñðòᱥbóᨵᐳÂḄᓫõfOCH2CHO-C]K:D.ö÷ᱥÏḄ*XImolḄ9ᩰ⏚ஹ1,2-ìù6îICH3NHCOOCH3ḄjᔠᱥhNaOH+TᐙᑖHᨬÈ4Éὑ2molNaOH18ஹÝúûᑭᵨ6⏣ýᓄᓄ@ᑴLÿ
ḄᑡḄ19ஹᩰ᪛ḄZᐹᨵᦔḄᓄᝢ"Ḅ#ᑖ஺&'ᵨ᝞*+ᑴᜓ:

5ᑡ01┯3ḄA.41X+Y—Z*+567ᡂ*+B.Zᙠ:;4Ḅ<=>ᱥᨵ8@C.ZᡠᨵBCDE'Fᜐ6HZ[ᱥḄ\][CO(NH)],Cᳮ᝞_ᑡᨵᐵaWEbcḄ)22A.BLᵯdḄb᩽B.ᵯfghi▢᩽klmḄpHnᵯfopqrᓣtC.ᵯDuvḄVᔣB-xyzឋᵯ᩽|yzឋᵯ᩽

6A.°±ᓄ²'ᵨ6³PO´Ḅµ⏚B.ỚPO¸◤Ḅºᐗ]+¼〉º¾ᵨLC.ℍ⃔Á'ᵨ6Â"7Q³ᔠᡂℍ⃔Á⏚┛D.ÅÆḄᨵᦔᡂᑖCa(ClO)2ÇஹÈ⌱Ê⚪(ᐳ84ᑖ)23ஹ(14ᑖ)ᓄᔠᱥJ<@Í⌕ḄÏÐOᐸᔠᡂÒÓ᝞_:IIO.SÔÔÔ□ÔÖᑡ×⚪:(1)GØFÙḄÚÛ<ÜঞḄ*+®Þ(2)ß*+ঝ³*+ণâãäᐭéḄHᑖù᪀Og᪀ð¡(6)ᑏíúûéᵬ:Lý⌕Cᧇ(þÿᑺ
⌱)ᨬᑴᜓᔠᱥḄᔠᡂ24ஹ(12ᑖ)ᓄᔠᱥHᔠᡂᶭ⊈!ᱥḄ"#$%&'()⌶+ᔠᡂ,-.:জញ(34᧕67ᓄ)ঝᵬ3:;<=>?@ABCADE஺GH)ᑡJ⚪,(1)ᑏMᓄᔠᱥHḄᑖNO___________C"7QRSḄTU(2)ᑏMᨵᐵABDX,B-C;F-G஺

7(3)ᑏMATBḄABZ[O,.(4)ᑏM]^_`)ᑡᩩbDḄᡠᨵ]ᑖd᪀$Ḅf᪀gO,জR:;hiABঝR:;jkABjklᱥm?@1.621-78593Aᑖ72—112.8s—444.6³´µ%ᵨ᝞¶ᡠ{·¸ᑴᜓªSClo22(1)¹ᘤMḄTU<஺(2)³´µ"ᵨ»═⏚¾C¿À⏚ᑴ?CLḄᓄ~Z[O<஺(3)Á®ᑮÃÄÅḄS2CI2,¹ᘤ·¸ḄÆÇÈÉe-_Tf(ᢥ«$ËMZᔣ)஺D·¸"ÌÍᮞḄᵨ(4)S2cLÏÐ"%RÑᨵḄᩖ±<(Óᓄ~O)ÔS2a2ÏÐ"ÕÄS2cLḄÖZ×_(ÓÖTU)஺.(5)ØlᱥS2cL"Ñᐭªjᑣ:;ABḄᓄ~Z[O<஺(6)ÚÕÄÛḄlÐÜÝÞ,?mglÐßᐭ50mLjᐙᑖAB(SO2ᐰâ⍎M)'äåæçèéêåæoCäoᔠé,ᵨ100mLìªíÞì,?20.00mLnoC¿î0.4000m஺ïL"Ḅ=⏚hnoABðὑ=⏚hno20.00mL,

8ᑣDEFGᐗIḄ+KᑖᦪMN(ᵨPᨵmḄRS⊤U)஺26ஹ(10ᑖ)VᓄXᐶZ[\ᙠ^⚪7᪆Faᑮ“SO2cᐭBa(N(h)2:efg⁐ijklmMᙠ⏚ឋp᛻FkNO3rSO3"sᓄᡂSO’?•uD8ij”஺ᨵwXxyz7᪆{e|+ᶧk“mᨵ◞kl஺2sᓄ|SQF,NO3-ᐵ”஺;l|“SO2cᐭBa(NO3)2:”ḄkᵨpHᘤ?@Ḅk᝞஺ᑡ⚪(1)ᘤaḄ¡MN஺(2)[\¢fC£ᙠ¤¥k¤¥¦ᜐlN஺(3)ᵨO.lmol/LBaCL:ஹ0.1mol/LBa(NO3)2:ஹ¨ᵨ©kªᑴ4¬:(⊤)ᑖ®ᙠCF஺¯°জঝঞট·4¸ḄBaCL:·4¸ḄBa(NCh)2:»·4¸ḄBaCL:»·4¸ḄBa(NO)32µᑺ25mL,¹ºᐭ¨ᵨ©25mL,¹ºᐭ¨ᵨ25mL:25mL25mL©25mLx¼জஹঝ°µᑺkḄ½ḄlN஺(4)জ°ஹঞ°¾c¿Ḅ½ḄlN஺(5)fÀজ°ÁᯠÃÄkঝஹঞஹট°ᙳefÆÇ஺Èঝ°ACF?@ḄÉSÊËRM(6)1-4ᑖ®Mজkঝkঞkট°ᡠpHÍAÎḄÏᓄÐÑ஺

9᪷ó(ᦪó%®ᑮḄfõ<஺27ஹ12ᑖö÷øùúûᵨüᓄý
A1Pþÿᩔ
A1P⍗ᓽឋḄP%஺᪗ᱥPH,Ḅᶇ!"#$0.05mgk%&'ᔠ)஺*+,-.ᵨ᝞1ᡠ345678ᳮ:*᪵<=ᓄᱥḄᶇ!஺C?ᐭ100gE?ᐭ20.00mL2.50xK-4mo]L-iKMn04ABḄH2sCh⏚ᓄC?ᐭD!ᐙᑖGHIᵨJK⏚L᪗ABMEḄAB஺
267BN6ᯖឋPQ⏚ḄRឋABᔾᦈUḄ02஺VWᣵY67,ᑣ:\ḄᓄᱥḄᶇ!_^“`a”“`c”ᡈ""f,'஺
367EP%hᓄᡂ⏚MnOjkl'MM+,ᑏnYGHḄoQpqrs஺
4ᦈt67EḄᔾᦈB?uvw250mL,!xᐸḄ25.00mLz┵|}ᵨ4.0x05moiL”ḄNa2sCh᪗ABM~ὑNa2sCh᪗AB20.00mL,GHᳮS02-+Mn0j+H+TS04'+Mn2++H20
$ᑨY᪵<ᔲᔠ)ᑏn$qO28ஹ14ᑖᐸᓄᔠᱥᙠஹᨵHᵨ஺

10(1)ÒÓS᪶᜜ᨵ¬Ö×Ø᝱¤wḄᵯSkFe3+Û᝱᪶᜜ᵯS᣸ÝRMo(2)ÞßᵨK3[Fe(CN)6]Fe?+,[Fe(CN)6TFà¬ᐗIᵯáឋᵫᜧᑮ[ḄäåM(ᵨᐗIæ°⊤U)kCN-F஺çᐔçḄᦪ½¼nযn(7r)=;HCNFCÓSê⍝ḄᩖᓄíîM°HCNḄ41M25.7C,ïðᜧ;N2Ḅ41(-195.8C)ᜧ;HCIḄ41(-85C)ḄÓml஺(3)FeCbFḄᓄXçᐹᨵòóḄᐳõឋkö÷Ø᝱øùúᑖS(Fe2c16)£ᙠkûùúᑖSḄü᪀RM,ᐸFFeḄªÿᦪ
»•MiJLFeOMiJLFe▲N(4)ᓄᔠᱥ(Fe4N)ᙠᩞᧇ⚞ᨵḼḄᵨᐸᨔ᝞ᡠ!஺#ᨔ$ᦪ
ᓫ&'()*Ḅᙶ᪗-.#⊤!ᨔ0ᔜ23Ḅ&45623ᑖᦪᙶ᪗8᝞0b&4Fe23Ḅᙶ᪗
(0,!!)ஹ(!0,!)222=(L,—»0),ᑣa&4Fe23=N23Ḅᙶ᪗ᑖ?
ஹ஺N@Fe23ABᨬDEFapm஺22GHIJKLMᦪḄN
N,\,ᑣOᓄᔠᱥḄP(Qg©n-3(ᑡTUV⊤WX)஺29ஹ(10ᑖ)Y⏚[\0]^ḄN0Q_`ᜧbcdᱥ.#ef᝞ghᜐᳮk2N0(g)+2C0(g);=iN(g)+2C0(g)l22mHi஺(1)nok2CO(g)+O(g)=2CO(g)lmH=-566kJ•mol-1,N?(g)+no)2N0(g)lmH=+181kJ•mol-1,ᑣ2223mHp___________(2)ᙠ_rs(gᔣuv
2LḄPwxᘤ0ᐙᐭ4molNOஹ2molCO஺জ}
ឤxPwxᘤᙠlOminWᑮ⊝᝱,
2ᩭḄ14/15,Bᑁ,N0Ḅᙳh᳛
,⊝Mᦪ
Lmol-1,NOḄᓄ᳛a%⊝ᔣឤxPwxᘤ0ᐙᐭ2molNOஹ1molCO,Wᑮ⊝NOḄᓄ᳛(“ᜧ”ஹ“”ᡈ“”)lঝ}
ឤPwxᘤ⊝N0Ḅᓄ᳛
b%,¡Ja%b%(“<”ஹ"=”ᡈ>”)(3)[\N0@C0¦ᔠbu#_r§=_rḄ¨8efᐙᨵAஹB©ᓄᑺḄhᘤᙠAஹB«`©ᓄᑺ6ᵨgC0ᓄ᳛@s(Ḅᐵ-᝞gᡠ!஺

11জ[\⌱®©ᓄᑺ(“A”ᡈ"B),ᳮᵫQ»ঝᙠ©ᓄᑺB6ᵨg°±550KC0ᓄ᳛g²Ḅᳮᵫ.³Qὃᫀ_ஹ⌱®⚪(ᐳᒹ·22¸⚪஺¹⚪ᙳºᨵ_¸»ᔠ⚪¼Ḅ⌱⚗)1ஹCூ᪆௃A.10mLO.lmol-LFNa2cO3¾¿⌲ÁÁJᑮ10mlLO.lmol-L-1Â⏚0ÃÄ]^ÅÆᓄÇbuÁJÈÂ⏚ÈᐰhÇ⏚ÊfËᡠ#ÌᑮÇ⏚Ê=ÍᓄÊḄ¦ᔠᱥᡠ#F3Î(ᜧ
kc(Na+)>c(CÏ)>c(CO32-)>c(HCO3-),AÐÑlB.ᵫ±K(CH3COOH)>K(HClO),CRTÒÓÔ(ᜧ±CKhCCXTÒÓÔ(«`¾¿0Ḅ▢F3ḄᱥÖḄËÎ(A=:aaঝுজBÐÑC.ᔣ0.1mol/LNH4cl¾¿0NH4++HO^NHyHO+H+,JᐭÙËNH4clÚuNH+,NH4+ÒÓ⊝Ðᔣ224cNHkc")ÛÜc(NHyHO),c(H+),ÒÓMᦪᓽ,NH4+ÒÓÔ(,,2.0éH)c(NHk)c(NHk)c(NHk)ᜧ,C┯ç;■ãä2)c(C)D.ê
Kp(AgCl)>K(AgBr),ᙠAgCl=AgBr«⛳=¾¿0ὅc(Ag+)ᜧ±ὅc(Ag+),c(Cr)>c(Br),íAgCkSspAgBr«⛳=¾¿¦ᔠî^ïðḄᓄ^ᡂòóḄAgBrïð@ô¾¿0c(C1)¨2ᩭAgCl⛳=¾¿0ᜧíJᐭõËḄÎAgN(h¾¿AgBrïðᨵᡠóöAgClïðJòóDÐÑlᦑøᫀ
kC஺ூûü௃

12⏚⌲MM?Na2cChAB&&"hᓄḼ⏚$!¡hᓄᐸGHpqr'sNa2CO+HCl=NaHCO3+NaClNaHCO3+HCl=NaCl+HO+CO2t;322ஹDூ£᪆௃A.¦§¨ᑴ◌«Ḅ$q◤⌕a®?¯⌲°W◀²ᨵ³ᱥ´³ᱥµ¶·¸GHᡂ²¹ᱥº»²ᓄ.fᓄᦑA½¾¿B.ÀÁÂÃᵫ☘Æᑴᡂ☘ÆÇᨵÆᐗÉஹ┱ᐗÉஹËᐗÉÌÍzᔠÎᦑB½¾¿C.ÏÐᑴRÑḄ“R”ᢣḄÓRᓽ⏚LᦑC½¾¿D.☘ÔÉḄ·ÕᑖQº!Ö+"Ízᨵ³aᑖQᓄᔠᱥᦑD┯Ø¿ᦑ⌱D஺ூÚÛ௃ᨵ³aᑖQᓄᔠᱥᵫᓟÝÞßàáᐳãäåᔠ|ᡂ·ÕᑖQº!ᱯçᜧஹᐹᨵêëå᪀ᓫᐗḄᨵ³ᓄᔠᱥÍzîᔠᱥ஺kïð·ÕᑖQº!az10000ḄᑖQñ'aᑖQ஺3ஹCூ£᪆௃A.-òóḄôõkᐗ⏚ö÷ᵯឋ45CHjCOOHABÕHḄùúÖᨩᵯonḄoQòó+ᡠü⏚'ý⏚A½¾¿B.Æᙠ⏚ឋᩩ
⏚᪷ᓄ⏚᪷ᓄ⍗ᑮ⁐ᓄ!ᨵNO3,B#$%C.&'(⁐Ḅ*ᡈᓄ,ᑣ.NaClO/0.⏚123ᡂ*5Na2sChᡈNaHSCh/0.⏚123ᡂᓄ,C┯7%D.8ᵯ:;Ḅ<=>?@ᐭBCD>E᧕3ᡂGHIJKKsp[Mg(OH)2]>Ksp[Cu(OH)2]LMD#$஺#$⌱⚗Co4ஹBூ:᪆௃ᵯ:ᵫᑴᜓXYZ*ᓄ[/.⏚Ḅ\ᔠᵯ:D^3NH4a+2HC1—3H2T+NCI3,ᯠ`@a*⏚b^36NaClO2+NCh+3HO=6ClO2t+NH3t+3NaCl+3NaOH,c!!X!NaOHஹNaChIᩭ:g஺2ூh:௃A.NaCKh/NCb^3ᓄ12ᵫiᨵBj3ᡠI12ᱥmᯠᨵH2On@ᡠI12oYp

136NaClO2+NCb+3H2O=6ClO2T+NH3f+3NaCl+3NaOH,ᡠIᜧrsᙠḄ▢ᨵCLvOHᦑA#$%B.NஹCᙳsp3ᩖᓄNCbᑖᨵ1{|ᵯ{ᵬ~ᑖᨵ|ᵯ{|{ᵯ/ᡂᵯ{᣸ᜧiᡂᵯ{Ḅ᣸ᦑNCLḄḄ?iCH4ḄᦑB┯7%C.NaCKhᡂC1O2,NaCKh*ᐗᓄᔠ+3ᓣ+4^3ᓄ12ᦑC#$%ᵯ:D.ᵫ12NH4a+21^1=^^=3H2f+NCbஹ6NaClO2+NCb+3H2O=6ClO2T+NH3T+3NaCl+3NaOHZᑴ3moicKh◤⌕OSmoINHCLᦑD#$%ᦑ⌱B.ூ௃|{ᵯ/ᡂᵯ{᣸ᜧiᡂᵯ{Ḅ᣸஺5ஹBூ᪆௃A.35clv37clḄᦪᐵᑣ36g*0.5mol,ᡠ!;ᦪ17NA,A#$%B.5.6gC3H6v5.6gC2H4!ᨵᐳᵨᵯ{Ḅᦪ¡L2Nஹ,ᑣ5.6g\ᔠᡠ!ᐳᵨᵯ{ᦪ51.2Nஹ,B#$%C.1“SiCh”!ᨵ4Si-Oᑣ!4moiSi-OḄᓄấᨔImoLᦪ2NA,B#$%D./¤rḄ,123ᡂCinS,6.4g¥¦ᵯᦪO.INA,D#$%ᦑ⌱B஺6ஹDூ᪆௃XஹYஹZஹW§¨©ᕜ«¬ᐗY/Z®ᕜ«W©ᕜ«¬ᐗ¯°ᨬᜧḄᑣWNa,Xᨬ᜜³ᵯᦪ᪶᜜ᵯ³ᦪḄ3µᑣXO,X/Z®ᑣZS,YḄᨬ#/ᨬ¶·Ḅ¸ᦪv6,ᑣYC1஺A.YḄᨬᓄᱥ{2ḄCᓄᱥHCIO,ᐗ¹⏚⌱⚗A┯7%B.¯°:X(O)¹᝱ÀᓄᱥḄÁឋ>¹»¼½ឋY(CI)>Z(S),ᦑ᝱ÀᓄᱥḄÂÁឋHC1>HS,⌱⚗C2┯7%D.X/WÃᡂĨ▢ஹ□Ḅᱥ;ḄrÆᙳ12ḄᓄᔠᱥNazOvNa2(h,⌱⚗D#$஺gᫀ⌱Do7ஹCூ᪆௃

14A.ÈᐗᙠÉCIᓄᔠ᝱sᙠÊBrᐗᵫᓄᔠ᝱¥ᓄË᝱D^3ᵯ¥¦ᡠI^3ᓄ123ᡂÌᓫ;`ᵨᨵÎᱥÏÐ⃓ᦑA┯7%B.b᧕/C12ᵯ:⛳vÓ.CJᑮÀᓄbஹ*vÀᡠI2ᵨᵯ:ᰚÕḄ*ᓄbḄoÖ×ØbᦑB┯7%C.ÉC᧼.ᑭᵨÛ^ᳮÛ^᪷Ýᱥ;ḄÞ®ÏÐᑖḄßàᱥᳮᓄᦑC#$%D.@ᐭ¤rḄ*ÊLᓄᡂáḄᓄᔠᱥ,ãỚḄj᳛ᦑD┯7gᫀ⌱C஺8ஹCூ᪆௃A.᪗çèé
H2O2Ḅè᝱᝱&ᵨ᥅ë=A┯7%B.25࠷,lLpH=13ḄBa(OH)2Ḅc(OH)=0.1mol/L,n(OH)=0.1mol/LxlL=0.1mol,ᦑOITḄᦪ0.1NA,B┯7%C.CLᐹᨵ¹Ḅᓄឋíʼ½Feᓄ+3ᡠIO.lmolFeîᐰðñ¥¦ᵯᦪ0.3N,ஹC#$%D.N2/ᕜᔠᡂBḄ12⌮12ᡠIóôEᘤ3molH,/1molN,ᐙᑖ123ᡂNHᑖᦪ?iN,3AD┯7%ᦑᔠᳮ⌱⚗C«9ஹBூ᪆௃A.÷ὅ^3ùᓄ123ᡂúóᓄↈüýþ12ÏÐᦑ┯7%B.CO2+HOHCOa+OH-,ÿᐭ
ᲩᐭBa?+,Ba?+C(V-ᡂBaCCh,⊝32ᔣ⌮ᔣ⁐ᦑC.!"ᨵAP+,$%&'ᓄ)*+,-ᦑ┯/D.0Br2+SO2+2H2O=H2so4+2HBr,12SO2Ḅ45ឋᦑ┯/஺ᦑ⌱B஺10ஹBூ᪆௃A.ᱥ;ᵬ=">?@ABC0>?ḄᡂDE(G+'ᓄ)C0Iᓄ(G+JK),AB.᪷NOP᪀RSTUᱥ;V>ᑖX=YZH5Xᐰ\]C15XJK^Ḅᱥ;ᦑᑖXSVC6a6,B┯/C._ᑖX="ᨵ2`abḄH5XᡠCᐸefKᱥᨵ2`CD.gᑖX="ᨵhBஹ⏣jBᙠelᩩnohB&pCqᓄᡂjBrsᑮu"⏣jBe`v!wḄᱥ;D

15ᦑyᫀ⌱B஺11ஹAூ|᪆௃O⏣ᙠ170C0ᡂOCᩭ|y஺ூ|௃BஹCஹD=ᙳ◤⌕uᨵA=O⏣ᙠ170c0ᡂO*!ᡂᦑ⌱A஺12ஹAூ|᪆௃A.Geᙠᙢ☢ᡈ☢ᜐᳮG*!ᜐᳮ᧕¢£¤¥@ᙢoᦑA┯/;B.§¨©=N%-3ªᑭᵨ'ᓄ455ᳮ0'ᓄqᓄ%®ᱥ;ᡠCᵨᓄ¯'ᓄ°ᡈᵯᓄ¯'ᓄ°ᜐᳮᦑBC.²³´³✂E¶=·¸ᐭ¹º◤⌕»¼½ᓾ¿⊡ᦑCD.O⏚OI|ᡂO⏚@O⏣uᨵO⏚%ᵯ|;O⏚ᵯÂÃ⏚ឋᑣO⏚ÅÆÇᜧ⏚ឋÇÉÊᵯ!ËÌÇÉᡠCᵨpHÍஹᵯÊ᳛ÏÐe`ÑÒÊᵯ!ËḄÏᘤÔᙳÕÑO⏚OIḄ|ÖÆᦑDᦑyᫀ%A஺13ஹDூ|᪆௃A.O⏣ḄIᓄ@IḄ|×ØÙVᨵÚᱥᑖX=Ḅ5Xᡈ5Xw]ᐸÛḄ5X@5XwᡠKÜḄVJKᦑA*⌱B.O!Ý⏚ឋÞß⏚àá⁐V$%OᑖX="ᨵââãäC]⏚ឋÞå⏚à'ᓄᦑB*⌱஺C.OhḄP᪀RS%CH3CHO,ᑖXS%C2HæC@&p0ᡂᓽ45ᡂO⏣ᦑC*⌱D.>èéᔠëì₩èî⁐V$%ï=Ḅïð=ᐭᑮñ>=V⃓J*V>@ó0ñᡂᦑD⌱஺ᦑ⌱D஺14ஹCூ|᪆௃A.ð□᩽ö=÷JøùeúVûTeᐗýqᓄ%TeChḄþÿᩭὃ⇋ᑮTeCh᧕⏚ᡠᓄ⏚A┯B.◤⌕"ᧅ$%ᑖ'"ᧅB┯C.(ᑖ᪆᦮+,-.ᨬ01ᑮḄ3456⊤☢9ᔾ▬'ḄSO,<=ᑨ?@ABᔲD◤⌕EFᨬGH

16þÿ
ᔲᨵSOᓽC;D.⏚TeO2Na2s03Te(hᡂTeᓫSOᡂS0ᡠḄ!"#$%:2SO+TeC)2=2SOj+TeJ,Te(h'ᓄᱥ!"#$*+,ᑖD┯/஺1ᫀ⌱C஺15ஹAூ᪆௃A.ᑖ!56789ᙠ;☢=>᪀Ḅ@!A*+ᜐCDEF☢ᦑA┯/;0B.H°H*᪗KḄL6@!Mឋ@!ᦑB;(PᩝᾦS)ஹ*\)(:VOHC.WXYḄZ[\+]^_`abcdeᦑCfD.lmolPᩝᾦS]NaOH
deᨬhiὑ3molNaOH,ᑖklYiὑImol,26WXYᔜiὑImol,ᦑDfᦑ⌱A஺16ஹCூ᪆௃ᵫHoNiᵯ᩽⊤☢asSCV-uᓄ%S,C(V-uᓄ%CḄde%defSnOᵯ᩽Aas20?—ߟ4e=()2T,2%'ᓄdeᡠNiᵯ᩽%▢᩽SnChᵯ᩽%□᩽xyᑖ᪆1஺ூ௃A.ᵫH{ᳮoNiᵯ᩽⊤☢asdeᦑAfB.□᩽aᜫᵯ!Ḅ'ᓄdeᵯ᩽de%~ᦑBfC.ᵯaḄ!deᨵ~2so2+O2+2O2-=2SO42—CO2+O*=CO32-ᦑC┯/fD.#ᙠSO4?ECO3?•ḄD*ᡂSO4?-CO3%ᡠsᵯ@⏚⏚Ḅ⊡ᐙ8ᦑD஺ᦑ1ᫀ⌱Co17ஹDூ᪆௃A.ᵞ*Cᓫᦑ┯/;B.$%Ḅ%2,2,4,5-;ᵬY-3,3-Yᦑ┯/;

17oC.JKᱥIḄᓫ6NO⏚PQ⏣$fOCHKHᱏḄᓫ6%PQ⏣ᦑUᨵᐳXḄᓫ6ᦑ┯fOCHjCftO-CjsD.Yᩰ⏚[ᨵ\]^_]1molḄYᩰ⏚`ὑ2molbᓄc1molḄ1,2-QdPe`ὑ2molbᓄcCH3NHCOOCH3[ᨵf]ghᡠ1molḄCH3NHCOOCH3`ὑ2molbᓄcijᱥkḄN1mollmᱥkḄnᔠᱥBNaOH'ᐙᑖqrᨬs`ὑ2moiNaOH,ᦑtu஺ᦑ⌱D஺18ஹCூ᪆௃P⏣yᓄᓄzᡂP|Y}2cH3cH2OH+O2ߟMS—»2CHCHO+HO,~ᔠᐵᑖ᪆32ூ#௃Aஹᑖ1ᑮP|ᵨ✂✂⌕ᵨᑮᦑA⌱BஹB%P⏣ḄyᓄᓄᦑB⌱CஹP|ᵨᑖ'ᦑᵨᑮᑖ'"ᧅC⌱DஹP|⌕ᵨᑮᦑD⌱ᦑ⌱C஺19ஹBூ᪆௃A.ᵫᱥkḄ~᪀.}^_]CHh?BPzᡂqrAtuB.ᵫZ~᪀.Zᑖᙠᨵ6mXḄHᡠZḄḄHdᱥᨵ6mB┯C.Zᑖ[ᨵ⛳CᵫB⛳O¢£ḄC᪀ᡂḄ%¤☢6~᪀ᡠ¥ᡠᨵOᜐXH§☢CtuD.Yᑖ[ᨵ⛳ḄOO¨h<=NKqrḄᓫ6Dtu}ᦑᔠᳮ⌱⚗%B஺20ஹAூ᪆௃᪷¬qruNᵯ¯°±²ᵯ᩽H1ᵯᓄᔠ´µ¶z·qrN▢᩽¹²ᵯ᩽N□᩽□᩽»qrN6c¼-6e=3C12tஹCO(NH)+3Cl+H0=N+C0+6HCl,▢᩽qrN2HzO+ZekH2f+20H-,ᵯ¾¿᩽,ᔣ▢222222᩽ஹ□᩽,ᔣt᩽ூ#௃A.(ᑖ᪆.BNᵯÁḄ¿᩽A┯B.ᵯ¯-▢᩽qrN2HzO+2e-=H2t+2OH-,'b᪷ÂÃÄᜧ'ḄpHÄᜧᡠᵯ¯~ÆG

18▢᩽»'ḄpHBᵯ¯ÇÈiᓣJBtuC.ᵯ¾¿᩽,ᔣ▢᩽ஹ□᩽,ᔣt᩽ᡠᵯÊËḄÌᔣ%B-±ÍÎឋᵯ᩽ஹ¹ÍÎឋᵯ᩽-A,CtuD.(ᑖ᪆.□᩽»zḄqrÐÑN2c¼-2e-=CbtஹCO(NH)+3Cl+HON2+C0+6HCl,Dtu22222ÒᫀNA஺21ஹBூ¯᪆௃A.^Ḅ⏚ឋÈO⏚Ö᪷¬×Ø.¹²ÙᐭḄ%JÂÃḄ^'⍎ḄÜ6ᨵCO2,ÝÞqrG'Ḅ⏚ឋÄpHßàAtuB.᪷¬×Ø.ᙠ±²NOyá1ᵯz·qrâ·ãNN2⍎ᡠ±²ᵯ᩽Nt᩽ᵯ°äå▢ᔣ¿᩽ÊË□ᔣt᩽ÊËᡠäåæ»ḄC1HÊᔣ¹»Na+Êᔣ±»ᡠ±²N□çᣚéB┯C.᪷¬BḄᑖ᪆.±°ᵯ᩽Nt᩽z·qrᵯ᩽qr}2NO3-+10e-+12H+=N2T+6H20,CtuD.ᙠ¹»zqr}CHOH+llH2O-28e=6CO2+28H+,᪷¬ᵯ᩽qr.êᨵImol^qrëÊ28moiᵯ,6528qrízN2ḄᱥkḄ%n(N2)=mmol=2.8mol,ᑣï`ὑO.lmolC6H6஺i9íz0.28molðÜDtuᦑᔠᳮ⌱⚗%Bo22ஹBூ¯᪆௃A.ñ⏚Ḅò⌕ᡂᑖNHCLA1(OH)3BHCIqróᑮsñ⏚ḄôḄtuA⌱B.Ớᐗ÷%ø6ù◤úᐗ÷¥᤬ᐭs$üúᐗ÷ỚᵨýþKb-ᡈ⊡ᐙLᨵᵨ┯B⌱C.ℍ⃔ᑺᵨℍ⃔ᓄᡂℍ⃔⏚$%&ᵨ'ᑴᜓ⊡┛ᑺℍ⃔⏚┛+,C⌱D.-./0Ca(ClO”1CaCL,ᐸ3ᨵᦔᡂᑖCa(ClO”ᐹᨵ7ᓄឋ9ᓄᨵ⁐ᱥ<=ᑮ-.Ḅ@ᵨ+,,D⌱஺Cᫀ⌱B஺EஹG⌱H⚪(ᐳ84ᑖ)COOH23ஹMNஹOP(ᡈ⏒SP)UVWXYZCOOH°COOH°CH,X^NHCCH«NH+CH3COOH+H2SO4fjnᡈᑁ(\ᑏ1^)+2H2OCXA-GaHOUNH?HOUN஻°HOCI

19CHjCOOIICOOII0||©3஺3஺HF஺_NO

20CHOCH,¯ÁZy}ᑖ᪀i᪀klஹᡈc(\ᑏ1^);Ho©ªNH2H0©«N஻(6)ᐜᵨ⏚ឋ⏚ᵬNᓄMNᯠ%ᵨ“Fe/HCl”N{NᑮNᵬ⏚ᯠ%ᙠᓄᑺ@ᵨ¡¢£¤¥WX£ᡂ0OPḄ¥ᔠᱥᐜÄN{Nᯠ%ÅᓄᵬNÆNᨵ{ឋÇ᧕QHªᓄᦑᔠᡂÉÊ᝞¡:¬ᓄᑺH„+C.II-I.ᡈ•±ᩩ³.°-G/24ஹCIHNO⏚P{WXÍÎWX215ூ᪆௃஺1,B°FeஹHa¢£{WXÑ£CA,A°ÏHNChஹÏH2s04Т£UVWXÑ£BIC°(CH3CO)2O¢£UVWXÑ£D,E:,E°NaBH4¢£WXÑ£FNHCOCH,NHCOCH,NHCOCH~ூ#௃(1)᪷eHḄi᪀kltᐸᑖ|lCHNOCi᪀kl,ᐸ30§Ḅ¨⏚P;I2I5ফB,B°FeஹHCIWXÑ£C,WX¬{WX;,G,᪷eEὅi᪀Ḅt·FTGḄ¬ÍÎWX;NHCOCH,

21বA,A°ÏHNChஹÏH2sChТ£UVWXÑ£Bᡠ&A->BḄWX¹gl:NO2+HNCHÏÔNO~(4)Di᪀kl:,DḄᑖ᪀Õᔠ¡ᑡᩩØ·জ¢£ÚÛWXÜÝ0ᨵÞN-CHONHCOCH,ঝ¢£ßaWXßaÑᱥ$w°FeChWXàá⁐ÜÝ0ᨵâNßaÑᱥ0ᨵãäNᓽᱥ<0ãäNåᡂḄâN;ঞ᪶çᐳè³éH-NMR)à¶ᑖ|3ᨵ4^ᓄêº᛻Ḅ³ᑣÕᔠ⚪ìḄᑖ᪀i᪀kl:(5)ᔠᡂ⌶î3CmᓄDwNH2¢£WXÑ£-NHCOCH3,%ᩭmᓄNḄðñN■óᐸᙠᔠᡂgªᓄ;(6)ô᯿}öᔠᡂÉÊ&ᵬ1(CH3co)2஺{ᧇøùᑴᜓḄᔠᡂÉÊ஺ᵬ✌ᐜª⏚ឋKMnO4COOIIᓄᵬ⏚6ᵬ⏚°Ï⏚ஹÏû⏚üᔠТ£UVWXÑ£ÁNᵬCOOIIACOOH,\°(CH3c0)2ᙠÐᩩØ¡¢£UVWXÑ£HC1@ᵨ¡WXÑ£ᡠ&ᵬmᓄkJl-NHCOCII,ூþÿ௃
⚪ὃᨵᱥḄᔠᡂḄᨵஹ᪀ឋஹ▲ᑴᩩ"#ᑖ%᪀&'ᑏᙠ*+ᱥḄ,-.⌕ᐙᑖᑭᵨ⚪345ᔠ6ᨵḄᑖ᪆ஹᑨ⌕9:;<=᧕?@ᓄB■DᐸᙠFᓄ,-.@ᓄᐜHᐸIᑮKLᙠᐸM<NᡂOPQᐸRSTᩭ஺25ஹᙊXYZ2KMnC\+16HCl\]´=2KCl+2MnCL+5C12T+8H2஺jkhicdabᔾᦈᒕaḄbcd

22■¶·¸Ḅ`¹¸ºᐭ¼½B¾S2cL`CLஹSCLஹSᑖ✂(ᡈ¹À).,1421422S,C1,+2H,O=SO,6+3SJ+4HC1—%ᡈ^mmூ᪆௃(1)᪷x¼½Hᑖ᪆ÄᘤMḄf(2)Æ═⏚È]^⏚ᙠÉÊËᡂÌᓄÈஹÌᓄ═ஹ̸`f(3)ÍÎᑮÐÑÒḄS2a2,̸ᐜ◀ᩖஹÖ×Ø]ᰚÚḄSdeᵨÜ`ᦈÞS2CI2,ᨬᵨßàᮞᦈÞhâ̸Kãä¸åæºçèf(4)᪷xS2CI2ஹSCLஹSஹCLḄéêÐëᑖ᪆f(5)S2cL`aìᓄdeᡂSO2ஹSஹHC1(6)í±#deḄ!"#$Ag++Cî=AgClJ஺ூ௃(1)᪷x¼½HÄᘤMḄᙊñòóf(2)Æ═⏚È]^⏚ᙠÉÊËᡂÌᓄÈஹÌᓄ═ஹ̸`ᓄô"#$%2KMnO+16HC1(^)=2KC1+2MnCl+5C1T+8HOf4222(3)ÍÎᑮÐÑÒḄS2CI2,̸ᐜ◀ᩖஹÖ×Ø]ᰚÚḄSdeᵨÜ`ᦈÞS2CI2,ᨬᵨßàᮞᦈÞ̸fAõÄᘤ¼½Ḅ9ö÷ø%e-j-k-h-iTC-d-a-bTf஺S2a2᧕`ᡠD¼½ßàᮞḄúᵨᔾᦈᒕâḄ̸ý■¶·¸Ḅ`¹¸ºᐭ¼½B¾S2a2`f(4)̸+ᨵᒕâᙳᨵ+ÿᐭ
ᡂSC1S2CI2ᨵḄᩖSCLஹ2,sஹci᪷s2a2ஹscLஹsஹCLḄs2cLs2chḄ!"#$%&(ᡈᑖ&)+2(5)S2cL,-./ᓄ12ᡂSO2ஹSஹHC1,᪷3ᜫᵯ67ឤ9:12;<2s2cL+2H=஺=SO,T+3SJ+4HC1+(6)@AB12ḄC6#B;Ag++C1=AgClJ,ᑣ20.00mLEFC6ḄᱥḄ,JKL£-OAAHPQR8moix35.5g/molx^^142..0.4moH/ix0.02L=0.008moL
ᐔTḄᑖᦪ<_______________20W00%=—%+mg11126ஹ┵YZ[\CḄEF]^_`abcᔲcᓄSO3*᣸◀[\ᑁḄ^■icj᡾2SO+O2+2HO=4H++2SO42-஺lஹNChmcᓄcᓄSCh",cḄcᓄᦔopNOyqrᙠcஹNChtuᩩ22wxcᓄy᳛q{஺ூ᪆௃

23(1)᪷[\|ᑨ~ᘤaḄ+(2)⌕“O?cᓄSO3i,]NCh-ᐵ”◤ᙠcᩩwxSO2ᐭBa(NCh)2EF஺(3)জஹঝᑺḄজEFcஹঝᑺEᨵc஺(4)জஹঞᑺḄᐳc᛻জEF⏚᪷C6ஹঞᑺᨵ⏚᪷C6+(5)¡জ¢ᯠ¤¥ঝ¦§¨©ªO?SO.*-cᓄ0.05mg,ᡠÂᔠÑூµ᪆௃পKMnO4EFᨵÒcᓄឋP%ᨵÒÈÉឋ+(2)ccᓄÓÔᑖP&,@AÕὑḄ×Ø⏚Ù᪗ÛEFÍÜᑣÌ3ḄÝᓄᱥḄÞᶇÍÎ+(3)ᵫ3ᜫᵯ67ឤஹÉ67ឤஹᵯ₹7ឤᑏ¦ãäḄᓄå#B;+(4)ᐜçèNa2s03᪗ÛEFÕὑḄé═⏚ëḄᱥḄìᵫé═⏚ëíḄᱥḄ«îNa2s03᪗ÛEFÕὑḄé═⏚ëḄᱥḄï¦ᔾᦈP%ÕὑḄé═⏚ëḄᱥḄðï¦ñòÝᱥ(ÂPH3ç)ḄÞᶇ஺ூ´µ௃(l)KMnO4EFᨵÒcᓄឋPH3ᨵÒÈÉឋ[\AḄKMnChEFḄ"ᵨᔾᦈ^ḄÈÉឋÊ■iᐸ

243᡾PH3Ḅfg;ফjkB.ljᯖឋnop⏚Ḅrឋstᔾᦈuc.Ḅ02,vwᣵyjk@cz@ᓄ{|ᑖPH3,}~ᒕḄKMnO4gὑḄ⏚᪗stᑣfIḄᓄᱥḄᶇ(3)jkE.P%@ᓄᡂ⏚MnO/?RSBMi?+,ᵫIᜫᵯpឤஹSpឤஹᵯ₹ឤyḄp-B5PH3+8MnOj+24H+=5H3Po4+8Mn2++12H2O(4)gḄSᳮ5SO2+2MnO+16H+=5SO2+2Mn2++8HO,Na2s(h᪗stὑḄ⏚¡ḄᱥḄ3442c஺ீ¤I=0.02Lx4.0xlormol/Lx-x--------=3.2xIQ-6mol»ᑣᔾᦈPHὑḄ┶⏚¡ḄᱥḄ3525.00mL=0.02Lx2.50xlO-4mol«L-'-3.2x1O_6mol=l.8x1O_6mol,PH3ḄᱥḄ=1.8xl(T6moix*=LIZSxlOfmol஺¦o8,,ஹ¨wee1.125xl0-f>wo/x34g/wo/xlO3,,,.ᱥ(¬PH3)Ḅᶇ=-------------------------------=0.3825mg»kg',0.3825mg»kg'>0.05mg«kg',ᡠ¬²0.1kgᔠ³஺28ஹ26[Ar]3d5ᡈIs22s22P63s23P63d5N>C>Fe1;2spᩖᓄHCNB᩽ឋᑖp·ᑖp¸¹ᙠº»aஹ111119¼N2B½᩽ឋᑖpHC1ᑖp¸¾º»Fy4(0,0,0)(-,-)JT^xlO30cra222AaூÀ᪆௃(1)Sp᪶᜜ᨵᵯpùᙠ²#ÄÅÆ᝱Ḅᵯp᪷ÉFeSpᜫwᨬ᜜Ë2ÌᵯpPᜫwÍ᜜Ë1ÌᵯpÃIᑮFe3+,᪷É᪀⌼Sᳮ'ᑏᐸ᪶᜜ᵯp᣸Ð(2)½ÑÒᐗÔḄᵯÕឋᜧ×ÑÒᐗÔᐗÔḄ½ÑÒឋØÙᐸᵯÕឋÃØᜧᐳÛÜ».Ýᨵ1Ì0»2Ìk»;᪷ÉHCN.CSpNᡂḄÛËᵯpßᦪáᑨCSpᩖᓄâ⍝᪷ÉᑖpḄ᩽ឋᑖp¸º»Ḅ¹ᙠᔲåᑖp¸æᵨçᜧèᑨᱥᰚêëḄ(3)᪷ÉFeSpᐹᨵuâ⍝¼CISpᐹᨵíᵯpßNᡂîï»ᑖ᪆(4)᪷ÉSpḄðßïk6ëḄᙶ᪗ògᙶ᪗Sëó¼ògaïkFeSpåNSpḄᙶ᪗ᑭᵨᙳõö÷{Ìᨔù.ÝᨵḄᔜûᐗÔḄSpÌᦪᑭᵨᱏ:÷ᐸþÿ஺ூ௃(l)Fe26ᐗᵫᙠᙠ᝱ᐰḄᵯᡠFe᪶᜜ᨵ26#᝱Ḅᵯ஺᪷%᪀⌼ᳮ)*+᝱Fe᪶᜜ᵯ᣸-.Is22s22P63s23P/(164s2,Feᜫ2ᨬ᜜424sᵯ56ᜫ27᜜43d8Ḅ1ᵯ9*ᑮFe3+,;Is22s22P63s23P63<15ᡈ@ᑏ>[Ar]3d)(2)ᙠ[Fe(CN)6]3-ᙠFeஹCஹNC#ᐗᵫᐗḄDEFឋHIᐸᵯKឋHᜧDEFᐗḄᵯKឋᜧEFᐗᦑNC#ᐗḄᵯKឋᵫᜧᑮOḄPQN>C>FeCNCஹNRᡂCᐳUVᐸWᨵ1஺VX

252C7TEFᦑCN•I6EJ7TEḄᦪMNn(c);nm)=l;2ᙠHCNICPQḄRSᵯQUᦪV2,WCPQXYᨵ[UᵯQFᡠ]CPQᩖᓄ`aVspᩖᓄHCNV᩽ឋᑖQFᑖQefᵨhᜧjk᩽ឋᑖQḄᑖQefᵨhFWHCNᑖQelmᙠnEFopᑖQqeḄfᵨhrsFtN2Vk᩽ឋᑖQFᑖQefᵨhN᩽ឋᑖQḄᑖQefᵨhuv;HC1x᩽ឋᑖQFyᑖQezᨵᑖQefᵨht{nEFᐸᑖQefᵨhNN2ḄᜧFᦑHCNஹN2ஹHC1~ᱥḄᰚᵫᑮḄV;HCN>HC1>N2(3)FeCbIḄᓄEᐹᨵḄᐳRឋFFeஹClPQeᓄEVᐳREFtᐸ᝱]ᑖQ(Fe2a6)mᙠ,xᵫjFePQᐹᨵ⍝tClPQᐹᨵ[ᵯQUFFeJC1PQqeᡂ¡¢EFFe2ckḄ£᪀¥V;ᵫj¡¢Eo¦jᐳREF§¨FePQḄ¡¢ᦪx4CFaXI(4)᪷ªb¢«FePQḄᙶ᪗§¨x]®¯°Ḅ8C⚔Vᙶ᪗P,ᑣᜐjaᱥḄFePQាµᜐjᨔ·Ḅ⚔X,ᦑᐸᙶ᪗V(0,0,0)NPQᜐjᨔ·Ḅ¸¹IºFᡠ]ᐸ¢«ᵨᙶ᪗⊤¼V(1,2F!);ᙠ¾ᨔ·I¿ᨵFePQḄᦪMV8X\+6X\=4,¿ᨵNPQᦪMV1,ᑣᙠÀCᨔ·I¿ᨵ4CFePQÁ1CNPQFᵫjNJFePQ82qeᨬÃÄÅapm,NJ☢ºXḄ&PQÄÅᨬÈF§¨ᨔ·ÉÊV2apm,ᡠ]¾ᨔ·ḄËÌm_4x56+14“9=Nx(2axlO-'°f/cmஹÏஹᵪ஺g/cm^Aூ௃Ò⚪ὃÕPQ᪶᜜ᵯQ᣸ÙஹᐗÛᵯÜឋÝᱥᰚNuஹᓄE`aḄᑨßJᦪMḄàáÁᨔ·Ḅᨵᐵàá஺ãäPQ᪶᜜ᵯQ᣸ÙåæÝᡂᓄEḄᱯFè᪷ªᙳê¯ëᑖ᪆àáF⚪MὃÕíUᱥ£᪀¨îḄãäJïᵨÁðñJᑖ᪆ïᵨÁàáòh஺29^-747kJ-mor10.04mol/(mol•L)5/144rᜧ2(g)2

26JK(mol)4200LM(mol)nn0.5nn
⊝(mol)4-n2-n0.5nn14NO?ᩭḄQRᑣ[4n+(2-n)+0.5n+n]/(4+2)=14/15,n=0.8mol,
⊝S:c(NO)=l.6mol/L,c(CO)=0.6mol/L,c(N2)=0.2mol/L,c(CO2)=0.4mol/Lv(NO)=(0.8moK2L)^-10min=0.04mol/(moleL)
⊝Uᦪk=C(N)-C2(CO)/C2(NO)C2(CO)=5/144ᵫXYEZ1R[ᜧNO
⊝ᔣ^LMXᔣRᡠ`
⊝aRᔣឤcdec22ᘤghᐙᐭ2moiNOஹImolCO,lmnᑮ
⊝SRNOḄpᓄ᳛s[ᜧ&ᦑ=ᫀ?0.04mol/(L.mol)5/144[ᜧ&ঝ᪷,XYEḄᱯuRឤNvwxឤcRvyx[ᜧNOR
⊝ᔣ^XᔣRpᓄ᳛[ᜧRᡠ`a%vb%,ᦑ=ᫀ?v&বজᵫ|}Z1RM⌱ᓄᑺA,AᙠḄRᐹᨵOḄᓄឋ&ᦑ=ᫀ?A,AᙠḄRᐹᨵOḄᓄឋ&ঝCOpᓄ᳛ḄᳮᵫZᓄᑺឋRᐹᨵḄLM஺