2022届湖南省衡阳市高三三模考试化学试题

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+3"2/g
=CH30Hg
+HOg
,°½zÍ2ÎB4Ï᝞'ÐÑᩭÓZfজCO2/g
+“2/g
=COg
+=+41/C/-moLঝCOg
+2H2g
=CHOHg
AH=-90kJ-moL32Ö½zজB᠒½z'o¶ØZÙÚ½z¶gᓄḄ/1体体系系能能W玳C8H1O+2H2C6+3H2CH-QH+H஺½zßà体体系系能能盘B.A.CttD.6.ᐵá“Óãäᓄ”æÇçÓè¶ᨵᦔêëìḄÓãGíᵨ᝞oᡠmîï/ᜳᢝîïᙳ"ḕᶍ1ßôÓã¶õᑮḄḄ/1A.ᵬîïË÷㻼ᔲᨵK+B.ùîïËãúûü⏚ḄῃþឋC.ÿ
ᑴᜓMgC%D.
ᑴᦈஹḄNO7.NA⊤ᦪḄᑣᑡ!"#Ḅ$%'A.12g()*+,ᨵᓄ/0ᦪ124NAB.᪗45622.4LCO2789:Na?஺?ᐙᑖ?@ABᵯDᦪ12NAC.ᵨFឋᵯ᩽ᵯI⛳KLMABᵯDᦪ2NANOᡂḄQR2D.STURILO.SOmol-L-1NH4cl
2L0.25m஺•W1NH4GXY+NH*Ḅᦪ1ᙳ[\

20.5NA,cdὅfg8.ᑡiDjklmᑏ"#Ḅ$()A.ᵨNa2sChXYᔾᦈg:CLx3S0j-+C12+HO=2HS0^+2Cl+S0l-2B.FeLXY+ᐭ8:x2Fe2++2+2Brj=2Fe3++l2+4Br-C.₝⏚⏚ឋ═⏚XY⁐x2Mn0'+5C20+16H+=2Mn2++10C02T+8H2஺4D.ᔣNH4HCO3XY+g:NaOHXYx/VH^+OH=NH3*HO29.Imo¦§(¨MKᓴªᓫ¬?@Ḅᰚ®(ᓫ¯x°±஺W1)²³᝞³?@ᱥKOᡂᱥᙳ2UNḄ¶T5᝱஺ᑡ¸¹┯»Ḅ$()MCLA/-641.3-364*MI2A.MBr2¼C%?@Ḅ4H<0B.ᵫMC%(s)ᑖIᑴÀMḄ?@$ᔾÁ?@C.ᓄᔠᱥḄÁ¶TឋÃÄxMl2>MBr>MCl>MF222D.MF(S)4-Br(l)=MBr(s)+F(g)AH=+600©•mo/-1222210.ᵬ$SÇᙠÉOᱥÊᵨËÌ+ḄͪCO(N42)2Aᓄ2Î᛻ÐÑᱥ¬ÒÓᓄ/ÔAᓄ2ᵯÔḄ
஺ᑭᵨᵬஹÖ×
ÒÓØÙ(ấ(Cu-Si2ấÝ)ÞßᵯIàáᑴᜓấ஺ᑡ¸¹┯»Ḅ$()ᵬÖA.ᵯ᩽M¼ᵯ᩽bãäB.åᵬæ+çὑ22.4LO2NÖæÀᑮ28gấC.Öæ+Y᝱Ca-Siᔠ(2□᩽Y᝱ì2▢᩽D.MîḄᵯ᩽?@l2xCO(N”2)2+”2஺-6e-=CO2T+N2T+6H+

311.ð⏚$SÇñ⌕Ḅóôᓄõö÷஺øù¹ᑴð⏚Oö+Ḅᐵ0õÄ$S02ḄûᓄüᓄxS02%g
+3஺29ᔳᑺS3g
AH=-98k
-moL஺Ẇþ⊤ÿS஺2ᓄᓄḄ᳛"=k-1
"1-ᐔ஻k᳛ᦪtᓣᜧ!aSO2"⊝$ᓄ᳛a%&'(஺2$ᓄ᳛nᦪ஺ᙠ4=0.90&*+,ᑡ.Ḅkஹa01ᐭ34᳛5ᑮḄv-t78᝞:ᡠ<஺.ᑡ=>?@ḄAA.CᙠDE.FGHIB.1J0”஺2KLM஺2ᐙᑖPQḄRM98ᑜC.ᓣGᜧᓫUVWᑁYᓄᑖZ[ᑖᦪ\YᓄᑖZᦪD.᳛ᐜḄᓣᜧ^_Aᓣ`akஹaᙳᜧ12..ᑡcdefஹghi5QḄjkᙳ?@ḄA⌱cdefcdghcdjk⚗ᐜxyz⁐|}~Cop+Aᔣ%opᐜqᐭrᓄsoptuᐭv⏚z⁐|}ᜫᨵS஺+ᔣ%opqᐭᓄop*Ḅ⁐Cop+B(NHtᙠ0.17HO>L-1K2sopuqMḄᐜxyz⁐|}~Ksp(ZnS)CZnSQoptqᐭMḄCiiS/opxy⁐|}>Ksp(CuS).ᵨpHᑖᙳO.lmol-pHNa2sO3>HS஺jᔠ"+GDᔆ1ḄNa2sO3\NCZHSO3opḄpHNaHSO3¡¢S஺ᡭḄ¤A.AB.BC.CD.Dஹ⌱⚪13.ᵯ`᳛A⊝Mᵯ¦§op`ᵯG¡ᜧ¨ḄᱥᳮM஺.*«¬VWḄᓄ\⏚opᑖq®¯°opḄᵯ`᳛qᐭ®ḄVW^”2஺ᓄḄ78᝞:ᡠ<஺.ᑡ=>?@ḄA

4电导率■(³஺)A.78I⊤<ᓄopq®¯°¶opᵯ`᳛ḄᓄB.aஹbஹc·¸opḄpHc?@ḄA()B.PiᡠC(NH-HO)32D.P3ᡠ

5%᪥ᓄðᐶò¨ó᪷õCæᙠcdö÷cd஺øù.ᑡú⚪:(1)ᵨý.cdþ:ö÷æḄ“
”6ᜐᳮK有孔Na2SO4b塑碳酸钙料-ᮞCCU板ABজAaḄᵨ"_ঝBCC஻'ᔲᵨ)ᩭ+,IIIঞB./Ḅ012345஺(2)ᙠ“;
”<=⏚╆@ABḄ=⏚C/ᡂEFGHIḄJKNa2s0O(/VW)SO-2H2஺<ᑖ0YJK@◤⌕Ḅ\ᘤ◀_`ஹbᴻd᜜

6NHHCO43NH4HCO3H2sO4NaOHÏÐÑᑖ□01¸ᓄᱥÓ4ÔÕÖḄp<Ù᝞®⊤:ÔÕᱥFe(OH)2Fe(OH)3CO(OH)2Ni(0H)2ÛÜÔÕÖḄpH7.52.77.66.9ÞᐰÔÕÖḄpH9.73.79.09.2àá®ᑡã⚪:(1)åæ1Ḅº⌕ᡂᑖ"çèvåæ2□01⌱ᵨḄᓄêᑺ5஺(2)“ëpH”Ö<ë⁚pHḄÙ";“îïᰀ_''Ö<᝞ñ"ᙠuvòóôY⚗ö<67஺2(0஻)2஺஺3Ḅ\ᘤ÷"..(3)“⏚ø"Ö”2஺2Ḅᵨ"஺(4)“Ôù”Ö./Ḅ0123451úûü◤ýþ<2Fÿ

3஺(5)M(0H)2ᵨᑴᜓᵯᵯᐙᵯ!Ni(0H)2+M=MOOH+MH(M!'ᔠ))ᵯ*+!K஺.+ᑣ0ᵯ1᩽Ḅᵯ᩽4!஺17.ᵫ6᛻89:ஹ<=>?@ABḄCDEFGHIᱥ᣸0▲MNOPQR(SPFG᣸0᪗iḄ⌕஺rq⚪(1)eᙠ20࠷:জn2(஺)+஺2(஺)=2NO(g)1ஹ⌮Ḅᓄᑖ!mkJ/molஹnkJ/mol¦

7ঝ4N43(g)+5஺2(9)=4N0(g)+6W0(/)1ஹ⌮Ḅᓄᑖ!pkJ/mohqkJ/moL2ᵨNH3ᜐᳮFG³SḄNOḄ!4NH3(9)+6N0(g)=5N2(g)+6H2஺஺)Ḅ´H=(,(2)¶·FGḄ“¹ᓄºᓄᘤ”½4moiNO(g)¾4moicO(g)ᐙᐭ1LḄÁÂÃᘤSᙠ~ÄžÆÇqAÈ2N0(g)+2co(g)U▲(஺)+2CO(^),OÌCOḄÍ⊝ºᓄ᳛aÑÄÅTÓᓄÔ2Õ᝞×ᡠÙ஺×ÚSC⌮Û᳛B1Û᳛(Ý”ᡈ“<"q~)¦ḄÍ⊝áᦪAD஺`åOÌ஺æ=k/c2(NO)y2(C஺)v^=fc^-c(W)-C2(CO2),k21ஹkêᑖ1ஹ⌮Û᳛áᦪ஺ᑣTJCCᜐëḄv.v^=஺(3)FG᣸îïᨵñᐗ¹ᓄïóᙠ¹ᓄᑺ⊤☢AÈᔾ▬ஹ*ᔾù◀COஹNOûᜧHIᱥ஺üᳮ᝞q(Pt¹ᓄᑺÿ
“*”⊤ᔾ▬᝱)I.NO+Pt(s)=NO*II.CO4-Pt(s)=CO*III.NO*=N*+0*IV.CO*+0*=C0+Pt(s)V.N*+N*=N+Pt(s)VI.NO*+N*=ᵯ0+Pt(s)22!"#$%ᡂᱥ()*ᱥ+,-.,/ᓄᐵ2᝞41642ᡠ4142জ41$:.,;330࠷>)*VḄ@ᓄA)*VIḄ@ᓄA(B“<”ஹ">"ᡈ"="):)*VIḄᯚ/IH()("<”ᡈঝ42$:.,LTaᓣPTbḄRS$:)*ᱥ+,ញᒓVWḄX⌕Z[

8\஺18.ᨵAஹBஹCஹDஹEefZghᦪjklᜧḄᐗo(ZghᦪᙳWq30)஺AḄr᝱Zg2PAsᨵ3tᵯgvCḄr᝱Zg2pAsᨵ1tᵯgvEZgᨬ᜜zᨵ1tᓫᵯg:ᐸk᜜zᨵ3tAs}ᙳ᣸ᵯgvDEᕜ:ᵯgᦪ;2஺(1)ᑏr᝱EZgḄᵯg᣸஺r᝱AZgḄIᵯABḄᜧ:ᐸZ[\஺(2)BᐗoḄᓄᱥḄ\ᐗoᓄᱥ$ᨬḄ:Z[\஺(3)AḄᨬᓫᓄᱥᑖgḄ᪀;,ᐸ$AZgḄᩖᓄ\஺(4)ᔣEḄ⏚¡$¢ᐭAḄ#᝱ᓄᱥPR¤:¥%¦⁐¨©:-ª¨©«¬ᑮ®¦⁐¡:ᔣ¡$¯ᐭ〉¤±⏣:᪆¦⁐ᨔµ஺জ¶¦⁐ᨔµḄᓄ·;,¯ᐭ±⏣Ḅ¸Ḅ\.ঝᑏ¶¹ᔠᱥ$¹gḄ»᪀஺(5)C6D½ᡂḄᓄᔠᱥḄᨔ¾»᪀᝞4ᡠ:ᑣDḄ¹Àᦪ\,ÁÂᨔµḄÃ,;pg-cm-3,ÇȯÉÊËᦪ;NA,Ìᨔ¾ÍÎa=cm(ÏᵨpஹNAḄÑÒ⊤)஺19.ᓄᔠᱥH\ÔfÕᢙ×ØᱥḄ$µ:ᐸÔfᔠᡂÙÚ᝞Û:

9oNaCrOA227ÝC6H12OßH2so4জÔᩩáC1CHOCH23ডFHâãÛᑡå⚪:Ý1ßDḄçè;,FᡠÏêAëḄçè;:Ý2ßজḄ)*;oÝ3ß)*ঞḄᓄ·îS;oÝ4ß)*ঠðA¥%Eñ;ᑖò᪀µḄó¥ᱥ:ᐸ»᪀;oÝ5ßAḄᑖò᪀µ$:Aô%õö)*Ḅ»᪀ᨵfÝ÷ὃ⇋úµò᪀ß஺ᙠüýᑖò᪀µ$:᪶ÿᐳ
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10'ᫀ1.ூ5ᫀ௃D2.ூ5ᫀ௃D3.ூ5ᫀ௃B4.ூ5ᫀ௃C5.ூ5ᫀ௃A6.ூ5ᫀ௃C7.ூ5ᫀ௃B8.ூ5ᫀ௃A9.ூ5ᫀ௃C10.ூ5ᫀ௃B1Lூ5ᫀ௃C12.ூ5ᫀ௃D13.ூ5ᫀ௃C,D14.ூ5ᫀ௃A.C15.ூ5ᫀ௃(1)9⊝;<#=ᑖ?@ᧅBḄ?CDᑭFᐭHIBJKḄLMNOP#ᕆᙠPS#TUBBCC஻WXᵨKᩭ[\JNH+CO+HO+Na+=NaHCOI+NH*3223(2)@ᧅ(3)Na2sCU(4)NH.3ஹNa2sO4(5)93.75%16.ூ5ᫀ௃(1)]⏚^_`aᓄấJKSCN(2)2.7-3.9Jde(3)fghijaᓄᡂhij#klmᑺf+3noijlm+2noij(4)Ni2+2HCO^=NiCO1+COT+HO-,pMqrstu᳛q᠒#pMqxy⏚╆{ᑖ|322(5)NiOOH+HO+e-=JVi(OW)+OH-2217.ூ5ᫀ௃(1)(5n+p-5m-q)kJ/mol(2)JJ40.5(3)}J~JᓣxpM#ᓄᑺឋ<#stu᳛⌲#ᡠstᱥMញᒓN18.ூ5ᫀ௃(1)3d'°4s'NmjḄ2PXᜐOḄᐙ᝱;

11(2)Pᑖjᙠ#¡<(3)£┵¥Jsp3HjN(4)[CU(NH3)]SO4-H2O³r[Cu(NH3)4]SOrH2஺Ḅ¶|MJ·¥4;¹N1ᑐ^NHjম8;ᶢ19.ூ5ᫀ௃(1)2-ᵬ¼-1-½⏣(¾¿ÀÁ⏣)ᡈ2-ᵬ¼-2-½⏣JÃmjஹ⏚(2)aᓄst