河南省TOP二十名校2023届高三9月摸底考试化学含答案

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2022-2023TOPᓝ᪥ᨴ᥎ὃᓄᔁ⚗1.ᔁᐳ8⚓"ὃ#$90ᑖ&"ᔁ☢(ᑖ100ᑖ஺2.*⚪,"ὃ-./012Ḅ4ஹ6ὃ789ᑏᙠ*⚪ᓱ=>Ḅ?@A஺3.ᐰC*ᫀᑏᙠ*⚪ᓱA"*ᙠᔁAEᦔ஺4.ὃGHI"0ᔁJ*⚪ᓱKLMN஺OPᵨᑮḄ=STUVWH-lC-12Cu-64Kஹ⌱Y⚪⚪ᐳ16Z⚪"[⚪3ᑖ"ᐳ48ᑖ஺ᙠ[Z⚪\]Ḅ^_⌱⚗`aᨵK⚗cdᔠ⚪f⌕hḄ஺1.ᡃjkᐰ1lmno⌼Ḅ✌⁂stuvwx…z20226ᨴ17{|}"L~“o…”"818஺|ᑡ┯ḄcA.“o…”ḄvwJḄl⌕ᡂᑖcB.G᪀…ḄᜧzᐸᡂᑖC.■ῖᧇᑭᵨᵯᓄ£¤¥¦…§¨ῖ⇨Dª«¬◫ᩞᧇ¯°᪛ᾦzᨵ³ᑖUᩞᧇ2.CO?ᐝµᓄ¶T·>ᑴᜓº»¼□Pᧇ¾¿À`JÁÂÃKÄOᢝÆÇÈÉᶍ஺ËCO2JÌ0Tᧇ"ᑴᜓḄ¼□PᔠᡂÍCOJÎÏOÐÑÒTᧇÓKÔÕᓄ|Öᓄ×஺|ᑡؤÙÚḄcA.CChḄG᪀ÛO=C=OB.H2OḄᳫÝÞu0^^C.J14G6஺ßᨵ=àᦪfḄ`UD.H2JD2âàãäå3.|ᑡؤÙÚḄcA.NOæz}-ᡂHNO3,ᑣNOcHNChḄ⏚⏊22B.êᩩì|"íJ}îÍ·>-ᡂFe3O4C.SiO2§æz}"§PËSiO2TᧇᑴᜓHSiO32D.ᵯïðñò#"óòôõᵯö÷᩽4.ùᵨ|ᑡ¾úû@Óü¾ú"OËýᑮ¾úfḄḄc

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ᐰᧅþºᮞS02⏚>NaOHfl]/A.ᵬNa2cChNaHCChḄឋB.ᑴ!H2C.ᦈ#S02D$%&Na2c03'(5.)NA⊤+,-./01ᦪḄ345ᑡ789:Ḅ;A.᪗=>?544.2g@ABCᔠE(FᡠHIJᦪKNAB.ImolCLLᐭF4HNOḄᦪPQRS"NAC.TU54pH=3ḄV⏚F4ᵯXḄH+ᦪPK10-UNAD.ᵨZឋᵯ᩽ᵯ\CuS044]^_ᔣF.ᐭlmolCu(OH)2bcឮe4f^ghᵯJᦪPK2NA6.ᓄlmnopqrrsᐵ45ᑡᱥvᵨ⌶ᓄlIᳮyᨵ{|ᐵ}Ḅ;⌱⚗ᱥvᵨ⌶ᓄlIᳮஹC102b)ᩔAஹ002bᵨᩭᜐᳮᑺᓄ᧕ᑖ\4Bᓄᵨᑺᑖ\qᱥb)◞EᦈḄᩞᵨNa2c03NH4clᜐNa2cChNH4clb¡Cᳮp\ᓄ¢Nᓄ£¨ᩩDᓄ¢Nᓄ£ᵨS¤¥¦§ª5b)¡pᑖ\«|A.AB.BC.CD.D7.¬9:⊤+5ᑡ«|ḄXJ®¯Ḅ;A.H2O2ᙠ±ឋFᓄCrO3Cr2O3+3HO2+2OH-CrO>+4HO2222

2B.A1(OH)3bS±A1(OH)3+3NH3«HO=A1O²+NH:+2HO22C.Na2s2O3ᙠ⏚ឋᩩª5³ᓄS2OJ-+HO=S2+SO+2H+2D.ᔣBa(OH)F´µ¶NHHSO·¸¹ºᐰBa2++2OH+NH:+H++SO²=BaSO"+NH3H2O+H2O2448.»@;ᐹᨵ½¾ᐳÀÁÂᡈÄÂḄᓫA@&4
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18¨»@Ḅ78┯ÖḄ;A.m×Ø4ÙÚRSB.ᡠᨵIJᨵb¬ᙠÛ¨Ü☢C.ºᐰ&pᡂßᱥvḄ!ḄCO2H2OD.mà!H2.ᡂáḄqᱥmABØKÛ}ᱥ9.Eᔿã8;noäåæçèḄ1ᵨ84ᔿãḄBn1ᵨNa2c03ᔾᦈ¡p«|3Bn+3Na2co3=5NaBr+3cCh+NaBrCh,5ᑡ789:Ḅ;A.BnêᓄᑺëìIᑺB.íᓄḄBnmíìIḄBnḄᱥvḄ!QÉK51C.pᡂ6.72LCO2^,gh0.5molᵯJD.ᔣᡠïF.±4bïBr210.ᵨ᝞Ôᡠ+ðñò(জঝঞ;÷ᨵs|øᑺḄùú)45ᑡᑖ᪆┯ÖḄ;ঞNaOH
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3A.0GcdeW>Z>Y>XB.fᓫhᓄᱥḄijeZ>W>YC.k(⏚⏚ឋeW>YD.ᓄᔠᱥᵬ45l.ᐳnᓄᔠᱥᡠᨵ0Gᙳq8ᵯGst7᪀12.uvvwᨵxyz{ஹᑭ}ஹw~Ḅᵨ஺ᐸzឋᡂᑖvvw⏚7᪀᝞:]ᑡ_`abḄ.B.Aᓄஹ(ᓄஹC.1molᨵᱥ<3molH2ᡂD.ᐗḄᱥᨵ1213.]ᑡᫀḄᑮḄḄ.⌱⚗Ḅᫀᔣ20.00mL£NaOHᐭᵬ¥¦ᢣ¨ᑺᵨtNaOHAO.lmol.L'©⏚᪗«¬t]ᢣ¨ᑺ#⁐®ὑ⏚°Ḅ¡±²ᵨ»¼½¾Zn4Fe,ᐭ⏚ᓄḄNaClᵨ¿ᜮ³´ᱨ□᩽Ḅ▢B¬ÁFeᵯ᩽ÂÃÄÅ°>¬ᐭƬÇÈᓄ᩽¹º`ÉC³₝⏚ᵯËᔾÌÍO.lmolLÎ₝⏚̱ᵨÏÐᘤÒpH#ᓄÓÔAgCl4AgBrᑖÖᔣ×ØAgCl4AgBr⛳4ᐭq°AgNOaDḄKspᜧÕÓÔÚAÛÜḄᱥZḄ°

4A.AB.BC.CD.D14.ᑢᜩßᦟᣴâãäåæ[Ç(ᓄ/0è᩽ឋéᩞᧇᵨ>pHឋ}ìíᵯîÍ}ìᨵíᵯîḄឋïðᑮ'ñòḄó¡஺]ᑡ_`abḄ.A.ôᵯ®ᵯ᩽Aõ᩽B.ôᵯ®ZH+ö÷ËGøᣚúᔣᵯ᩽ᵯ᩽BûüC.ᐙᵯ®▢᩽Ḅᵯ᩽ýZM++2e-=ZnD,ᐙᵯ®ImolZd+÷ú®ᨵ2moi[Çÿ
15.ᙠ(Pd)ᵨᓄᦔᓄᓄᓄᑺ!ᩖ#$%ᦋ'ᓄ()*+ᔊ-᝞/(*⊤3ᔾ▬᝱TS⊤37᝱)ᑡ:;┯=Ḅ?()>3ஹ扫没玄把A.@H2O2*+Aᡂ?CD*+B.*+ᔊ-Eᙠ*+C.FᵨPd—Na+ᓄᑺGHIJḄKᱥᙳNFᵨPdᓄᑺOPQD.ᐸSᩩUVWXFᵨ!ᩖNa+ḄᓄᑺᓫZX[ᑁ]O^K_16.`ᔠ*+Ḅb⊝dᦪᵨfᔠᱥPQdᦪ⊤3CM+@NH3ᙠhijEᙠ᝞b⊝(ᐸKஹlஹ

5nஹK4ᑖr?CF+Ḅ⌲vPQdᦪ):Cu2+—[Cu(NH3)]2+U[CU(NH,3)2]2+U[CU(NH)3]2+U[CU(NH3)4]2+3KஹKKK,23ᔣ⏚ij᠒ᐭ]ᔜḄᑖᑖᦪযij$Ḅ'ᓄᐵ᝞/B.CM++4NH3^=^[Cu(NH3)4]2+Ḅb⊝dᦪKḄ/C.c(NH3)=10-3molL1X,c{[Cu(NH)]2+)=c{[Cu(NH)3]2+}>c{[Cu(NH3)]2+)334lgK|+lgK,+lgK,D.M®Xlgc(NH3)=τ03¯ஹ°⌱²⚪´µ⚪ᐳ3·⚪ᐳ39ᑖ஺17.º»¼·½¾¿@ÀÁ⏚*+Â᳛'ᓄX3.2gÄÅᐭÆÇᘤ(ÉÊ᛻)ÌÍÎ25mLi.35mol•UÀÁ⏚஺ÒÓ´*+ÔÕ▤×ÉØÙÒÓ90minÜÝÞᨵàáâKA150minÜÝãijäå⁐(*+ç᠒▤×A),éG⌲ê'ë⁐(*+çì▤×B),ᨬîijᕈðå⁐(▤×C)஺(1)@ÀÁ⏚*+Ḅ$%ñ-òI஺(2)óô26.6C,*+-ᨬô27.8C÷ᙠ45࠷hùúû*+ÒÓ'ᓄüᜧ:Ø(3)¾¿@1.35mol•LþÀÁ⏚ᙠÉᩩUÙë⁐Ḅ
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6᝞⊤:CBᑁA⁐"$#⁐"⁐"6⁐6⁐&'0.001molL-'KMn04V§6⁐&ᐭ5~6&;<=6>&ᐭ&ᐭ101⁐20&;&;<@6⁐=6⁐'ABCDE;=&'2<6⁐<6⁐<6⁐0.001molL"KMnC>4MNO3⌲&&'JK⏚MNOP⁐MNOP#4⌲&&'NaOHP#⁐⁐U▅Wᧇ⊤NY⏚ᙠ[\]^_✌ᐜbᡂHNCh,fgHN02hi⏚ᵯkl^mHNO2^=^H++NO2">⍗rAᓽᑖtᡂNONO,NOuvwCi?+bᡂ#⁐zᔠk|CUNO2"—>஺2জᑖ᪆vg_⁐#$Ḅu[\D_cH*"BᜧcCM+"Bᕈ⁐ঝ[\]^_—cCu2+"ᜧwNOuᔠbᡂCuNO2"°,ᕈ#⁐ᵨ⊝ᳮt"ঞᨬ;ᵫ,cNO"C[CUNO2"">]£cCF+"Bᜧᕈ$⁐஺4"ᙠ[\¥¦§¨©ª2HNO=NO+NO2+HO^11஺322218.ÌÍÎÏhᙠЧÑÒ_Ḅ¦ᑡÔÕÖ]^஺×ØÏᯏṺÛÜ⌕ᡂᑖZnOஹFezCh,áᨵâãFeAsO>FeSb?C"6çᩖé"ÈᧇÔÎÏḄêëì^᝞íu%஺262ஹH2s஺4

7ïðᑡñ⚪u(1)AsSbhóVAôᐗöAs÷óøᕜúᑣAsḄ|᪀ýþíÈFeSb?06_ÿᐗ
Ḅᓄᔠ஺(2)⏚Fe?+ᨵZnOḄ஺(3)pHᜧ5Fe3+ᐰ!ᡂFe(OH)3$%Fe(OH)3$%Ḅ$&'(ᵯᙠpH=5.2+,-5.2$&'(ᵯ.As/Sb0AsO1/SbO23ᙠ⏚4ᑴpH=565.2Ḅ789஺(4):;<,>c(Zn2+)=lmolLiZM*@ABCḄpH஺{EFKp[Zn(OH)2]=1.2xlO“7,lg2=0.3,lg3=0.5}(5)⏚GᑖIJKḄLMNOPQ9LM:RS.NOᵨᑮḄVᴻXᘤᨵZ[ஹ஺(6)]ᵯ^_Ḅ`⌕ᡂᑖ(bᓄc)d0ef“⏚”/“I”ijkᵨ஺19.ᵬmno᦮d0qrᓄCH4/CO2st;:u%vᑴᜓx▬z{Ḅᔠᡂu(H2/CO|ᔠu%)஺(1)EFrᓄ2moic}ᔾᦈ386.6kJᑣd⌮ᵬmno᦮Ḅᓄcᱥ___!ᡂᱥ(b"ᜧ-”ᡈ“”)஺(2)TCஹp0n(CH4)2n(CO)2n(Ar)=l2123Ḅᢗᧇᙠᘤ_!ᵬmno᦮2`⌕CO(g)+H(g)^CO(g)+HO(g)222oজ%_zᐭArḄOᵨ9஺ঝCH4/C02Ḅ⊝rᓄ᳛ᑖ960%/80%,ᑣHzḄ᳛T°C<Ḅ⊝ᦪK=—஺(3)ᓅ¢ᜧc£¤ᓣᦟᣴ¨©@ªtᵬmno᦮ᐝ¬ᓄᑺRh/CexWCh,ᐝ®¯°ᳮ᝞³(Vb⊤µ¶·¸)஺ᐝ᯿ᐝ¬ᓄᑺ!ᵯ(e)/·º(h+),»¼RS<ᑡ¾¿┯ÁḄ9஺A._ᨵÂ᩽ឋḄÅÆ/ÇᡂB.e-ÉCe7rÊᑮW,RËrÊᑮᔾ▬ᙠ¶·¸ḄCChᑖÌC.h+/Rh▬ÍḄᨔ϶ÐᔠÑRBÒᙠRhÌḄCÓÔÕÖὑÊ◀D.CO2Gᙠ¶·¸ᶇ<¶7ÚÛG¬ᓄᑺܶÝz(4)Þឋᵬmßᧇᵯà_á᩽Ḅᵯ᩽஺âஹ⌱ὃ⚪2ᐳ13ᑖ஺çὃ!É20ஹ21⚪>_è⌱⚪Oé஺᝞êëìíîᢥᡠìḄñ⚪òᑖ஺

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