河北省巨鹿县2022-2023学年化学高三第一学期期中学业水平测试模拟试题（含解析）

《河北省巨鹿县2022-2023学年化学高三第一学期期中学业水平测试模拟试题（含解析）》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2022-2023
ᓄᔁ⚗1.ὃ⌕ᑏὃ஺2.⚪ᡠᨵ!ᫀ#$%ᡈ'ᑏᙠ!⚪ᓱ*ᙠᔁ+!,ᦔ஺./0ᑖ#$ᵨ2B34+!5.60ᑖ#$ᵨ7⁐9:Ḅ<94+!஺3.ὃ=>?*ὃ$@ᔁ!⚪ᓱAᙠB☢*DEὃᕒᦈH஺/ஹ⌱K⚪(M⚪Nᨵ/O⌱⚗Pᔠ⚪)1ஹHCOOHSᧇᵯVḄW+Xᳮ᝞[ᡠ\஺]ᑡ_`abḄcHCOOHKOHf1HC(xrKHCO,yA.AᵯdK+ef◞hᔣjklB.a᩽ᵯ᩽nopqHCOCT+2OH--2e-=HCO
+H,0C.Aᵯfs◤⊡ᐙḄᱥxXqH2sO4D.Myl0.4molᵯz*ᳮ{|ὑ᪗]L12LO22ஹ@]ᑡeᐭᨵS0ḄBaCl*ᨵḄc22A.HC1C.ClD.NO223ஹᑖzᐹᨵᙠᑁᶇdஹᦔ᳛ஹᱥᑭᵨᱯ*]ᑡᐵ¢ᑖzḄ_`abḄcA.ᑖzḄᓄឋxᦋ¥B.ᑖzḄ=᪀ஹᱥᳮឋxᦋ¥C.ᑖzᑁḄ+ᵨ§¨D.ᑖz©ª«¬4ஹ/®¯]*ᙠ
O°ᙳq0.5LḄឤ³´µ³ᘤ·no¸CO(g)+C12(g)^COCh(g),ᐸ³ᘤInoᙠ5mindºᑮ¼⊝᝱஺ÂÃᱥxḄ/mol¼⊝ᱥxḄ/mol³ᘤ¯/࠷¿COChCOC12COCI2

1I5001.01.000.8n5001.0a00.5m6000.50.50.50.7]ᑡ_`abḄcA.³ᘤIÄ5minḄ¼ᙳnoÅ᳛vCO
=0.16mol-L'min1B.ÆnoanoqᔾÈnoC.³ᘤHÂÃdCLḄᱥxḄq0.55molD.ÉÂÃdᔣ³ᘤIÊᐭCOO.8molஹCh0.8mol,ºᑮ¼⊝dCOyᓄ᳛ᜧ¢80%5,ÌÍÎᵨH
ÏnoᑴᜓªᓄÏḄÒÓ᝞Ô[ᡠ\ZnÕÖᨵ×ZnSᩖxÙ*]ᑡ_`ÚabḄcÒÓQজঝA.জஹঝÝÞßᨵàNaOHஹàH2sChB.áp᮱ÊÈÄ*ᵨáᦈãঞᜐæS*efçèᑨêëC.=>nod*ᐜíîáp᮱ÊÈ*ïᐵµðñKD.òóôõᑁḄö*ᢗᐭ〉*Éᨵ*ᓽúûüᑴýþªᓄÏ6ஹᙠᢣᩩᑡᔜᜧᐳḄA.ᙠNaHCChK+ஹCl\A1O\SO?"2B.ᙠcH+
=0.1moHL-iḄ:K\IஹChNO3C.ᙠ⁐!ḄSO2,CO2\Na+ஹK+33D.ᙠpH=lḄCa2\Na\CIO,NO37ஹ0.6mol♦L”ḄFe2Sh3"L2moHJḄC11SO4Ḅ#ᔠ200mL,%ᐭ'()ᐙᑖ,-./0Fe?+1CM+Ḅᱥ3Ḅ4562:1,ᑣ%ᐭ()Ḅᱥ3Ḅ6A.0.16molB.0.22molC.0.30molD.0.48mol8ஹᑖ8ᓄ::;"Ẇ=Ḅ>ᵨ@Aᑡᑖ8BC"DEFGHḄA.IJ⏚ஹLMஹ⁤OஹPᮞᑖRST⏚ஹMஹUஹVᓄᱥ

2B.HC1OஹH2so4(W)ஹHNChᙳᐹᨵ\VᓄឋFVᓄឋ⏚C.^_)ஹ`ab᪍ஹIdஹedஹfdᙳ6#ᔠᱥD.NaO,NaOH,Na2cO3ஹNaCIFSTgḄhVᓄᔠᱥ29ஹi:;jklmnᑴᜓCa(N(h)2,mnqr᝞tᡠv(ᜳᢝqrzᶍ|)஺z~2NO+CaO2===Ca(NO2)22NO2+CaO==Ca(NO3)»ᑡGHḄ22A.ᐭN26᣸qrḄB.qrBஹDḄᑺᑖR6d"W⏚C.ᱏᣚᡂᩈᑴᜓLḄO⏚┛D.qrAVᓄg"⏚ᑖCO2"CO10ஹCLᐭNaOHᑴ0^_(¡⌕ᡂᑖNaClO)஺'ᓄ:jᙠ£¤f¥¥ᐭNaOH¦§mn0ᑮCUTஹC1CK©Ḅᱥ3Ḅ(mol)1,-ª«t(min)Ḅᐵ®¯஺ᑡGHḄn/molA.ᑴ°^_Ḅᓄ:,-±²³6C12+2NaOH=NaC14-NaClO+HO2B.a´ªᔜWµc(Na+)>c(Cr)>c(C103-)=c(C10-)>c(0H-)>c(H+)C.t~t,CRTḄᱥ3Ḅ¶Ḅ·¸3CKT=2CI-+CIO3-24D.ᵨ^_ª6¹\^_ᦔ»ᔣ^_%ᐭWU⏚11ஹᑡtv1½-Ḅ¾¿ÀÁḄA.tI⊤viᔾÄ,-ᑖRᙠᨵஹÅÆᓄᑺḄÇÈ,-ɲḄᓄ

3B.H⊤O.lOOmol/LNaOH20.00mLஹ0.0100mol/LHClᡠᑮḄC.ID⊤Ḅ⏚⏚ᵯ"#$cNO2Ḅ?ᓄ᳛c>b>a12ஹᑭᵨC"DEᣚGᵯHI=JKLM⏚NḄOPQRSM⏚TUVᳮ᝞ᡠ஺ᑡ[\]^Ḅ_()A.NbM⏚c#a%>b%B.aஹcd□"DEᣚGbd▢"DEᣚGC.MஹNbᑖgSRhiTjiD.SlbmRḄ%&dNH+OH-=NH3+H2஺13ஹnᓄnoᱥAஹBஹCஹDஹEஹX,pᙠ?ᓄᐵr(sᑖRᡂᱥT%&ᩩ+uᶍw)஺ᑡxy┯{Ḅ_ÊᡝTÌA.|DdNaCl,}A=~C%&RᡂB,ᑣE=_CGB.|D_⁐ᙠiᨬ-d⋎⁐ᑣA=_C.|D_ᑣA.B.Cᙳ=~X%&RᡂDD.|D_⏚ᑣA=_ᓫ=_ᓄᔠᱥ}D=~%&RᡂBᡈC14ஹᑡᔜ"DᙠᢣᜧᐳpḄ_A.ឋ$Fe"ஹK\Cl\SO?B.1.0mol•LḄFeCL$H\S2\Cl\SO?'C.pH=12Ḅ$K\Na\CHsCOO',BrD.~%&SRjiḄ$Na\K\C02\N0'3315ஹᵯH⏚ὶᔠRS⏚T¡Ḅ¢£᝞ᡠᐸ▢᩽T□᩽ᙳd¥ឋi7ᵯ᩽஺¦§§¨i7ᵬ~i7ªḄ78«¬d12,JI]^Ḅ_

4A.a᩽1ᵯÏḄÐ᩽ÀÑB.ÒᱥÓ6⏚C.ÔᣚÕd6▢ÔᣚÕ×ᐕÙ▢ÉÚD.bᵯ᩽,Û³62H2O+2e=2OH-+H2T16ஹᑡᨵᐵᔠᡂÜḄ¾¿ᵨÝÞᱯᑡ·ᳮᩭâãḄ×ÚA.ᵨ(äåN2"H2#ᔠæᨵᑭTᔠᡂÜB.èé5>éᩩêᨵᑭTᔠᡂÜḄ,-C.500஺×ëì5£¤êᨵᑭTᔠᡂÜḄ,-D.ᔠᡂܪíᵨîïðñòè·ᧇḄᑭᵨ᳛õஹö⌱ø⚪×ú⚪ᒹü5j⚪Ú17ஹᨵýᱥIᨵýᔠᡂ«æ᝞ᔠᡂJᡈèÿᱥ
ᐸᔠᡂJḄ᝞:•ᩩ+®ᓄᑺ.±HCIজ,OC",AḄᱥᨵ2ঝᨵᱥBᨬ!ᓫḄᓫ#$J%&ᨵ3'(ᐗḄ*+R,-CH-CHCHOঞR.-CHO+R2-CH2CHOII(R1ஹ-%./ᡈH123OHR;45678⚪:1
AḄᓄ;<=%>EḄᓄ;?%.2
FfGḄAB+CHᑖ2EFGHḄ<=—.3
JḄJ᪀!?%஺4
ᑏNIᙠPᩩR7SᡂTUᱥḄᓄ;ABVW?஺5
ᨵᱥKGḄXYᱥZ[ᑖ2\]^G_14,ᑣaᔠ7ᑡᩩRḄKḄXᑖc᪀dᨵefὃ⇋idc᪀3஺a.ᨵj'k/b.lGmSnoABpGqFeClஹrsABᑏNᐸE᪶uᐳwxyᨵ6'zz☢|}^%ḄJ᪀!?»

518ஹỚ⏣EBᵨḄ⌼ᑺᓄᔠᱥGᔠᡂỚ⏣ḄEdᐸᔠᡂ᝞7:<1)CE&FGHḄ<=%—O(2)C-DḄAB+C%.(3)E-FḄABESᡂᨵᱥX,ᑏNXḄJ᪀!?ߟo(4)HDḄXYᱥᑖ2?%CioHuNO”ᑏNX7ᑡᩩRḄHḄXᑖc᪀dḄJ᪀!?:জ/⏚>ঝGmSABᐸᱥ}GqFeChrsmS⁐AB>ঞᑖ2Eᨵ6fXᓄ;᛻Ḅx஺3CHO%1ᧇᑴᜓ(5)ᑏN6Ḅᔠᡂ£W.(¥¦ᑺ§CHO⌱ᔠᡂ£WḄ©ª«¬⚪⚪)஺19ஹ¯⏒(soc12)±¯⏒(SOC12)²ᵨ³ᓄᑺ´ᵨµ¶ஹ·¶ஹ¸ᧇ¹º»ᨵᔠᡂ¹º஺±¯⏒¼2ᵨᑴ┞±¯⏒(Li/SOCb)ᵯ¿஺ᨵᐵᱥ\ḄÁᑖឋ\᝞7⊤ᱥ\ᰚÅ/cÆÅ/cᐸÇឋ\জ᧕Sᜧ]ÊËSO2c12-54.169.1ঝ᧕ᑖSO2cLÌÌS01+Clt22H2SO410.4338ᐹᨵᔾឋÏÐᑖ

6ÑÒÓᵨÔÕÖ×ḄØᓄ¯Ùᔠᡂ¯⏒ABḄÚᓄ;VW?%SO(g)+Cl(g)0SO£12(1)AH=-2297.3kJ-mol-1.ABÛÜ᝞ᡠ©(ᜳᢝàᘤḕᶍ)ä45ᨵᐵ8⚪(1)àᘤAḄ<=%>(2)àᘤBḄ³ᵨ>(3)ÛÜåEæçḄ¦ᑺ%,ᙠÑÒÓᵨxᓄèᔾᦈêë¯⏒ABḄì2VW?%(4)%íT¬ÑÒE¯⏒Ḅ᳛ᙠÑÒï³E◤⌕òóḄô⚗ᨵ(ö÷ø)জᐜúûüýúÙdঝþᑴÙ£ÿ᳛
᠒ঞ⚠
〉ট⚠(5)⏒ᵨ⏚(CISOsH)ᑖ!"#
$%&Ḅᓄ)*+,-.2clsO3H=H2SO4+SOZC12,/*0#ᑮḄ23456ᨵ⏚஺জ:ᑖ!2ᱥ4ᑖ<=⏒Ḅ>?@ABC-ঝEF>?*ᫀH?⏚ᑖ!ᑴJ⏒2346ᨵ⏚
Kᑡ*ᫀᔠᳮḄO.(QRS)A.J᪵3VWX
YZ⁐\]V^_`.aJV^
ᐭBaCkV^2cd⁐ef
ghiᨵHzSO”B.J᪵3ᙠklᩩnKopᐰ%&
rᓾtuvBaCkV^
ᨵd⁐ef
aYZ⁐\]V^_`
ghiᨵH2SO4.(6)Li—SOCLᵯxᵨWyz{|ᘤ஺$ᵯxḄᵯ᩽ᩞᧇᑖ-┞
ᵯ!V^OLiAlCL-SOCL஺ᵯxḄ%&⊤-.4Li+2S0Cl===4LiCl+S+S0o22জᑏ=$ᵯx᩽cḄᵯ᩽%&,ঝ$ᵯxᙠXஹḄᩩnK
O20ஹᑭᵨiXc2NaS0«5H0,>?ᵨ᝞Kcᡂ¢+஺2232

770%HSO24¡ÚcmR%&᝞$Na2s(aq)+H0(1)+S0(g)=NaSO(aq)+HS(aq)(I)222322H2s(aq)+S0(g)=3S(s)+2H0(1)(II)22S(s)+NaSO(aq)_A_NaS0(aq)(III)23223(1)Ýᘤ¢ßᡂàᐵáâãäåᔣ¢£BḄç⚠éᧅᑁìᐭ7îïᡂðì|,ᑣ᦮ò¢£ióឋôõ.¢£DḄ÷ᵨ_o¢£Ed___________஺(2)dùúSlû#&ü¡ÚCNazSTNa2s஺3ាõßᐰ%&ᑣ¡ÚCNa?S
N&SO3ᱥḄ(3)BḄᵨSO?Ḅᡂ᳛ᐸḄ!ᨬ#⌱%஺a.)*+b.⛳
Na2sO31c.⛳
NaHS(h1d.⛳
NaHCOs1(4)89:SO,<᠒>ᐭ@AC,BᵨḄC.(5)EFGH(III)JKL᠒ᑣ@ACGHNᑮPQḄRS»GHUVWᵨ⏀YZ〉\]^@AA,89`ᵨ⏀YZ]^abc:ᵨdefḄgᘤiᨵ»a.@kb.)lmc.nod.┵qA21ஹt᯼v᣸xᜧḄCOஹCO?ஹSOz,PM2.5(Wᐭ}⚩ᱥ)t᯼ᑗJᐵ஺S&ஹCOஹCO?K᛻LᜧḄ!KḄᔠᳮᑴஹᑭᵨᓄᡃ᛻Ḅᨵᦔ⌶஺(1)PM2.5ᢣᜧᡈ¡2.5¢£ḄWᐭ}Ḅᨵ¤⚩¥ᑡᨵᐵ§¨©ªḄ()a.PM2.5«qᡂ¬!b.PM2.5⊤☢°vᜧ☢°ᔾ▬ᜧḄᨵ³ᨵ¤ᱥc.´µ¶·᣸x¡¸¹º¸t@»᣸xḄ¼ᶇᱥ,ᜧ¾¿ᨵÀÁ¡ᨵ³ᱥ

8d.ẆᑴÄltᧇᵯÇȶ,ÉÊ´µ¶·,Ë̹ÍWÎÏÐPM2.5(2)ᨵÌᵨCO2Ñᵬ⏣tᧇḄÔ¨ÕC0+3H2^=iCH0H+H0232EFÕCO2(g)+3H(g)CH30H(g)+H0(g)AH=~akJ•mol-1ã222H(g)+0(g)=2H0(g)A^=-bkJmoLã222H0(g)=H0(1)åæckJ•mol-1ã22CftOH(g)=CftOH(1)åédkJ•mol-1,ᑣ⊤êCH30H(1)t@^Ḅ^ᓄëÔ¹ì.(3)íîï¿WÎð¸¥ᑡGHᑴᜓᵬ⏣ÕC0(g)+2Hz(g)CH30H(g)஺ᙠó°WôḄõóᘤᐙᐭlOmolCO
20molï,COḄ÷⊝ùᓄ᳛úûÍஹüý(P)Ḅôᓄ᝞ÿᡠ
஺জᑡᑨᑮᓄ⊝᝱Ḅ()஺a.HḄ#ὑ%᳛'(CH30HḄ,ᡂ%᳛Ḅ2.2b.0Ḅ12ᑖᦪ5ᦋ7c.19:0Ḅ;ᓄ᳛

92022-2023)£¤¥ᔁ§ὃ©ᫀ(iª«!᪆)ஹ⌱¯⚪(±⚪²ᨵ³⌱⚗µᔠ⚪¶)1ஹcூᑖ᪆௃ᵫ$Aᳮº»
¼½OᵫHCOOHKOH¾ᓄ-KHCCh,CḄᓄᔠ¿ᵫ+2¿ᓣÁ-+4¿
Âᓄ,ᦑ¼½-᩽
ŽÆᐭ02-Ç᩽
È/ᑖ᪆!⚪஺ூ⚪ɪ!௃A.ᵯx4ᵯ!V^4Ḅ□<ËÌᔣᵯxḄ᩽
ᦑÎᵯÏK+Æ¢◞ÑᔣÅÒÌ
A┯ÔÕB.ᵯx4᩽cÖ%&
Ç᩽cᓄ%&
Ç᩽ᵯ᩽%&,-HCOO+2OH-2e=HCO+HO,B2┯ÔÕC.᪷ÈᐭŽḄᱥ-02X,ᐸ%&-.4Fe2++O+4H+=4Fe3++2HO,FeJ++e-=Fe2+,Fe?+AÚᓄᑺ
Ü=ᩭḄ22ᱥ-K2s04,K+ᩭÞ¼½ᵯ!^
S0ᩭÞX,ᦑÎᵯ¢+4◤⊡ᐙḄᱥX-H2so4,CâÕD.᪷ÈᵯËãឤ»
4n(O)=n(),ᦑ±¾Ì0.4molᵯË
ᳮåæὑ᪗éêëKḄìí-.2e04molx22.4L/mol^2.24L,D┯ÔÕ4ᦑ©ᫀ-.Co2ஹAூᑖ᪆௃îᓄX%&cᡂï⏚
ï⏚⏚ឋñWHCLᡠóï⏚ᓄô%&
ᑣᔣBaCLV^4ÆᐭSO2V^ö÷ø
aÆᐭùḄúûì
V^4öᯠýᨵef
ᑣ$ûìþÿ
⏚ᓄ
⏚ᡈ
⏚ᡂ஺ூ⚪௃A.HC1
⏚ᓄ⚞ᡠᨵᡂ"ᔠ⚪$⌱⚗A'()B.*
⏚ᡂ
⏚*
⏚*ᓄ+,-ᑖᡂ
⏚⚞ᡠ"ᔠ⚪$⌱⚗B┯0)C.1ᓄ
23ᡂ
⏚4⏚5ᓄ⚞ᡂ
⏚6ᡠ"ᔠ⚪$⌱⚗C┯0)D.1ᓄ73ᡂ8⏚8⏚ᐹᨵ:ᓄឋᓄ
⏚ᡂ
⏚
⏚ᓄ⚞ᡂ
⏚⚞<⁐ᡠ"ᔠ⚪$⌱⚗D┯0)>ᫀ⌱A஺3ஹBூ⚪௃AஹAᑖBC3ḄᑖB5EF3ᑖBGHIJKLḄMNO᝱HHQᑖBᓄRឋSGHᦑA

10┯0)BஹAᑖBC3V▭XYZ3ᑖBḄNᔠAᑖBC3ḄᑖB5EF3ᑖBḄMNO᝱Hᡠ3ᑖB[Ḅ\᪀ஹᱥᳮឋSᦋaᦑB'()Cஹ3ᑖBᑁḄcᵨeXO-HfᑖBaᡠ3ᑖBᑁḄcᵨeaᦑC┯0)Dஹ3ᑖBᑁḄcᵨeXO-HfᑖBa3ᑖBghfiaஹfaᦑD┯0஺⌱B஺4ஹC0.8molூ⚪௃A.jᘤIgl5minḄmᙳo᳛v(COCL)=qr=0.32mol/Lmin-i,sto᳛uvwxyz{ᦪ5minuvᑣV(CO)=V(COCL)=0.32mol/Lmiiri,ᦑA┯0)B.st~gᦪtninwᦔm⊝ᓣCOCLᱥSḄzAm⊝ᔣ⌮ᔣᑣ⌮ᔣᔾ'ᔣᦑB┯0)C.stCO(g)+Cl(g)#COC12(g),2CO(g)+C12(g)#COC12(g)(mol/L)220ᓄ(mol/L)1.61.61.6m⊝(mol/L)0.40.41.6m⊝ᦪK='^—=10,m⊝COᓄ᳛1-6m°1/Lxl00%=80%;0.4x0.42mol/Lstngᦪt\ᔠCO(g)+Cl(g)?iCOCh(g)2(mol/L)22a0ᓄ(mol/L)111m⊝(mol/L)12a-l11IHGHᑣm⊝ᦪGHᑣK=]x,a-1)=1°'a=0.55mol,ᦑC'()D.CO(g)+CL(g)=COCL(g)AḄᔣjᘤIᐭCOO.8mol,Cl0.8mol,Gx¡¢£,2£m⊝ᔣ{ᦪᜧḄᔣm⊝ᓄ᳛¦§Ax80%,ᦑD┯0)ᦑ>ᫀCo5ஹDூ>ᫀ᪆௃A.জgNaOH◀«ᢵ,ḄHCLঝgᑭᵨH2s°±H2,ᦑA'()B.²³Ḅh᧕ᰦ¶·¸¹gḄᓄᑣº᮱l◤⌕ᵨ¾ºᦈNঞᜐÂÃÄFJÅÆᑨȳ

11ᦑB'()C.VÉ\ÊËᐜÍÎÏÍÎFᐭhÐNaHᙠhḄÒÓgÔᓾÖ×NaH¸¹gᓄᦑC'()D.ØÙÚᑁḄÛᢗᐭ〉z3gᨵÞßàáᑴhᓄ·²Naã3ᡂhᦑD┯0)>ᫀD஺6ஹCூ>ᫀ᪆௃NaHCChäåᵯçHCCh-5A1OTA⚗┯0⏚ឋᩩêëIஹNOஹᵬ²,ᓄíî3ïᐳñB⚗┯0)Ðò⁐óô¾õaöḄäåäåᕈøឋùᨵᜧzḄOIT,SO32\CO32,Na+ஹK+5OH-ᜧzᐳñC⚗'()pH=lḄäåùᨵᜧzḄH+,5CKTᐳñD⚗┯0஺Ãúû⚪ὃýRþäågçBḄឋSçBḄVSḄÿ
ᐸᵨᑮᐹ᛻ᑖ᪆⚪ஹ⚪஺⚪⌕ᱯᐵজ!"#$%ᙠḄᩩ)
᝞CO?ஹCIO-ஹOH-+,-ᜧ/%ᙠ01ឋ!"
ᙠ⏚ឋ!"4-ᜧ/%ᙠ5Fe3\Al3\NHl+,ᜧ/%ᙠ0⏚ឋ!"
ᙠ1ឋ!"4-ᜧ/%ᙠ5HCO674-ᜧ/%ᙠ0⏚ឋ!"
84-ᜧ/%ᙠ091ឋ!"
ᙠ:1ឋ!";ᜧ/%ᙠ஺ঝ!"#$Ḅឋ=
᝞Fe/I
S2-,SO?+ᨵ?9Ḅ@Aឋ
B9Cᓄឋᱥ=4-ᜧ/ᐳ%5MnOஹCIO-ஹFe"+ᐹᨵ?9ḄCᓄឋ
B9@Aឋᱥ=4-ᜧ/ᐳ%஺ঞ⚪HI⌱⚗Ḅ◚Mᩩ)
᝞!"ḄN⁐ஹ⏚1ᢣQᑺḄS⁐U+
ᱯ9VW
XY4WZ[\⁐Ḅ
ᡠᨵḄ^!"_[`aXYḄ஺7ஹAூ⚪cd௃ᵫg2Fe3++Fe=3Fe2+;i
஻(Fe3+)=0.6mol-L”x2x0.2L=0.24mol,jὑ“(Fe)=0.12mol,lᡂn(Fe2+)=0.36molnBFegḄCM+Ḅᱥ=Ḅ/ox,ᵫgFe+Cu2+=Fe2++Cu;i
pqgḄM(CU2+)=/i(Fe)=/i(Fe2+)=x0361no]+x2!""(Fe2+)=(0.36+x)mol,"(Cu2+)=(0.24-x)moLᑣ--■————=—,x=0.04mol,ᑣqᐭyzḄᱥ=Ḅ/o0.24mol-x10.12mol+x=0.16mobᦑ⌱A஺ூ|ᫀ~௃ᡃ8;Ꮇnqᐭyzᱥ=Ḅ/oX,jὑCM+Ḅᱥ=Ḅ/oyᑣᑭᵨᵯ₹ឤ
;0.24x3+0.24x2=(0.24+x)x2+(0.24-y)x2,ᓽx-y=0.12জ0.24+x_2,ᓽx+2y=0.24ঝ0.24-y-Iজஹঝ
x=0.16molo8ஹBூ|ᫀ᪆௃A.⏚ஹ1(⏚)ஹ⁤(Na2sOHOH2஺)ஹlᮞ(CaO)ᑖ0⏚ஹஹஹCᓄᱥ,ᦑA┯5

12B.HC1OஹH2SO4()ஹHNO3Clᐗ¢Ḅᓄᔠ¤[+1¤
SஹNᙳᜐ0ᐗ¢Ḅᨬ¨¤
_ᐹᨵ9Cᓄឋ
_[Cᓄឋ⏚
ᦑB©ª5C.«¬zஹ®¯᪍ஹ±^ஹ²^ᙳo³ᔠᱥ
´^0µᱥ
ᦑC┯5D.NaO,NaOH,Na2cO3_0Ḅ¶Cᓄᔠᱥ
·[NaCl40¶Cᓄᔠᱥ
ᦑD┯஺2ᦑ⌱B஺9ஹCூ|ᫀ᪆௃Aஹ¸¹ᑁḄ»¼½NOCᓄoNO2,¾¿ÀᱥḄÀ/
ᡠÁᐭN2᣸ø¹Ḅ»¼
ᦑA©ª5Bஹᵫ0⏚ᐹᨵᢵÅឋ,ᡠᙠAlᡂḄNO¼½¶ᨵÆ/HNO3Ǽ
;ᵨ¸¹BḄ^◀É,o■ËCaO2B^g
ᵨ¸¹DḄÌ⏚ÍNO¼ÎÏHÐ
ᦑB©ª5CஹÑᱏᣚᡂᩈÕ
ᵫ0ᩈÕBÖ⏚4-g,ᡠ4ᑮ⌕ᑴᜓḄÀᱥ
ᦑC┯5Dஹ¸¹AÙÚCᓄ!"
ÁÛμÜÁᐭCOÝCOḄ³ᔠ¼
COÞ22NaOHᔾᦈálᡂNa2co3,ᙠ¼Üâᓽ;ᦈãᑮCO,ᯠáᑖ"åᧅḄÖÌ⏚çᐭA
BlᡂḄNa2cChgèéêCO2,ëᑮᑖ#ḄcḄ
ᦑD©ª஺ì⚪©ª|ᫀoC஺10ஹDூ|ᫀ᪆௃í⚪ᑖ᪆Aஹîïᵨ²¼BÚCᓄ!"gᑴð«¬"
©ª5Bஹ²¼BÚCᓄ!"g
ᑮëa
ñ²⏚᪷#$B²⏚᪷#$Ḅóô+
õḄÀᱥ[²ᓄஹñ²⏚ஹ²⏚
ÅlgḄ#$ö[CI2+8OH=6C1+C1O+CIO3+4HO,ᡠ!"ᕈ1ឋ
ᑣ!"#$óḄᜧøᐵù[c(Na+)>c(CD>C(C1O23')=c(CIO-)>c(OH-)>c(H+),©ª5Cஹ᪷úûü;i
t2t4,CUT#$Ḅᱥ=Ḅ/ý
CKh-Ḅᱥ=Ḅ/þq
᪷úCᓄ@Agÿ
ᐗᓄᔠᨵᓣᑣᨵ
ᡠᓄḄ3CKT=2C+CK)3
Dஹ!"#ᨵ$%⏚᪷()
*ᐭ,-⏚
ᑣ%().$%⏚᪷()ᙠ⏚ឋᩩ23456
ᡂᨵ89:%9
ᦔ<
┯>
?ᫀ⌱D஺ὃDEὃF!ḄᑴH56
IJKḄᑖ᪆
NᓄO56ᳮQḄ6ᵨ11ஹDூ⚪UVW௃A.ᔾZ56
56ᱥḄ\]^_ᡂᱥḄ\]
56"*ᐭ`ᓄᑺ4bᓄ
.Jcd
A┯>B.eNᓄfgh-⏚
-⏚i_j⏚
0.0100mol/LHCl,HC1klḄpHm2,nJK"pHm1,ᡠo-⏚Ḅ,pmO.lOOmol/L,qrst
B┯>C.uv⏚*wxW
(),pyᜧ
{ᵯ}yj
~ᑮ⊝*ᐭwv⏚ᵯ(
(),p^{ᵯ}^
Jdᔠ(),pᓄ
{ᵯ}b>a>c᪷ᵯ(
aஹbஹcDv⏚Ḅᵯ(pEaD.4co(g)+2NO2(g)=N2(g)+4CO2(g),ᙠᐸᩩ2cḄ3yᜧl56ᱥCOḄᱥḄ]
Nᓄᓄ᳛yᜧ
NChḄᓄ᳛Ec>b>a,D

13?ᫀ⌱D஺12ஹDூᑖ᪆௃ᵫJ
ᵯWM"ᵯ᩽m▢᩽
▢᩽¢w£ᵯ)ᡂH2¤OH56¥mE4HO+4e=2HT+40H,ᧇ"Ḅ§᪷()¨©bªᐭ«¬
«¬"ON¤NH56ᡂNH3H2O஺22N"m□᩽
□᩽¢wᜫᵯ)ᡂCh¤H+,56¥mE2HO-4e=OT+4H+,ᧇ"Ḅ¯⏚᪷()¨©22cªᐭN
N"H+¤NO56ᡂHNO3஺ூ⚪UVW௃A.N"m□᩽
□᩽¢wᜫᵯ)ᡂ02¤H+,ᵯ᩽56¥mE2HO-4e=OT+4H+,ᡂ22e()
e(),py*
°N"¯⏚x!,pa%B.ᵫ⚪²ᑖ᪆aஹcm▢()³ᣚª
bm□()³ᣚª
ᦑB┯>C.MஹNᑖµ«e9¤N9
ᦑC┯>D.«¬Ḅ56mNH+OH-=NH3+H2O,ᦑD?ᫀ⌱ED஺13ஹBூ?ᫀW᪆௃A.¶DmNaCLAmeNᓄfஹEmNᓄ·ஹBm·⏚fஹCm·⏚efஹXm-⏚
dᔠᓄᐵ¹
AB.¶Dº»⁐½¾
ᙠ¿9"ᨬÁmÂ⋎⁐ÄÅDmFe(OH)2,XmNaOH,CmFe2+,BmFe3+,AmCL,EmFe,ÆÇÈᓄᐵ¹
B┯>C.¶Dº»jÉ
AmNaஹEmN9ஹBmNᓄfஹCm©NᓄfஹXmwஹDmeNᓄf
dᔠᓄᐵ¹
NaஹNᓄfஹ©NᓄfÊ.w56
CD.¶Dº»j⏚
᝞m¯⏚
ᑣAm9ᡈÍ9
BmNO,CmNO2,Em02,XmH2O,¯⏚.Î56ᡂNO,,¯⏚.Î56ᡂNO2,D?ᫀ⌱B஺14ஹCூ?ᫀW᪆௃Ï⚪ᑖ᪆EAஹ"ឋx!"cᜧ]ÐᙠFe3+,cᜧ]ᐳÐ
A┯>BஹFe?+¤S2-NᓄO56cᜧ]ᐳÐ
H+.S2-Ócᜧ]ᐳÐ
B┯>Cஹᔜ()ᙳᜧ]ᐳÐ
CDஹ.Ö56ᡂe9Ḅx!m⏚ឋᡈὅÉឋx!
CO3ஹᙠ⏚ឋx!"cᜧ]ᐳÐ
D┯>஺?ᫀ⌱C஺ὃDE()ᐳÐ15ஹDூ?ᫀW᪆௃AஹØឋᵯ᩽ᵯWÙ⏚fx!
▢᩽ᡂe9ஹ□᩽«N9
9:ᵬ.9:ÛḄ:ÜÝÞm1:2,ᡠᵬmN9ஹÛme9
a□᩽
b▢᩽஺a᩽.ᵯßḄ᩽qà
A┯>BஹÛe9
e()áᵯ
wḄᵯ(⊝âẚä
«eNᓄf
°åeNᓄfx!
B┯>CஹåeNᓄf
()³ᣚªdm□()³ᣚª
C┯>Dஹbᵯ᩽▢᩽
e()áᵯ
ᵯ᩽56¥E2H2O+2e-=H2T+2OHேD஺?ᫀ⌱D஺

1416ஹBூ⚪UVW௃ᔠᡂÍ56"
◤⌕éᔠὃ⇋56ë᳛ஹ56ᱥḄᓄ᳛(íjîᢝᙠlOMPa30Mpa)ஹ`ᓄᑺbឋ(ðpñᑴᙠ400500࠷òó)õöḄᐵ¹ᔠᡂÍ56º÷56:ÜøḄáZ56
ᦑ*íᨵᑭ_ᔠᡂÍ9,nðcᑭ_⊝óû
üýþÿஹ
ᵨᓄᑺᦋ⊝ᦑ⌱Boஹ⌱⚪(⚪ᒹ5⚪)17ஹᵬᵬ(ᡈ4-ᵬᵬ)CHO!"#$%&ஹ'10l22()nHஹC-O-CHேjH-C00H)*ᩩ,,.<4j3QH.i)HO6n,c_t+(n2“qcHrO-cH,OHCH,7B9?@ஹCCHO9?⏣ஹD9?᪷567ঞ>7E9CC-O~fH-CH/HO,D~^~?)H1/110IJKLMNᓄOᡂOHOHFlf^O^H-CHMOOH),FQO!"#OᡂG(H,C-0-CH-CH-€(>OH)»᪷5Jᑖ&R᪀TUᨵ3WXᐗZOH>7G[HC1QO\ᡂ"#$%&\ᙠ'^_`aOᡂH9H
C-O-CHbH-COOH,Hᙠcឋᩩ,eQOCIfg"#h⏚ᓄOᡂI9ᔥH-COOH,kᑖ&Iᙠlm⏚nᵨeQOᡂoᓄ"#OᡂZoJ9OHOᑁCHQCH,஺IOூ⚪qrg௃(1)AḄᓄtuv9ᵬᵬ(ᡈ4.ᵬᵬ)xEḄᓄty9CioH]?஺zx(2)FfGḄ"#{|9!"#Hᑖ&T}~Ḅuv$%&ஹxoT(3)JḄR᪀y9"'CO'஺CHr<>CH,

15(4)Iᙠ)*ᩩ,eQO"#OᡂᱥḄᓄt"#;y9()nHஹC-O-CH^H-C00H)*ᩩ,.m50H(.l)H2O1+n;0,1cHj-y-y4*H,(5))KGḄ)ᱥᑖ&G14,KG)W)CH2)᪷5⚪7KḄᑖ᪀ᑖ&TUᨵ<᪷5ᑖ&y7#ᨵ``ᓽᨵ)OH<)CH=CH-CHOᡈ'I¡ᙠZaCH0ᑖ¢£ᑮ3ᑖ᪀ᦑ¥ᔠᩩ,Ḅᑖ᪀ᨵ6ᐸTHOQ-CH-CH-CHOḄ᪶©ᐳ«¬ᨵ6W®®☢°±92.21.11.1஺COOH18ஹ²ஹ'%"#ClHsC—2—O——/2—CH-COOHᡈ…NH2IOCHOoCOOH°2sochCHOᓄᑺ/´cooii:CH3CH3CH3)*ᩩ,_Lo^yiicooH0H)Q.NH2O/OxHC—C2-—NHHN-43ூᑖ᪆௃AI⏚ឋ═⏚¶LMNᓄ9B,BQO²ᓄ"#(·¸"#)OᡂC,CQO\¬%"#OᡂD,D~½ᨵ)W'QO·¸£ᑮᨵ¾¿ÀᱥX,XḄR᪀y

16COOH(4)HḄ9ᱥXᑖ᪀:ᨵ2᷊¡<1¢¡ᑖ£[GOH“N04,ᑖ¤ᡂFII,NCOOHICHaD¥2¦xHḄᑖ§᪀1ᨵ¥¨Xᐸ:ª«ᑡᩩsজ¬(a-¢¡⏚XᨵpᓝpC0°Hᡈ-°)8°HNHQঝ±,²³Xᐸ²³´ᱥµpuFeCb¶·±,¸⁐Xº»0¼½¾0ᡈ¾jpH3c—C-0—H—Cߟ0—ঞᑖ:ᨵ6¨ᓄ»᛻ḄÀXᑖ᪀ᨵpqḄÁÂឋO——/ᑣÄᔠᩩsḄHḄᑖ§᪀1᪀Æ£[H3C—2—0——:—fH—COOFIᡈNH20._,CH311τH—C—OߟC2—C——COOHNH2r´Qx/OমÈCHO<Éஹ[xᧇᑴᜓ/=\XÐÑ00æp(<(ç±,èéCHO113c/<
—NIIIIN-\/—CH3NH2Ok/Ot,ᡂuX,%uzÒpu
ÓC"°Ôᓄvᓄt,ᡂf0°ÕXCOOH|5

1719ஹᳫÂÃÄÅᔾᦈÈ"#ÉḄ$Ê<Nᓄm■ÌÍÎÏÊx■ÌÏÊTfÐÊÑᐭᵬ
SO£Lfg⛳<ÔÕfSO2cl2+401T-SOÖ+2C×+2H2஺জঝঞÐ✂B2S0C12+4e-=4C×+S+S02t┞ÛÜÝÞ᧕[0ஹO2"#xSOC12à>[f"#ூ¹ᫀg᪆௃1᪷5âᘤḄ᪀⌼>ᑨæçèᵬTâᘤAḄuv9ᳫÂÃÄÅx2
âᘤBTéêḄëìcíᮞ■ÌÏÊTḄfÐÊÑᐭçèïᔾᦈᢵQñ!ḄNᓄm<$Êx3
çèòTéêḄóᑺ⌕õ$Êöᐭ÷ø"#çèᡠú~Lg$Ê#9⛳<ÔÕfx4
ᙠûüýnT◤⌕ÿḄ⚗ᨵজᐜঝᑴ᳛᠒ঞ⚠!"〉$%&ট()*+⚠ᔲᑣ.*ᑖ05
1ὅ345Ḅ6789:;ᜧ"=>?@ABCᑖD>EᱥᙠHIᩩKL*+MNᐰPQRᡈᢵᡈᑖ0UVᓾX*YZ>[\56]*^⁐`ab6cdef56ᕈ⏚ឋ>[\56*ᐭBaCL56Ekl⁐mnofpᨵH2s046
ᵫrPQ"sSOCLᙠt᩽vᵯxyz{kᡂS,}~ᨵkᡂSO2ᵯᙠஹḄᩩKLBC┞᧕H2Oஹ஺2PQSOC12"PQ஺ூ⚪0௃1
᪷ᘤḄ᪀⌼"ᑨᵬᘤAḄ3ᳫᦑ¢ᫀ3¤ᳫ2
ᵬ¤SO+C12^=^SO2C12,1ᓄ¦ஹ§3ᨵ¨Ḅ⏚ឋEᱥ¦⏒§.0ᡠ«ᘤB¬Ḅ®2¯°±ឋᱥ²±`ᮞᔾᦈ¶PQNḄ§·1ᓄ¦■¹º»¼■¹¼?Bᐭᵬ½SO2c120ᦑ¢ᫀ3¤ᔾᦈ¶PQNḄ§·1ᓄ¦■¹º»¼■¹¼?Bᐭᵬ½SO2c120஺3
¾¬Ḅbᑺ⌕Á§ÂᐭXÃPQᡠ«)50§Q3⛳·ÅƦ⏒§ÇᓄÈPQḄDxÉÊË3SO2CI2+4OH=SO2+2C1+2HO,ᦑ¢ᫀ3¤⛳·ÅÆSO2CI2+4OH=SO2+2CI+2HO.42424
ᵫͦ⏒§ÎᩩKL3⁐6ᰚ83-54.1C,78369.FC,ᙠÐѼ“Ó”100࠷«ÕÖ×ᑖ0kᡂ1ᓄ¦·§ØÙ.kᑖ0ÚÛ3ÜÝÞßà¦⏒§ḄE᳛ᙠßàáâ◤⌕äḄ⚗ᨵজᐜঝᑴ᳛᠒ঞ⚠!"〉$%&ট()*+⚠

18ᔲᑣ.*ᑖ0ᦑ¢ᫀ3¤জঝঞ஺5
জ1ὅ345Ḅ6789:;ᜧ"=>?@ABCᑖDᦑ¢ᫀ3¤?@஺ঝ§å⏚CISOaH
ᑖ0PQ32C1SO3H=H2SC>4+SO2c12,>EᱥᙠHIᩩKL*+MNᐰPQRᡈᢵᡈᑖ0UV,ᓾX*YZ>[\56]*^⁐`ab6cdef56ᕈ⏚ឋ>[\56*ᐭBaCL56Ekl⁐mnofpᨵH2sh,ᡈ>PQXḄEᱥçè*BCL56ᨵl⁐mnefpᨵ¦⏚᪷Dx]*^⁐`ab6cdofpᨵH2s04,ᦑ¢ᫀ3¤B»6
জᵫrPQ"sSOCLᙠt᩽vᵯxyz{kᡂS,}~ᨵkᡂSO2,ᵯ᩽PQ32soeL+4e-=4Cr+S+SO2T.ᦑ¢ᫀ3¤2SOCl2+4e-=4Cé+S+SO2T஺ঝ┞ឋ²ëì᧕H2OஹPQSOCL"PQíᵯᙠஹḄᩩKLBCᦑ¢ᫀ3¤┞°ëìîï᧕H2Oஹ02PQSOCL"PQ஺20ஹ6ðÝñòᢝc■¹᎔ᔾNaOHRᔠᳮᓽ"V2:1cᑴ]*¦⏚ḄñRᔠᳮᓽ"V56cøùRᡈúûüᜫVaஹdூ¢ᫀ0᪆௃1
ᘤíNᡂXᐵ
ᔣBḄ⚠ᧅᑁᐭᡂᢝᑣ"#ឋ%&'D()*+,-*.ᐰ01ᑮ■4᎔ᔾḄ7ᵨ'E9ᔾᦈ;"SO2ஹH2sḄ7ᵨ■4=>?"@⌱ᵨNaOHBᦑDᫀ*ᢝ'■4᎔ᔾ'NaOH2
AFGḄᓄIJKL*MNa2sO3+H2sOfNa2sO4+SO2T+H2O,᪷O⚪QᡠS3TFG@UVWGᐵYM2Na2s2H2s3s3Na2so3,2Na2sFGZ[Z\ᡂZNazSCh,]◤⌕INaiSOj,ᡠ`a0CNa2sbNa2shᱥdḄefg*2:1,ᦑDᫀ*213
hiSO2Ḅ\ᡂj᳛9lmhiBn\"oḄp᠒ᩭᑨtᡠ`BuvSO2FG⌱⚗xᨵ⛳bNaHSChBv{|ᓄ}FGᦑDᫀ*c4
ᑖᧅᨵᴻlmᑴᑖᧅḄᑴ}⏚Ḅj@`ᑴn\{|ᓄ}Ḅj᳛ᡠ`*Sth᠒ᐭa0C,ᵨḄ79ᑴ}⏚ḄjᦑDᫀ*ᑴ}⏚Ḅj'5
᪷OC\ḄFG@a0CFGᑮ\FG*}v}⏚FG\ᡂ}}⏚FGḄ*Bᡈᜫaஹ┵0◤⌕Z¡¢ᵨ£¤¥ᦑDᫀ*Bᡈ¦ᜫ'ad.321ஹabedCH3OH(1)+3/202(g)=C0(g)+2H0(1)AH=-(—c+2d-a-b)kJmoHac<4S0-2e2222-+2lW=4H++S0na12.8ூ⚪Q©ª௃Da."B¬®¬¯°±²ᙠlO7mio-9mf´µPM2.59ᢣᜧ"±²¸®ᡈ¹®2.5¯º,ᐸ½ᨵ¾¯°±²ᙠ10’m10-%,f´@`ᡂ¬ᦑa¿À'b.PM2.5⊤☢Ãᜧᐹᨵᔾ▬ឋuᔾ▬ᜧeḄᨵÆஹᨵÇᱥdᦑb¿À'

19C.PM2.59È⌕ᩭÉ9ÊËᵯஹÍÎ

20ஹÏÐ;"᣸Ò¹mKÓmÔaµ᣸ÒḄÕᶇᱥᦑc¿À;d.ØÙÚÛÐ;"᣸ÒØÙÜÝÞußà?"PM2.5,ᦑd¿À'ᦑ⌱abedফâMজCO2(g)+3H2(g)y^=CHOH(g)+HO(g)A///=-akJmoF132@2H(g)+O2(g)=2HO(g)-”2=_bkJmor122ঞH2O(g)=H2Oপ-//.)=-€kJ-mol-1টCH30H(g)=CH30HপAH4=-dkJ-mor',᪷Oãäåæ33AH=-AH1-AH+-AH+2AH=-(-c+Zd-a-bJkJ.mol1,ᡠ`CH30HপÔaḄᓄIJKL*2342233CHOH(1)+-O2(g)=CO(g)+2HO(l)AH=-(-c+2d-a-b)kJ«mol',ᦑDᫀ*32233CHOH(1)+^O2(g)=CO2(g)+2HO(l)AH=-(^c+ld-a-bjkj.mol132(3)জa.4Ḅὑj᳛¹®(BOHḄ\ᡂj᳛Ḅ2éᙳ⊤ë¿FGj᳛FGìᢥîgïᐵYðuñòᑮó⊝õᕒḄὑj᳛¹®CLOHḄὑj᳛Ḅ2éZFGᑮó⊝ᦑa┯ø'b.gḄÃᑖᦪúᦋ9ᓄIó⊝ḄᱯýᑮÜó⊝ᦑb¿À'c.þ"ஹCOḄÿᓄ᳛ᱥḄᨵᐵ⊝ᱥḄᓄᓄ᳛ᦑc┯!"d.#ᔠ%&'()*+,-#ᔠ%&'ᱥḄ./ᙳ᥅23ᜧ#ᔠ%&%&Ḅᙳ᥅25ᦋ(789ᑮ;⊝ᦑd<="ᦑ>ᫀ@acঝBC<*+@%&&D./Ḅ*+3ᜧEF⊝ᔣ<*+HᔣIJcoḄᓄ᳛3ᜧᦑEFPAVPB,ᦑ>ᫀ@V"ঞ9ᑮᓄ⊝M᝱AOᘤḄ&D@20L,COᓄ᳛@50%,ᑣᓄḄCO@10molX50%=5mol,RljC0(g)+2H(g)—CftOHCg)2(mol)10200(ᓄ(mol)5105⊝(mol)5105c(CHpH)⊝UᦪK=C(C°)C”3»᳝—2?Y=4,᝞[*+\]ᐙᐭlOmolCO`20molH2,ᙠ⊝M᝱BCOᓄ᳛px(W)22020@80%,ᑣᓄḄCO@10molX80%=8mol,R!IC0(g)+2H(g)—CHsOH(g)2

21(mol)10200(ᓄ(mol)8168⊝(mol)2488Vb&D@VL,ᑣ=4,cdV=4,ᦑ>ᫀ@42pxV(4)জᙠfᧇᵯijkᐭl%Ḅ@<᩽kᐭnlᓄoḄ@p᩽nlᓄoᜫrᵯstulᓄ*+ᵯ᩽*+v@SO2-2e+2HO=4H++SO42-,ᦑ>ᫀ@SO2-2e-+2H2O=4H++SO42-2224Lঝ᪗xMyz2.24LO2ḄᱥḄ@:------=0.1inol,IᵯsḄᱥḄ@0.4mol,}ja@▢᩽tu22.4L/molsḄᵯuᡂᓫuᡂḄᱥḄ@^^=0.2moL@0.2molx64g/mol=12.8g,ᦑ>ᫀ@12.8஺