2021-2022学年山东省日照市高一（下）期末化学试卷（附答案详解）

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FN஺*H+ᓄN"38Fe2++NO]+10"+=8Fe3++3HO+2NH*,ᦑC23D.HC1OᓄNHjḄy⏚ឋ¢᛻ᑣy27/7¤+3HC10=M+3Cl-+5H++3H2஺ᦑD┯ᦑ⌱5ACoᵫL▢᩽_ḄHCFe§ᓄFe®,FeB
FNO*H+ᓄNH5,¨©NHjªHC1OᓄN2,□᩽_2c«-2e-=ClT,ᯠ©C0+®஺=“஺+HQO,2±jᑖ᪆l⚪஺o⚪ὃrᵯl²Ḅ³%Cᳮᵯ᩽yḄµᑏᑁ¸ᒹºᓄ»CyḄḄµᑏᵯ᩽yḄᑖ᪆ᑨv⚪½஺P16⚓ᐳ22⚓

1616.ூmᫀ௃PTᕜ?P4A12HA6A6AH4(0")3+஺”-=[4(0")4«N2HL••••4e-+40H-=N2T+4H0NaHS0HSO^+Br+H0=SOe+2Br~+3H+2322ூl᪆௃l5ᵫᑖ᪆AHஹBCஹCNஹD0ஹENaஹFAlஹGSiஹHS+(1)”Sᐗ;ᙠᐗ;ᕜ?⊤ḄOÂPTᕜ?Pᓛ4Aᙠᐗ;ᕜ?⊤ᐗ;4()ᡠᙠ@AᜐP1ÆU$ᐗ;Ç(4)ᡠᙠ@AᜐP13ᑡᙠPÉᕜ?IAAFEL4AḄÊᐗ;CGᦪËÌ12.ᦑmᫀ5PTᕜ?P{A12+(2)4ᐗ;Dᐗ;ᵫibᡂQÍ“Î⁐ᓄᑺ"X/஺2,ᐸᵯH58565H••••ᦑmᫀ5H56565H••••(3)EஹFḄᨬ.eᓄᱥÖyᓄᱥᑖ×NaOHஹAl(OH),¨ØyḄh34(0H)3+OH-=[4(஺”)4«ᦑmᫀ54(஺")3+0$-=[4(஺)4«(4)ÙYᨵ18cᵯḄC(Û)ᐗ;ḄᓄᱥᑣYIN2H4,EḄᨬ.eᓄᱥÖyᓄᱥNaOH,ᵨÜឋᵯ᩽ஹN2H4ஹÝNaOHḄÞßàáᡂâᧇᵯ²ãᱥÖ¢᛻äåᑣN2H4âæᡂN2ç᩽Øᓄyè/ᙠç᩽ᜫêᵯëឋᩩí0ᡂN2ᑣç᩽Ḅᵯ᩽yN2“4-4e-+40H-=N2T+4HO,2ᦑmᫀ5N2H4-4e-+40H-=N2t+4H0+2মᵫHஹ0ஹNaஹSᢥCcᦪð1A3A1A1bᡂQÍᓄᔠᱥZ,ᐸᓄñNC1//SO3,ᔣZḄÞßóᐭ〉ö÷øᑮúû⁐+yḄhHS஺*+B/2+H0=S0l~+2Br~+3H+,2ᦑmᫀ5NaHᫀ3+HSO3+Br+H0=S01~+2Br-+3H+.22AஹBஹCஹDஹEஹFஹGஹHüÍ@Aᐗ;ᑖýᙠTc(þḄ=ᕜ?ÿḄᦪᜧAḄᦪᨬᦑAHᐗᐸEḄᙠᕜᐗᨬᜧᑣENa+ᵫᦪBஹCஹDᜐ"#$ᕜ%FஹGஹHᜐ"#&ᕜ%DஹH'(HḄ)ᦪ*DḄ2+ᦑD0ᐗஹHSᐗ஺(.)Ḅᨬ᜜1ᵯᦪ*Fᨬ᜜1ᵯᦪḄ2+ᓽFᨬ᜜1ᵯᦪ3,ᑣFAl+BஹCஹD(.)4"'ᕜ(56ᦑBCᐗஹCNᐗBஹG'ᑣGSi஺7⚪ὃ:;ᔠឋ)4>ᐵ@AᵨCDᐗ*E⚪ḄᐵFGHIJᐗᕜ⊤LᐗᓄᔠᱥO⚪PQRὃ:STᑖ᪆CᳮXYஹZ[ẠOḄIJ]^஺17.ூaᫀ௃de⏚—0Hஹ-CH஺gᡂiAjklm⏀ᓄ⏘ᜫqrឋiAs᳛uvAC

17[X^>CHCH,BrILC1LOII;+NaOH+NaBrxCH-CHCH.Br,/CCl4,NaOH/HQCHCHCH,xOHOHூE᪆௃E(1)E(]-CH2coOHEḄde⏚F*ℍ⃔ℍ⃔XḄ;᪀*஺“ஹ-CHO,ᦑaᫀde⏚—஺“ஹ—CHOJ(2)4-8iAgᡂiAFtGiA¡¢£ᑴjk¥Xlm¦*jklm⏀ᓄ⏘ᜫqrឋiAs᳛uvᦑaᫀgᡂiAjklm⏀ᓄ⏘ᜫqrឋiAs᳛uv(3)48*¨©—€:11=஺}{2,¯"°✏²¥᧕´"µ᧕´"ᨵ·´ᑺᦑAº»B.dḄ'@ᱥd¼Q½¾[O—CH=CH2¥X*dḄ'@ᱥᦑB┯ÀC.d¼ஹÁÁÂFXLÃÄÅTgᡂiAÆᩩÈÉlmol()_CH=CH2ᨬÌXL4mo1%ÅTgᡂiAᦑCº»-£CH-CH3JD.ÆᩩÈÉd-CH=CH2ÐÅTgÑiATᡂ6*ᦑD┯ÀᦑaᫀAC(4)C-஺ḄᓄSiAÔÕILCILOHÖ×஺3+NaBr'xILCILOIIᦑaᫀ[0^"HÛ,NaOHÜ+NaBr(5)dLÞᯋÅTgᡂiATᡂ(D-CH=CH-CH3,ᯠáLâÅTgᡂiATᡂHjHCHj,ᨬáᙠÃ.ᓄãµ´äஹgåᩩÈɵETᡂCFCHYÖᔠᡂçè^^r-CH-CHCH,BrCC1NaOH/Hq43xᦑaᫀ:CHCCH-(0J-€H-CHCHBr/CCLNaOH/HOOH”3#18⚓ᐳ22⚓

18dLeᯋÅTgᡂiATᡂdeïdeïLHBrÅTgᡂiATᡂGyCHðCHpr,ñòCH^CHprÅTµEiATᡂDñ$òCH2cH20H,de⏣ôõ.ᓄTᡂE,%ELGiATᡂde⏚eö÷IJEøL-CH2coOHஹGICH3cH2OH,ùúµETᡂFℍ⃔ℍ⃔û⏀ᓄ⏘ᩩÈÉTᡂe⏣(5)dLÞᯋÅTgᡂiATᡂO-CH=CH-CH3$ᯠáLüÅTgᡂiATᡂ|Q]-^H^HCHᨬáᙠÃ.ᓄãµ´äஹgåᩩÈɵETᡂ3in7⚪ὃ:ᨵ·ᱥḄCDLᔠᡂýþᨵ·ᱥÿஹஹᨵஹᩩḄᑖ᪆ஹᨵᱥ᪀ឋஹᨵḄᑏஹᔠᡂ"#$%&'ᐙᑖᑭᵨ+᪗ᱥ᪀-ᩩ./ᑖ᪆01'⚪+34ᙢὃ789:ᑖ᪆0ᳮ<ஹ=>?@ᵨḄ<஺18.ூDᫀ௃ឤHIJKᧅNOPQaRSTU(஺”3஺஺)2஺+“2஺-2CH3C஺஺//ᑭZ[⏒Rᩰ⏚ᨔ᪆`72.2%aᨔூb᪆௃bc(1)dᘤAḄfgឤHIJKᧅ'ᦑDᫀicឤHIJKᧅj(2)dᘤBgᳫlNOm'nᵨgNOPQ'op.R'qp`R'ᑣ.Rpia,ᦑDᫀicNOPQjaA(3)RSTUḄstguUᙳ'wZxᑴz{j|}xᑴz{ᙠ7(TC'⌱〉ḄTUiRSTU'ᦑDᫀicRSTUj(4)|}ᡠᨵdᘤ◤⌕./ᜐᳮ'g[⏚⏊«%஺஺)2஺⍗R᧕:ᡂ[⏚'ᐸḄᓄ9ic(C/CO%஺+H2012cH3COOH,ᦑDᫀic(஺“3஺஺)2஺+“2஺-2(?”3஺஺஺'j(5)ᑴᜓᔠᱥ᎔ᐭNR'+ḄgᑭZ[⏒Rᩰ⏚ᨔ᪆`'ᦑDᫀicᑭZ[⏒Rᩰ⏚ᨔ᪆`j(6)6.9gRᩰ⏚ḄᱥḄ£i13¤““=O.OSmol,¥ᑴḄ[⏚⏍Ḅ£i10mLx1•087஺5-3=10.87g,ᱥḄ£i§*=0.11m஺''[⏚⏊£'ᢥRᩰ⏚%«ᳮ¬q:ᡂ[⏒Rᩰ⏚Ḅ£i0.05m஺'x180g/mol=9g,ᑣ|}Ḅ®᳛i°x100%=72.2%,±⌕²ᑮ´{µ¶Ḅ[⏒Rᩰ⏚ᨔ·'ᵨZ¸´Ḅ¹iaᨔ'ᦑDᫀic72.2%+aᨔ஺(1)dᘤAḄfgឤHIJKᧅj

19(2)dᘤBgᳫlNOm'nᵨgNOPQ'op.R'qp`Rc(3)RSTUḄstguUᙳ'wZxᑴz{j(4)|}ᡠᨵdᘤ◤⌕./ᜐᳮ'g[⏚⏊(C/C0)2஺⍗R᧕:ᡂ[⏚j(5)ᑴᜓᔠᱥ᎔ᐭNR'+ḄgᑭZ[⏒Rᩰ⏚ᨔ᪆`j(6)[⏚⏊£'ᢥRᩰ⏚%«ᳮ¬q:ᡂ[⏒Rᩰ⏚Ḅ£'®᳛=º»x100%,ᳮ,-.±⌕²ᑮ´{µ¶Ḅ[⏒Rᩰ⏚ᨔ·'ᵨZ¸´Ḅ¹iaᨔ஺⚪ὃ7[⏒Rᩰ⏚Ḅᑴᜓ®´{Ḅ¼½'¾aὃ79:|}¿ᔠ<'À⚪Á{&஺19.ூDᫀ௃+226.7CD0.625ÂÃ30%ÄUÅ·Æz{ᓣ¶'ᓄ9È᳛Éᜧgூb᪆௃b:Ì(1)ᵫ⚪Î=জC(s,Ð)+O2(g)=CO(g)QH=-393.Sk]/mol,2ঝi(9)+Ò2(஺)="2஺஺)Ó“=-285.8kJ/mol,ঞC2H2S)+|஺2(஺)=2CO()+25“2஺(1)QW=-1299.5fc//mo/,᪷Ö×ؽÙ2জ+ঝ-ঞ²2c(s,Ð)+“2(g)=C2H2(஺)Ó"=+226.7kJ/mol,ᦑDᫀic+226.7+(2)জ4ÜᨵÝÞgßÈ᳛'àg⌮ḄÈ᳛'â¹ᑨ1gᔲåᑮæ⊝'ᦑA┯éjB.êëìí·îᱥḄ£ÂÃ'ïᘤ·ðÂÃ'ᦑgᔲåᑮæ⊝'HñÂÃ'HñÂÃâ¹ᑨ1gᔲåᑮæ⊝'ᦑB┯éjC.ëìí·£ᦋÃ'ïᘤ·ðÂÃ'ᦑí·ó{ÂÃ'åᑮæ⊝'ᦑCßôjD.ëìУᦋÃ'ᦑУÂÃ'åᑮæ⊝'ᦑDßôjE.1õH-Hö÷':ᡂC-Högøùß'â¹ᑨ1gᔲåᑮæ⊝'ᦑE┯éjᦑDᫀicCD+ঝḄÐḄᱥḄ£ri=*=úc☠º=12.5mol,ᵫ2c(s,Ð)+/ভ42H2(஺)=2c(Ð)
/'ᦑü÷ýḄᱥḄ£i6.25moZ,þý)=ÿ=ᘵ=ᦑᫀ0.625+0.(3)জឤឤᐙᐭឋᦋᱥᡂᱥḄᦑᦋᓄ!"᳛ᦑᫀ$ঝᵫX(g)+3Y(g)U4Z(g)'X
4Z,ᑣ)1.2znᵫᱥ*Z+,ὑ0.3ᔣᱥ*X,XḄ/ᓄ᳛01x100%=30%,Imolᦑ2ᫀ30%+(4)জ34565ឤᩩ89:ḼḄ<=45>?ᓣA20⚓ᐳ22⚓

20Dᓄ!"᳛Eᜧᦑᫀ45>?ᓣDᓄ!"᳛Eᜧ$ঝ3GHIJᙠ65ឤᩩ89:ḼḄ<=45>?ᓣDLMEᜧᦑNLMOᓄ+3PᑮR⊝ᦑᫀT஺Vপᵫ⚪YZজCs,[\]+஺2஺]=CO2SAW=-393.5kJ/mol,ঝ஺_9+3஺2஺]=42஺_1Q”=-285.8kJ/mol,ঞC2H2஺]+1஺2஺]=2C0+WO1Q252H=-1299.5ᑜ/mol,᪷abcdef$2᪷ag⌮ᔣijᩭᑨmTᔲPᑮoR⊝p᝱$ঝᐜstuḄ[\Ḅᱥ*ḄgO᪷avwḄᔜᱥ*Ḅᱥ*Ḅgyzj{ᓄ!sgᦪyzstuḄᱥ*Ḅg}ᐭ~/]=2=ᓽ$0.3জឤឤᐙᐭឋᦋᱥᡂᱥḄᦑᦋᓄ!"᳛$ঝ᪷avwḄᔜᱥ*Ḅᱥ*Ḅgyzj{ᓄ!sgᦪyzᵫ)ZḄᱥ*Ḅgstu,ὑᱥ*XḄᱥ*Ḅg}ᐭ/ᓄ᳛~ᓽstuXḄ/ᓄ᳛$4জᓣDᓄ!"᳛Eᜧ$ঝgᓽPᑮoR⊝p᝱஺⚪⌕ὃᑭᵨbcdest5ஹᓄ!R⊝p᝱Ḅᑨmஹᓄ!"᳛Ḅstஹᓄ!R⊝ḄstjZD⚣ὃ⚪஺20.ூᫀ௃A+4e-+2H2஺+4Lt+=4LiOH4AICI^+C-e-=nCAlCl1.5n4ூ᪆௃14⏚ឋ═ᵯ£Zn¤⏚¥¦§᧕©ª4ᵯ«ឋᩩ89Zn«©ᦑA¬$B.ᵯ£f+ᵯ®0᜜ᵯ°ᵫ±᩽³ᔣ᩽ᵯ*ᑁµᑣT▢□¸®Ḅ¹ºᦑB┯¼$C.«ឋᩩ89Znᜫ¾ᵯ®ᡂZ/+¤¿À᪷¸®±᩽Ḅᵯ᩽ᡭ1-2e-+2OH-=ZnUOH>ᦑC┯¼$2D.±᩽6.5g+ᓽvwḄ0.17HOI,ᑣ/¹ᵯ®OZmoE,ÂÃÄḄ□᩽᝞ÆÇᨵCu4ᵯᜫᵯ®Éaᵯ®Êឤ,ὑḄCuT6.4g,JᵯÂÃÄ+ËÄÌ□᩽□᩽ÍzÄÎÏḄᐸÑÒÓÔᜫᵯ®Õ,ὑᑣ,ὑḄ*gÖdT6.4g,ᦑD┯¼$ᦑᫀA+2জ┞-Ùᵯ£4┞]T±᩽B_ÚÛᵯ᩽]T᩽ᐙᵯ+4┞]▢᩽B_ÚÛᵯ᩽]□᩽§ᵯÜ᩽ᦑᫀ$

21ঝwᐭÝHLiᜫ¾ᵯ®ᔣ᩽¹º᩽)Ḅ0H-Þᔠᡂ¿Àᓄ┞᩽ᵯ᩽஺2+4e-+2HO+4Li+=4LiOH,2ᦑᫀo+4e-+2HO+4Li+=4LiOH22(3)জ4ᵯ+ÒÓT±᩽ᐙᵯ+T▢᩽ᙠᵯ£à□¸®ᔣ▢᩽¹ºᦑᫀ$ঝÉa±᩽Ḅᵯ᩽4+TAICI4-3e-=442c5$Zá,ὑImolAl,ᡂ4molAlCl^,2ᦑᫀ4+ঞ[\ᵯ᩽T᩽᩽+e-=AlCli+C,ᑣ□᩽ᵯ᩽nAlCl^+C-e~=CAlCl^>nnᦑᫀAlCl^+C-e~=CAlClinn4(4)ᵫḄᵯ᩽-28e-+11HO=6CO?+28H+,ZNᨵ28mol22ᵯ®/¹+ᡂ6ã0%஺2$ᑣ/¹7moiᵯ®+ᡂ1.5ã0%஺2$ᦑᫀ1.5஺(1)«ឋ═ᵯ£àᜫᵯ®Ḅ᩽±᩽±᩽©Àᓄ±᩽ᵯ᩽271-2e-+20"-=Zn(0H)2$'ᵯ®Ḅ᩽᩽᩽©äå᩽ᵯ᩽MnO2+e-+“2O=MNOO”+OH-,ᵯ®æ±᩽0ç᜜ᵯ°³ᔣ᩽èéᵯ®/¹Ḅst⌕ᵨᵯ®Êឤ$(2)┞-Ùᵯ£,4(┞)T±᩽,B(ÚÛᵯ᩽)T᩽wᐭÝHLiᜫ¾ᵯ®ᔣ᩽¹º᩽)Ḅ஺”-Þᔠᡂ¿Àᓄ┞$(3)¸®ᵯ£,4ᵯ+,ÒÓT±᩽,ÕÀᓄᡂ42஺îᵯ᩽ïð4+7AICI^-3e-=4AlClj,[\ᵯ᩽T᩽᩽3G4஺4+36-=34஺o+3Ḅ,ᑏ2lᐙᵯ+□᩽Ḅᵯ᩽ᑣ◤⌕ó᩽ᵯ᩽ô᎔çᩭ$(4)ᵯ+ö÷/ᓄᡂCO2Ḅᵯ᩽C6H5஺"-28e-+11HO=6COT+28”+,22ᡂùÀᓄúḄᱥ*Ḅgᵫïð<=st஺⚪ὃåᵯ£¤ᵯ£Ḅfåᳮ,ᒹýåᵯ£ஹ±᩽Ḅᑨmᵯ᩽Ḅþᑏᨵᐵᵯ
Ḅ⚪஺22⚓ᐳ22⚓