2021-2022学年河北省衡水高一（下）月考化学试卷（3月份）（附答案详解）

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2021-2022
ᓅḕ⊝ᓝᨴὃᓄᔁ3ᨴ1.᠒᠒ᐭᑡᱥᐸ!16஺#ᔆ1ḄCiiS஺4&'Ḅ(ᵯ*+ᓄ᝞-ᡠ/ḄA.01B.NaClᨔ3C.KOH&'D.Ba0H2
2.ᑡᵯ456789Ḅ:A.Al(S0)=Al3++SO^~B.HCO^2H++COj-24323C.Ba(OH)=Ba2++(OH)D.NaHCO=Na++HCO^233.ᑡᐵ<=஺2஺஺3>NaHC/Ḅ?@A89Ḅ:A.NaHC%BCᑖEFᡂḄHIᱥᙳK

1C.3.01x1023Ës02ᑖmḄ©!32gD.C4Ḅ᥅©!16g9.ᑡᐵ<ᱥḄ©⊤¹89Ḅ:A.100mL0.3mol-LḄNa2sO4&'Na+ḄᱥḄ©!0.6mo஻LB.10࠷ài00mL0.35mo/LḄKC1⛳>&'0åᣵ5gឮèᑮ10࠷àᐸ3Ã`<100mL,ᱥḄ©ᜧ<0.35mo஻LC.ᙠ/5஺4>NaClḄឋ¤ᔠ&'᝞ìNa+>SOî-ḄᱥḄ©MïᑣK+>CᔆḄᱥḄ©ñMND.1LḄᔾᦈ22.4Lô³᪗ÀàᡠyôḄ:Imo/•ᔆ௃10.÷ø⊤/ùúûüZᦪḄþᑡ⊤¹A89Ḅ:A.᪗¾¿À22.4Ld³ᡠÿ
ᦪ2MlB.5.4gᡠḄᑖ
ᦪ0.3MlC.Imol⏚Ḅ⏚᪷
ᦪ2!D.Imol#$%&'(ᜫ*Ḅᵯ
ᦪN.11..ᑡ0ᢈᡂ34⌕$6ᓄ8Ẇ:ᶖḄ=>A.ᑭᵨBCDEFG“Iᑴ”LMNFGB.OPQRᙢᳫḄU□W᜜YZC.[
\]^_.`abD.OPᵫdᓄᔠᱥᑴghiḄ`ᢈj12.#$%ᙠlimnopqᨬstᡂᱥ=>A.NaOB.NaOC.NaCOD.NaOH2222313..ᑡᐵ6yḄz{q|}Ḅ=>A.`ᑴy~Cl?HC1Oᑖ
B.`ᑴy⁐ᐜ⁐C.ᐝ᯿yᨵiᑈqiC*2D.yopᦪᜩqpHᜧ14.ᑖQYᨵᦔஹ¢ᓫ᧕YḄ08¥஺§¨8ᵨ.⊤ᡠª«¬ᡠ8®¯°YᑖQqᐸᵬ&³ᒹᐵW஺.ᑡᔜ¶q|}Ḅ¶ᔠ=>ᵬ³AÀÁᱥyஹÂᡭஹÄÅஹÆÇÈBÉNa2CO3.NaOHஹKOHCᵯËÌCaCO3,NaClO,Î⏚DÉឋÐᓄᱥCaO>NaO>KO222A.AB.BC.CD.D15.᪷·᝞¹ḄºᓄᐵW»P¼q.ᑡ½{┯¿Ḅ=>Ò2⚓qᐳ16⚓

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¥í¬C/++2OH-=Cu(OW)1216.20gAᱥÌ14gBᱥÌាùúᐰ'(qtᡂ8.8gCᱥÌஹ3.6g஺ᱥÌ0.2mo/EᱥÌ,ᑣEᱥÌḄ᥅
()A.100^-mol-1B.108^-mol-1C.55g-mo/-1D.96g-mol-117.ᢣᑡᑜᐗḄᓄᔠ#$NaOஹNHஹCa(Q0)2ஹHSO^஺22318..ᨵᑡ80ᱥ
$জ஺2ঝ5ঞ“2஺@co2ঠH2s஺4ডFe(OH)39:ঢ஺12“22஺1<ⅅ>)ণNaCl?@(1)ABCᔜᱥ
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ḄúḄ?@ḄùÝᘤqᐸB᪗ᨵ$জüঝúঞéটýþঠÿ
⚗Ḅ஺A.জঞঠB.ঞটঠC.জঝটD.জঝঞ4⚓ᐳ16⚓

4(2)◤ᑴ5007nLlmoZ"TḄ⏚◤ᵨᑖᦪ98%ஹ!l.84g61"3Ḅ#⏚mLo(3)$%&'ᘤᢥ⚪(2)+,-ᵨ◤⌕⌱0'ᘤᐸ23o(4)-ᵨ45Ḅ6789:;Ḅ<=>o(5)?ᑴ@Aᔣ67CDEFGᨵIᣵᙠ67᜜☢9᝞OᜐᳮRo(6)+,ᵨSᜮIUV6W☢XYḄ>oB.—yC.XD.D?+,⍗ᑮ\ᑡ^_`⏚ḄᱥḄ#bᨵOcdR(fgh23)A.jkB.jlC.mcdজno#⏚pqᓾsV6oঝ67ᨵtuvwO

5xᫀz{᪆1.ூxᫀ௃Dூ{᪆௃{ACiiSO,ᐭuvwl▢ஹ□Ḅ#ᵯᦑA┯B.NaClᨔwᵯஹᜧ▢ஹ□#ᵯᦑB┯C.CuS஺4ᐭKOH᪷¡9¢ᡂᓄ¥¦§ὑ©Eªᐭ«¬ᵯ₹®ᦪ¯°F±Ḅ²ᶍᨵᜧḄᵯ¯°F±ᦑC┯D.CuSCUᐭ8a(஺“)2µCaSCUBa(0H)2¡9¢ᡂ⏚¶¥¦zᓄ¥¦·-▢ஹ□#¸ᵯ¹⏚¡9ºᐰW¼ᐭBa(0H)2#ᜧᵯᦑDXYᦑ⌱D஺ᵯḄ½⌕¾¿▢ஹ□#Ḅᜧ¸#ÀᜧᵯÀÁÂᑖ᪆஺°⚪ὃÄᵯ{Ḅᵯឋ⚪ÆÇÈÉÊ$¡9ḄËÌᑖ᪆ᵯ{▢ஹ□#Ḅᜧ¸#ÀᜧᵯÀ஺2.ூxᫀ௃Dூ{᪆௃{4ᵯ₹FÍឤஹÏFÍឤᵯÐAÑÒ2(5஺4)3=24ᡝ++350ÕᦑA┯B.Ö⏚>×ᐗ⏚ᑖÙᵯᵯÐAÑH2c஺3="++HCO^HCOs^H++஺0ÚᦑB┯C.O/TÛᑏFÝᵯÐAÑBa(0H)2=Ba2++2O/r,ᦑC┯D.NaHC/ᙠwºᐰᵯ¢ᡂNa+ஹHCO^,ᵯÐAÑNaHC/=Na++HCO3,ᦑDXYᦑ⌱D஺A.ᵯ₹FÍឤஹÏFÍឤB.Ö⏚>×ᐗ⏚ᑖÙᵯC.O/TÛᑏFÝD.NaHCgᙠwºᐰᵯ¢ᡂNa+ஹHCO^°⚪ὃÄᵯÐAÑḄÛᑏßàὃįẠâãḄäåzᮣçèᵨéYᵯ{ஹᵯÐAÑÛᑏÝᑣ>{°⚪ᐵì⚪ÆÇFᜧ஺3.ூxᫀ௃A6⚓ᐳ16⚓

6ூ{᪆௃{4Ö⏚íîᑖ{¢ᡂÖ⏚ஹ×ᓄÖzwÖ⏚ïCஹNaஹ0ðñᐗòFóᓄᱥᦑA┯B.ô©õ\ᙠwḄ{NaHCO

7ᱥஹ¦ᵯ4¨◤⌕ᶇᓄ*5ᔲᔠ«ᓄ¨஺6.ூ%ᫀ௃Bூ᪆௃@¬⁐¯°᣸◀C"2+ஹFe2\Fe3+.MnO7¨ᨵ⁐GḄ³ᙠ஺A.H+ஹCOgµ¶¢lᙠ¬!dᜧ·ᐳ³ᦑA┯B.NH3K+ஹC¹ஹS஺@µ¶!º⁐¬ᙠ¬d»ᜧ·ᐳ³ᦑBstC.Ag+C¼ஹSOJ¢lᙠ¬!dᜧ·ᐳ³ᦑC┯D.CR+ᨵ⁐G!½¾¬⁐ḄᩩᦑD┯ᦑ⌱@Bo⁐¯°᣸◀C஻2+ஹFe2+ஹFe3\MnOf¨ᨵ⁐GḄ³ᙠ஺A.G⏚᪷GB.ÀGµ¶!5⁐GC.ÁGÂGஹ⏚᪷GD.~Gᨵ⁐G஺'⚪ὃ*Gᐳ³ḄᑨyÃὃḄÃ⚣⚪Ũ9ḄÆ⚪tG!dᜧ·ᐳ³ḄÇÈÉ@d¢lÊᑖḄGµ¶d¢lᓄË«ḄGµ¶d¢lÌᔠḄGµ¶Í᝞Fe3+3SCN-¨Ë⚪8ᡠ◚ÐḄᩩ᝞@¬Ḅ⏚ÑឋÒᩭᑨy¬5ᔲᨵᜧ·ḄH+ᡈ0/T;¬ḄÕ⁐᝞⁐¯°᣸◀C7+ஹFez+,Fe3+.MnOf¨ᨵ⁐GḄ³ᙠ஺7.ூ%ᫀ௃Cூ᪆௃@44Ö2lᡂ×Ø3^2Al+3Cl-2AlCl,Al⏚lᡂ234cb3/BP2XZ+6HCI=2AIC1+3HT,lᡂ4C%,ᦑA!⌱32B,CuC%lᡂCuC2^Cu+Cl-CuCl,Cu⏚!ᦑB!⌱22AC,FeØ2lᡂFeCbᓽ2Fe+3C%2Fe4,Fe⏚lᡂFeC63᜜ᓽFe+2HCI=FeCl+HT,ᑖ}lᡂFeC^3FeCLᦑC⌱22D,Zn5lᡂZMC%^Zn+Cl-ZnCl,Zn⏚lᡂZnC23à22ᓽZn+2HC/=ZnC%+“2%lᡂZnC%ᦑD!⌱ᦑ⌱@CoÂáᐹᨵâᓄឋdRãäåÅᓄᨬÃä᝱⏚ᐹᨵ¦ᓄឋdRãäåÅᓄèéä᝱º⏚ê3åÅëìឋíî⊤HµðḄåÅÒᑖ᪆%஺'⚪ὃ*åÅ3Âáஹ⏚ḄtÂáḄឋ45'⚪ᐵ7Âáᐹᨵâñ8⚓ᐳ16⚓

8ᓄឋஹ⏚ᐹᨵ¦ᓄឋóôãäåÅḄ᧕┯ö⚪89!ᜧ஺8.ூ%ᫀ௃Cூ᪆௃@Aஹ4·ᓫøg,Im஺஺Ḅ4·18g,ᦑA┯BஹáL᥅aLúᭆüᑖ᪆᪗þÿ
ImolḄᙳ22.43ᦑB┯Cஹn=ᔠ3.0"1023502ᑖḄᱥḄ0.5ᑣ=O.Smolx64g/mol=32g,ᦑC!Dஹ᥅$ᓫ&g/mo/,CH4Ḅ᥅$ᦑD┯ᦑ⌱C஺)⚪ὃ,-᥅$ᭆ/Ḅᑖ᪆ᑨ2ᱥḄ3᥅$Ḅᐵ56ᐵ789:Ạ6ᐵ7⚪<=>ᓫ஺9.ூAᫀ௃AூD᪆௃DE4100F0.3m0ᔆḄNa2s஺4HIJMz+ḄᱥḄKLE0.3mol/Lx2=0.6THO//3ᦑA!EB.MLNOPOQᱥḄ⛳3HIJHIḄᱥḄKLQSNOTHIḄUᐵV0.35mo/L,ᦑB┯C.᝞XNa+3SOI-ḄᱥḄNYZ⏚᪷]ᡠ_ᵯ₹ᜧcd]ᡠ_ᵯ₹᪷HIJ▢□]ᡠ_ᵯ₹NYᡠgK+ḄᱥḄKLᜧcCᔆḄᱥḄKLᦑC┯D.1LḄhᔾᦈ22.4LkHIḄᜧc1L,ᑣᡠlkhḄKLcImo/•mIᦑD┯ᦑ⌱EAoA.ᵯDHIJ]KL=ᵯDKLxᓄopJNq]ᦪ

9D.ImoldᐰqᜫImolᵯᜫḄᵯᦪN*,ᦑD!ᦑ⌱ECoA.᪗
22.4LzḄᱥḄImol,{ᨵ2moiz|B54ghḄᱥḄ0.3C.᪷}⏚~ḄᓄoptImol}⏚~J{ᨵImolZ⏚᪷]D.d1ImoldᜫImolᵯ.)⚪ὃ,ᦪḄᨵᐵ3ᑨ2⚪NaCO-10H0=222232232Na2cO3+10HO.2ᦑ⌱ECoᑗúdûcôJᑗüúýᕈÿ⁐Ḅ☢->ᨩᡂNa2஺-⁐ᡂNaOHᡂ
NaOHᙽᔾᦈ஺஺2ᡂNazCd-10//O-ᨬᡂ210⚓ᐳ16⚓

10!"($ᓄ)ᵫ(ᑖ᪆+.-⚪ὃ01Ḅ2⌕ᓄᔠᱥḄឋ7᪷91ᐸᓄᔠᱥḄឋ7;<=>Ḅ?@.⚪ABCᜧEFGᐵIẠKLḄMN.13.ூ+ᫀ௃Bூ᪆௃U4WXYZ>UC%+HO^HCl+HCIO,HC10`a⏚WZcdᨵC%ஹ2HC1Oh`஺iᑖjᦑA┯noB.HC1;pq⁐rstuᐜwHC1O;pq⁐rstux⁐ᦑByzoᐝ᯿C.HC1OC{|}ᐝᑖ>U2HCIO—2HCI+O2,ᡂXᦑC┯noD.HC1OC{|ᑖᡂHC1,pHᦑD┯n.ᦑ⌱B.WXYZ>UCI2+H2O=HCl+HClO,HC1Oᐹᨵa⏚ឋஹᓄឋஹឋ<1C{|ឋWZcdᨵC%ஹHC1Oh“2஺iᑖj.-⚪ὃ0WZḄᡂᑖ1ឋ7⚪ABCᜧ-⚪EFIẠKLḄMNh.14.ூ+ᫀ௃Cூ᪆௃U4ᡭZஹ!dᡈὅ<ᱥ7ᔠᱥᦑAC⌱;B.⏚ᵯ▢j`⏚᪷jC¡ᦑBC⌱oC.CaCO,NaClOஹ¥⏚ᓄᔠᱥᙠZcᡈὅᰚ¨©᝱«¬ᵯᵯ73ᦑC⌱oD.®ᓄY⏚¯°ᡂWᓄhZஹXC¡ឋᓄᱥᦑDC⌱Uᦑ⌱UC»A.²³ᱥ´d-ᱥ7oB.ᵯḄ▢jµ᪷jḄᓄᔠᱥ`¡oC.ᙠZcᡈὅᰚ¨©᝱«¬ᵯḄᓄᔠᱥ`ᵯ7oD.Y⏚¯°´ᡂ¡Ḅᓄᱥ`¡ឋᓄᱥ஺-⚪ὃ0¶ᱥ7Ḅᑖ·¸៉²³ᱥஹ¡ஹ¡ឋᓄᱥஹᵯ7ᭆ»ᓽ;+⚪ABCᜧ஺15.ூ+ᫀ௃C¾ூ᪆௃U4᪷9¿ᑖ᪆;KB`஺2,¯°ঝ`2Na+OzÂNaz஺2Ãᓫ7NaÅÆÇÈᯚÊ⁐ᦑAyzUB.¯°ঞ`2NaOH+CuS0=Cu(OW)I+NaSO,¯°ট`CIZ(OH)2+2HCI=4224CuCl+2H0,Я°ᙳ`ÐᓄᔠᱥGÒÓᣚᡂᑖḄ¯°Õᑖ¯°ᦑB22yzo

11C.ᵫ¿ᑖ᪆/0জ22NCI2O2+2H2O=4NaOH+஺234ᦑc┯noD.¯°ঞ`2NaOH+CuS0=Cu(OH)I+7£125஺4᪷9ÙᑖÚᑣÜᑮjÞßà42`Ci?++2஺//-=QZ(0//)21,ᦑDyzUᦑ⌱UCo᪷9çᓄᐵèXBYÃᓫ7¯°ᡂéÊ⁐X,;ëKX`Na?஺?ᑣX¾B`஺2Ãᓫ7`Na,ì(¯°ঝ`2Na+C)2Â%&2஺2î⁐AY7஺2஺2¯°;Üᑮ஺2hYðYYCuS/¯°ᡂq⁐òó,;ëKî⁐A`ô஺Y`NaOHᑣ¯°জ`22஺2஺2+2ö஺=4Na0H+02T,¯°ঞ`2NaOH+CuSO=CU(0H)2I+NaSO,¯°ট`Ciz(O஻)2+2HCI=CuCl+2HO,9(ᑖ᪆42422+஺-⚪ὃ0îúᱥḄëû”ᱥ7Ḅý⁐ஹ©᝱1çᓄcᱯÿ
“ẚᐗᓄᔠᱥ⚪Ạᙠὃ!ẠḄ#$஺16.ூ+ᫀ௃Bூ/᪆௃ூᑖ᪆௃2⚪ὃᱥ3Ḅ4Ḅ56⚪789ᜧ2⚪;<=34>ឤ@AḄB8/+C⚪᪷E34>ឤF56EḄ34HᔠM=256᥅M34஺71ூ/+௃ᓄ
⍳O34>ឤ@Aᑣ
ᨵm(A)+m(B)=m(C)+m(D)+m(E),ᑣ?n(E)=20g+14g—8.8g—3.6g=21.6g,`E)=.=l08g/m஺ᦑ⌱B«17.ூ+ᫀ௃-1-3+1+4ூ/᪆௃/jklm+1nopᐗḄᓄᔠnx,᪷EᙠᓄᔠᱥkrsᓄᔠntᦪvmwFx2xl+2x=0,/xx=—1nyR%k|m+1no}ᐗḄᓄᔠnx᪷EᙠᓄᔠᱥkrsᓄᔠntᦪvmwFx+1x3+x=0,/xx=-3nyCa(C10)k┛ᐗ+2npᐗ-2noᐗḄᓄᔠnx,᪷Eᙠᓄᔠᱥk2rsᓄᔠntᦪvmwjFx+2+(x-2)x2=0,/xx=+lnjHSOk|ᐗ+1npᐗ-2noᐗḄᓄᔠnX,᪷Eᙠᓄᔠᱥkrsᓄᔠntᦪvm1Fx+l+x+(-2)x3=-l,/xx=+4,ᦑ+ᫀmj—1y—3y+1y+4஺᪷Eᓫ3kᐗḄᓄᔠnm0ஹᙠᓄᔠᱥkrsᓄᔠntᦪvmwHᔠᔜᓄ/+2⚪.12⚓ᐳ16⚓

122⚪789ᜧᑭᵨᓄᔠnḄᑣ56ᢣ@ᐗḄᓄᔠnḄᓽFr/+.18.ூ+ᫀ௃ঞঠটঢডণ2Na+2HO=2NaOH+WT2H++S0^~+Ba2++2220H~=BaS0+2HO42ூ/᪆௃/j(1)জC2ᓫ3£9ᵯ/3¥9¦ᵯ/3jঝlᓫ3£9ᵯ/3¥9¦ᵯ/3yঞ¨஺ᓄᔠᱥmᵯ/3yটCO2ᓄᔠᱥm¦ᵯ/3yঠ“25஺4ᓄᔠᱥmᵯ/3yডFe(0H)3¬®ᨵ¯°ᱥ3±²³ᔠᱥ£9ᵯ/3¥9¦ᵯ/3yঢG2H22஺11(ⅅ¶)mᓄᔠᱥ¦ᵯ/3jণNaCl¸¹®¯°ᱥ3±²³ᔠᱥ£9ᵯ/3¥9¦ᵯ/3yᦑ+ᫀmjᑖº᪗¼ᵯ/3¦ᵯ/3³ᔠᱥ±²CºḄᱥ3ঞঠটঢডণ(2)l½¾
ᡂ|pᓄlv|ÀᓄÁmj2Na+2H2஺=2NaOH+HT,2ᦑ+ᫀmj2Na+2H2஺=2NaO//+“2Ty(3)⏚½|pᓄÃ
ᡂ⏚Ãv¾ÄÅÁmj2"++5஺k+8஺2++20H~=BaS0+2H0,42ᦑ+ᫀmj2H++SOl-+Ba2++20H-=BaS0+2HO.42(1)ᵯ/3jᙠ¾¸¹kᡈᰚÊË᝱ÍÎÏᵯḄᓄᔠᱥy¦ᵯ/3jᙠ¾¸¹kvᰚÊË᝱Í9ÎÏᵯḄᓄᔠᱥyᵫ¯°ᡈὅ¯°ÒÓᱥ3ÔᡂḄm³ᔠᱥy(2)l½¾
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13(2)3ᡝeO+IOWJVO3=3Fe(WO)3+NOT+5/஺
ḄÄÅÁmj3FeO4-NO1+310H+=3Fe3++NOT+5HO,2ᦑ+ᫀmj3FeO+NO3+10H+=3Fe3++NOT+5HO-,2(3)⏚νù⏚|᪷
ᡂépᓄù
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