2023届高考化学一轮专题复习：化学反应原理综合专题训练

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2023
ὃᓄ⚪ᓄᳮᔠ⚪1.AஹBஹCஹDஹEஹFᦪᜧḄᐗᐗᕜ⊤Ḅᕜ஺Bᐗ!ᨵ3$%&'($%&ᡠ!Ḅᵯᦪ+,:DḄ᪶᜜ᨵ8123᝱5,Ḅᵯ;Eᐗ7Fᐗᜐ,9ᕜ+:Ḅ;<=Ḅᦪ+>3,'EᐗḄ@᝱3dB⍝Dᨵ4$FᡂHᵯ஺IJKLᑡN⚪P(1)ᑏTD@᝱ḄUᵯ᣸WX_________,F@᝱Ḅ᜜Zᵯ᣸W[o(2)Lᑡ^_5`aḄb(cd)஺A.efᓄấḄ+Hᑖjklefᓄmᜧᡠnop:SiO2>CO2B.u9ᵯv%ᵫxᑮᜧḄz:BC.N?7CO}ᵯ~᪀+D.ឋ:H2OH2S,ᑖḄbᑖᙠ(3)Fᐗᕜ⊤_____ᐸvb~ᑁ⏘Ḅ⏘bẆḄp஺ᔣFḄ⏚¡¢£ᐭ¥kḄC7A¦ᡂḄ§~X©ªᡂ«F(X)4p+,®vḄ᪀[(ᵨᐗ°d⊤±)஺(4)²ᓄᔠᱥ7Fপ(I⊤±ᓄᔠU+1)ᔠ¦ᡂX1ᡠ±Ḅv®vmḄᩖᓄ¸[.(5)BᓫjḄ9,»¦~Ḅᨔ½᝞X2ᡠ±ᑣ9$ᨔ½ᡠ!BḄ$ᦪ஺(6)ÁÂᑖḄÃ~᪀ÄÅḄᵯÆឋஹÇDḄÈᵯH}ÉÊËÌ7DḄÍᓫᓄᱥ᪀ᓝᑖ+ḄOFḄ᩽ឋÐxḄbo212(7)D7F¦ᡂv$ᦪl1:1Ḅᓄᔠᱥᨔ½7NaClÔÕDvḄÖ×apm஺FvḄÖ×bpm,ᑣ®ᨔ½ḄÚᑭᵨ᳛»2.9¸᪀ḄÞßᓄᔠᱥḄᨔ½᝞Xᵬᡠ±஺ᨔ½SmÅAsḄᢗãä᝞Xåᡠ±஺XæÅO"ᐳ,ᓰêᨔ½ḄDLë☢äíîὅḄlðᵨxÅ1-xó⊤ᑣ®ᓄᔠᱥḄᓄô[⊤±

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ᑮᔠᱥ2-ᵬ-8-ᘙᴉᑖḄᩖᓄ!⍝#NCH3OH$஺(5))$*+,-./0ᓄᓫᨔ3ᐸ56᧊89:ᨵ“-./8=”?@஺AᓄBCᵫGa(CH)IAsᙠMNᩩ
ᑴᜓᑮQRᑮSMᱥTUᱥTᑖC(V“᩽ឋᑖ’'ᡈ"]᩽ឋᑖ")As%ᑖḄ_`ab$«(6)efgQᕜiMn?+nᓄHq2ᑖpq2HO,(1)=2H,O(1)+O,(g)AH,,ᐸxᳮ᝞{q2|ᔁ*4⚓ᐳ11⚓

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Ḅ(᪗)஺53A.CECNMnᵯḄCB.MnḄᦪ#6C.CH3CN'CḄᩖᓄ*+#sp2ஹsp3D.CH3CN'12ᐔ2ᦪ456#582ঝ:;r(Co2+)=65pm,r(Mn2+)=67pm,CDMnCO6CoCOḄᑖGHI(“K”ᡈ"O”),GPQ஺33(4)S600UVḄWXᑡZ◤ᵨᑮ^_ᩞᧇ஺^_ᩞᧇTiNᐹᨵNaCl+h᪀(᝞k)ᨔmnᦪ(ᨔmop)#aD(lD=101(,m),ᐸ'▢t(NDuᵨ☢wxyᨬ{ᚮ}y~ᑣr(Ti3+)#D,ᓄḄ{Ig-cmqᑡ~ᓽ)஺

58.╅ஹᵨᑴ⌼ᔠஹ{ᘤ26Mg26Al⊦ḄᱥᵨᙢḄẆ¢஺£¤¥ᑡ¦⚪83P(1)¨©ª᝱╅ᨬK¬Ḅᵯ᣸¯k⊤±#²³´I,ᑣµ¶·Ḅᵯ᣸¯¸¹ஹ;ª᝱᪶᜜ᵯᡠᜐᨬK¬¿⍝ḄÁÂ#஺(2)EDTAÃÄ'ḄCa2+ஹMg?+hᔠÅCa?+ஹMg?+ÆIÇOÈÉhᡂ┡᮱ÄÍMg?EDTAḄh᪀Î~#/OOCCH,ஹ/CH,COOஹMgMg'OOCCHzNCH2CH2NஹCH2coO,জMgzEDTA'ÐᡂᐗÒḄᵯÓឋᵫᜧᑮ×ḄØÙ#(ᵨᐗÒÚ⊤±)஺ঝMgzEDTAᑖᑁḄ'sp3ᩖᓄḄ(ᵨᐗÒÚ⊤±)஺(3)╅ÜᙳÞßᐗÒàᓄáᙠ1000CãᐰtG#BeCbᓫæBeCbᓫæḄçè᪀+#஺(4)ᙠᰚêᩩì¥Ḅíᓄᱥ_ᵯàᓄᱥî_ᵯᑣḄíᓄᱥ#ᨔæïðñᩩì¥Ḅàᓄᱥ#³òæ³òæ'ᡠóḄᓄô2#(᪗)஺A.t2B.᩽ឋ2C.ö᩽ឋ2D.2(5)ᵫMgஹAlஹ0᪀ᡂḄ÷ø◌úxyᨔmh᪀ûü᝞kᡠ±8জ÷ø◌úḄᓄô~#ঝ:;ýþᨬÿḄMg
Ḅanm,NAᦪḄᑣ◌ᨔḄᔁ6⚓ᐳ11⚓

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᪶᜜ᵯᨵu÷øù᝱஺11.úûᐗÑNஹFஹSiஹAsஹSeஹClḄᓄᔠᱥᜧᑡ⚪(l)Si3N4◌$%&'(ᨬ*+Ḅᱥ,-.ᐹᨵ123ஹ453ஹὊ17ឋ,ᐸ:;ᨔ>?SiCLASiBCḄᩖᓄEFG஺(2)0ஹFஹC1ᵯNឋᵫᜧᑮQḄRSG?OFzᑖWḄXY᪀FG:OF?Ḅᰚஹ^_4;CbOab%o(3)Seᐗfg᝱aWḄaW᪶᜜ᵯW᣸lmG?AsḄp.ᵯqrsSeḄp.ᵯqrᜧḄabG஺(4)XeF2ᨔ>:uvᨔwᨔxyᦪ᝞|ᡠ~ᨔxᜳᙳG90஺ᨔxAᨵXeF2ᑖW஺ᨔxyᦪGᓫ3Ḅᙶ᪗w⊤~ᨔxAᔜaWḄ,GaWḄᑖᦪᙶ᪗᝞A_aWḄᑖᦪᙶ᪗G(g,Xe-FGrpm,ᑣB_aWḄᑖᦪᙶ᪗G?ᨔxAAஹBYqd=pm஺12.᪷¤aW¥᪀ஹᐗfᕜ§⊤¨ᐗfᕜ§©Ḅªᑡ⚪(1)Aᐗf«᜜¬ᵯWᦪ%ᨬ᜜¬ᵯWᦪḄ!ᐸ᜜®ᵯWḄ¯⍝⊤~m%஺(2)B%1~36³ᐗfaW᪶᜜ᵯW᣸lA´ᡂᵯWᦪᨬ¶ḄᐗfBᐗfḄ·%,ᙠᐗfᕜ§⊤AḄ%஺(3)Cᐗfg᝱aWḄ¯⍝⊤~m%|AḄ(¹S³)º.¯⍝⊤~m»r¼Gg᝱aWḄ¯⍝⊤~m%bG½»¾ᔠ(¹S³)஺¿ᔁp8⚓ᐳ11⚓

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஺ঞ╎ᵯZn,+ᔾᦈᵯḄNHஹᡂznNH,!"#$%&ᨵ)஺*஺᧕┯4ট.#ZnSᨔ1Ḅᨔ12ᦪ4azpm,89:;<=ᦪḄ>4NA,ᑣᨔ@ḄAB4g<0^ᑡHIJK஺

11

122ὃMᫀ:2sZp11.3d1°4slABDdsZߟNILsp2>sp38OF2aH2OḄb@c᪀a------NHie"f4Vh"ijkᵯlឋno"pqrḄᵯlឋsᜧupqvḄᵯlឋs"0F2pw%nᨵxyzᵯ%y"{|}F-0*ᐳᵨᵯ%yᔣFḄ᩽ឋ2)ூ᪆௃⚪ᑖ᪆AஹBஹCஹDஹEஹF4w%ᦪᜧḄᐗ"uᐗᕜ⊤Ḅᕜ஺Bᐗw%&ᨵ3)"¡¢)ᡠ&Ḅᵯ%ᦪ¤f"ᑣB4¥ᐗ¦DḄw%᪶᜜ᨵ8©ª«᝱fḄᵯ%"ᑣD4pᐗஹC4®ᐗ¦EᐗqFᐗᜐuf°ᕜ¤±Ḅ²"³´Ḅw%ᦪ¤s3,¡EᐗḄµ᝱w%3d¶⍝nᨵ4)¸ᡂyᵯ%"ᑣE426º»ᐗஹF429º½ᐗ஺2s2P(1)Dµ᝱w%Ḅ¿ᵯ%᣸ÁÂÃ8Fµ᝱w%Ḅ᜜Äᵯ%᣸ÁK43dm4sL(2)A.Æpᓄấhᡂw%ᨔ@"Æpᓄ¥hᡂᑖ%ᨔ@"ᡠÃÉÊ:SiO2>CO2,AÌͦB.Î4Nw%Ḅ2P¶⍝ᜐuÐᐙÒ«᝱"ᡠÃÓ°ᵯ$ᵫZᑮᜧḄÖ4CH2S,àᑖ%ḄÞßឋqàᑖ%áâᙠr*äᐵ"DÌÍ஺ænᡠç"èéÌÍḄjABD஺(3)Î4Fµ᝱w%Ḅ᜜Äᵯ%᣸ÁK43di°4slᡠÃFᐗuᕜ⊤dsê஺ᔣFḄë⏚íîïðᐭòórNHஹIḄö÷"ᡂCU(NH3)4"#$%Ḅc᪀K4ù'-«(4)ᵫÂü"#$%¥w%ᨵx"°¥w%ýeþÿḄᐸᐰᡂᓫᦑḄᩖᓄsp2ஹsp3o(5)ᵫBᓫ$Ḅ%&'(Ḅᨔ*+᪀-./012ᨔ*345Ḅᨔ*6ᨔ*7ᡠ9Ḅ6ᦪ8(8x-+6x—+4x1=8)086(6)H2O+᪀ᓝᑖJKḄ0F2Ḅ᩽ឋOPḄQR0F2SHzOḄU(+᪀JK%VWXᵯZឋ[\]ḄᵯZឋ^ᜧ`\aḄᵯZឋ^OF?7\ᨵdefᵯeghiF-07ᐳᵨᵯelᔣFnopḄ᩽ឋ஺(7)DFᡂt6ᦪu1:1ḄᓄᔠᱥCuO,ᨔ*NaClKDtḄapm஺FtḄbpm,ᑣ2ᨔ*Ḅ(2a+2b)pm,ᨔ*Ḅ((2a+2b"pm?2ᨔ*7ᨵ46Cu?+S460ு46CiP+S46஺2-Ḅᫀ1⚓ᐳ13⚓

13/,,(4○4/34r47rb.I14xI--------pmc/3»3\(4x_+ᑶp/n)ᡠᨔ*Ḅᑭᵨ᳛I33J(2a+2b)3p,"33(a+/j)'¡¢R£⚪ᨵᐵᱥ$Ḅ+᪀Sឋ$Ḅ¦ᔠ⚪§¨©ᜧ஺ª⌕ὃi᪶᜜ᵯ᣸±Ḅ²³´ஹ᪶᜜ᵯ᣸±Ḅ⊤-¶ஹᐗ&ᕜ¹⊤Ḅᑖº¶ஹ»ᔠᱥ+᪀Ḅ⊤-¶ஹᩖᓄ¼⍝¾ḄᑨÀஹᑖ᩽ឋᜧPḄᑨÀ¶ஹᨵᐵᨔ*ḄÁÂ஺⌕ÃÄp⌕ÅÆ1~36ᐗ&Ḅ᪶᜜ᵯḄ᣸±ÇÈÉ᪷Ë᪶᜜ᵯḄ᣸±ᱯ¡ÍÀᐸᡠÎᐗ&1⍝ᐗ&ᕜ¹⊤ᑖºḄÏËÉ᪷Ëᱥ$Ḅ+᪀ᱯ¡ᑨÀÐÑḄᩖᓄÉ᪷Ëᐗ&ḄᵯZឋÒ+᪀ஹᑖ+᪀ᱯ¡ᑨÀᑖḄ᩽ឋᜧPÅÆÓÔᨔ*ḄᱯÕÉᵨᙳ׶ᑨÀᨔ*7+᪀ØḄᦪÙÚÁÂᨔ*7ᡈtḄᑭᵨ᳛஺2[281+16(l-x)+19x]2.SmFeAsOlxI\ÜI0)(0,0,a2cNxlOMAூÞ᪆௃ᵫᨔ*+᪀7ᔜᡠᙠãä012ᨔ*7SmḄ6ᦪ4*å=2,FeḄ6ᦪl+4x^=2,AsḄ6ᦪ244XR=2,2ᨔ*7OSFḄ6ᦪæS8XR+2XR=2,F■ḄuèX,O?-Ḅuè1-X,ᦑ2ᓄᔠᱥḄᓄÄ282SmFeAsO/x16ᨔ*Ḅ$é205஺+56+75+3-x+Wg=2[28.6ê+"ê,Pᨔ*Ḅ(5NA/PmZdmᦑë¨᮱4ᵪ2ã`î☢☢ðᐸᙶ᪗êóó03ã`ôᐸᙶ᪗
0,0,3õ஺3.(1)OMgGeO24740(2)abcNxlO21AூÞ᪆௃ê1õ᪷Ë᝞/ᡠ-ᨔ*᪷Ëᙳ׶Zᳫã`ᨔ*ᑁã`ᨔ*Ḅᑁ9ᨵ4+4+4+4=166Yᳫᨵ46ã`ᨔ*ᑁXᳫã`⚔¡Ḅᨵ86ã`4ᩩôðḄᨵ46û☢ðᔜᨵ26ᨔ*ᑁᨵ56ᑣᨔ*7ᐳ9ᨵḄX8XR+4X+6X+3x1=86ü1ᓄᔠᱥ7GeS஺Ḅ6ᦪu1R4,ᑣ1R4uèḄXRZ,ᡠ/7Z⊤-OY⊤-GeX⊤-Mgᑣ2ᓄᔠᱥḄᓄÄMgzGeCU,ᦑᫀROMgGeO42(2)4x73g/mol+8x24g/mol+16x16g/mol740ᨔ*Ḅ$éý=:"gᨔ*Ḅ(V=abcnm3=abcxlO_21cm3,Nmor1Aᫀ2⚓ᐳ13⚓

14m740740i7403þᐭ᪷
ᨔḄ/=±w஻c஺=ᦑᫀ^"7rxio2iVNahcxlOahcNabcN0AAA4s4p4.(1)p%IIi□17ফsp?(3)43+,-.-/ᰚᓄ◤⌕ẚ5ᐳ789ᱥ;Ḅ<+,-8=>.ᶍ@A-/ᡠCᰚDᶍ@A-/;C60HᑖJᨔᰚᓄKL◤MNᑖJOPᵨRᡠCᰚDS@A63ூU᪆௃(1)XYᐗ[Ḅ7\ᵯJ᣸_`ns2np2,ᦑcAᕜe⊤Ḅpgh32iᐗ[ᐸ᜜lᵯJ᣸_`4s24P2,ᐸn4s4p⍝⊤p`q|||Ist᝱vwJḄᵯJ᣸_`Is22s22P63s23P63dHl4s24P2,ᐸ{O|}~᝱Ḅ44ᵯJᨵ1+1+3+1+3+5+1+2=17s(2)HQPB.HQPN᪀Xᙳ☢᪀ᑣᐸNḄᩖᓄ`Hsp2s(3)জ12g+,-Ḅᱥ;Ḅ<Imol,XwJᡂqᐳ78XwJᡂᐳ78ᡠC12g+,-ᨵC-C8Ḅᦪ2Ms-/ᨔXwJᡂᐗ1CwJ¡¢3x3=1•C-C812g-/Ḅᱥ;Ḅ<Imol,ᑣ12g-/ᨵC-C8Ḅᦪ1.5▬,ᡠC12g+,-ᨔ.12g-/ᨔᨵḄC-C8ᦪ¤¥43sঝ+,-HwJᨔᰚᓄK◤⌕ẚ5ᐳ78-/ᰚᓄK§◤⌕ẚ5ᐳ78¨8©ªCᑨ¬-/ᐳ78Ḅ8=ᜧA+,-ᐳ78Ḅ8=®¯+,-ḄᰚD@A-/s°C“)ᡂḄHᑖJᨔᰚᓄKMNᑖJOPᵨR°ᐳ78Ḅ²³ᜧAᑖJOPᵨR®¯+,-ḄᰚD³´AC60,ᫀ+,-.-/ᰚᓄ◤⌕ẚ5ᐳ789ᱥ;Ḅ<+,-8=>.ᶍ@A-/ᡠCᰚDᶍ@A-/sC60HᑖJᨔᰚᓄKL◤MNᑖJOPᵨRᡠCᰚDS@sঞA.C02ᑖJᨔᑖJᚮ·A¸¹sB.ºH»ᑖJ¼½¾8ᡂḄᑖJᨔHᑖJᚮ·B┯ÀsC.Á+ÂᨔC┯ÀsD.Ä+ÂᨔD┯ÀsE.ÆᓄÇÈJᨔE┯ÀsᫀÉ3⚓ᐳ13⚓

15ᦑ⌱As(4)জᵫͪÎSiᨵ8cA⚔DᑣᨔÒᨵ1SisLiᨵ4cAÔÕ4cAᑁᐳᨵ5ᦑᐸᓄ×`:LiSis5__7x5+2863ঝÚᨔḄÛ=3/10*3=aVNxlO-஺A2s2p5.°|TIsÞ~|àá(ᡈã┴)sp3C

16(7)8ூ᪆௃(1)4s4PGaḄ3ᵯ᣸·¸4s24plᵫ¹ᑭᳮஹ¼ᱯ¾ᑣ%3ᵯ᣸·(2):⍝*ᵯᜐLNஹᐰNஹᐰÁÂ\OP%ÃOP%ᐸSTᵯUÃᜧÄZnÆᐰᐙN%X-GaÇOP,ᦑSTᵯUÇᜧ%ᦑ²ᫀ¸É;(3)জ᪷⊤Í*ᰚΤÏÐ%ᕈÒ᝱ḄÆGaCb;GaC13ஹGaBnGabᙳ¡ᑖᨔy%X-ᑖÔÕGHIᜧ%ᑖÖ×ᵨØIÙ%ᰚΤGHᓣ%ᦑ²ᫀ¸GaChÄঝGaF3¡Uᨔy%GaCbᑖᨔy%Uᨔyᰚ¤ᑖᨔy%ᦑ²ᫀ¸GaF3¡Uᨔy%GaCbᑖᨔy%Uᨔyᰚ¤ᑖᨔyÄ(4)2-ᵬ-8-ÜÝÞᑖ*ßàáḄᩖᓄ:⍝<=sp?ᩖᓄ%ᵬ*áḄᩖᓄ:⍝<=sp3ᩖᓄ%ᦑ²ᫀ¸Sp2ஹSp3;(5)Ga(CH3)3AsH3ᙠTPᩩåæᑴᜓéᑮGaAs,᪷êឤìíTaîᱥCH4,C%¦᩽ឋᑖÄAsH3ᑖ*Asñòsp3ᩖᓄ%ᑖÁÖQ᪀`©┵%ᦑ²ᫀ¸¦᩽ឋᑖÄ`©┵Ä(6)óᓄᐵõ%ö÷ᓄøùUúûéᑮü÷ᓄýøU¸2HO(1)=2H,O(I)+O,(g)AH1জ22MnO,(s)+HO(1)+2H+(aq)=Mn2+(aq)+0(g)+2H,O(1)AHঝ2222Gþÿ
জ-ঝᑮHO2(l)+Mn2+(aq)=MnO(s)+2H+(aq)AH=AHI-AH,ᦑᫀHO2(l)+Mn2+(aq)=2222MnO2(s)+2H+(aq)AH=AHI-AH2(7)ᵫ☢!ḄCa2+$%&'ᨬ)*+&ḄF-ᦪ8-0ᦑᫀ8o7.(1)45ᱯ7ᑣ(2)

17বBDFGHM/+,JKLMḄC02+OP⏚᪷'STḄU'SVᵨXLY0Lᑭ[P⏚᪷ᑖ]C022.04x(48+14)(4)~~4~aN(axlO8)3Aூ]᪆௃পSid14eᐗg0ᐸijᵯS᣸mn3s23P2,o᝱SiqSijᵯSᨵ4-0ᑣstu᝱ᨵ4v“5ᱯ7ᑣxyz{|x|}•5ᱯ᪷ᜧᐝᦪ-7
0ᓽᵯSᑖmᑮḄqS⍝0ᐜGḄnᑖᓰḄ⍝0ᵯS᣸mn⊤e]3s2p£¤¥5ᱯ7ᑣ(2)SiHCb§SiCLᙳᑖSᨔ«0SiHCbḄG¬ᑖSM[SiCL,SiHCbḄx¯XM[SiCLḄx¯X0ᑣ°±SiHCl3VsicᾙqSᦪ§iᵯSᦪᙳG+ḄᑖSᡈ'Sµ+ᵯS«0ᦑOSiC14µ+ᵯS«Ḅ'SᨵSOᡈP0+¶%ᵯ·ឋH>Si,ᑣHᔾ»ᵯSḄXLY0SiHCbTH¼-1i0Si¼+4i0SiHCb½]◀¿ᡂấ⏚§HC1᜜-1iḄH§½ÃÄḄ+1iḄÅÆ¿ᡂÅÇ0ᦑᐸ½]ḄᓄÉÊnSiHCl+3HO=HSiO+3HCl+H32232(3)জA.CH3CNTNᨵËᵯS¬0CÌᨵËᵯS¬0CH3CNOMnqSÍÎ0ÃÄËᵯS¬ḄdNqS0A┯ÐB.Í«5-CO§1-CH3CN,ᦑMnqSḄÍÎᦪ6,BÒÓC.CH3CNTᵬoCsp?ᩖᓄ0-CNTḄCspᩖᓄ0C┯ÐD.CH3CNᓽCH3c×N,ᓫÙᐰd஺Ù0×ÙÜ-஺Ù0Ý-ᐔÙ0ᦑCH3CNT6ÙOnÙᦪßàH5:2,DÒÓᫀ⌱BDঝGHMn2+,JKLMḄCo?+OP⏚᪷'STḄU'SVᵨXLY0Lᑭ[P⏚᪷ᑖ]C02,ᑣMnCChHCoCO3Ḅᑖ]äåF(4)¶%▢'S(Nஹ)èᵨ☢!éᨬêᚮì0ᑣᐸ☢¬íîï2-N3-'SḄðK0ᨔñòᦪaD,ᑣ-N3-ḄJKïXZaD,0TV+ḄJK!(a-2x"a)D=*aD42441114x(48+14)ᵫᨔñ$%1-ᨔñTN3-Ḅ-ᦪ=8xg+6xa=4,Ti3+Ḅ-ᦪ=12x1+1=4,ᑣ-ᨔñḄ=--——êå4x(48+14)4x(48+14)---------------gû=NA(axlOü)3gem஺(ax10-8cm)3ᫀ?6⚓0ᐳ13⚓

188.(1)ᨬþqᳮᱯᑣ(ᡈ┴)(2)0>N>C>H>MgCஹNஹ0(3)(4)BDমMgAhO44N^X°21ூ᪆௃প᪷᪀⌼ᳮ12MgᐗḄ!᝱᪶᜜ᵯ᣸'()Is22s22P63s2,ᐸᨬ,-.ᵯ᣸'(/3s2,013P!᝱╅ᨬ,-.Ḅᵯ᣸'3⊤5/678ᑣ9:;Ḅᵯ᣸'<)-=ᨬ>ᳮஹᱯᑣ?13A1ᐗḄ!᝱᪶᜜ᵯ᣸'()Is22s22P63s23p*!᝱@᪶᜜ᵯᡠᜐᨬ,-./3pஹC⍝ḄE/(ᡈ┴)஺(2)জHᕜJKLᐗMNᔣPᵯQឋ⌲TUVHKLᐗMWᑮYᵯQឋ⌲TZ[,MgaEDTA]^ᡂᐗ/0ஹNஹCஹHஹMg,ᑣᵯQឋᵫᜧᑮbḄcd/O>N>C>H>Mg஺/OOCCH,ஹ/CH,COOஹMg(coccH)NCHCHNஹcQMg22ঝᵫMgzEDTAḄf᪀g(/°࠷஺jCH2coOMgzEDTAᑖᑁḄ⛳noᡂ4p஺qஹrssp3ᩖᓄNᨵ1wxᵯwஹᡂ3poqN/sp3ᩖᓄᓫq0ᨵ2wxᵯwஹᡂ2pGq/sp3ᩖᓄᑣzᑖ]rssp3ᩖᓄḄ)CஹNஹ0஺(3)2—1x2BeCLᓫ{]]|xᵯwᦪ=y=0ஹᵯwᦪ=2+0=2,ᑣᐸ᪀/஺(4)ᙠᰚᩩY@Ḅᓄᱥᵯᑣ@Ḅᓄᱥ/ᨔ{?ᓄᱥᵯᑣᓄᱥ/ᐳᓄᔠᱥA1CLᑖ]|xᵯwᦪ==0ஹᵯwᦪ=3+0=3,ᑣᩩY@Ḅᓄᱥ{]A1ᐹᨵC⍝ஹWᐹᨵxᵯwᡂqᦑ{]ᡠḄᓄq/᩽ឋqnq⌱BD஺(5)জ᪷ᙳ¡8pMgs⚔£ஹ6pMgs☢|ஹ4psᨔ¥ᑁᑣMgpᦪ=8x+6x4+4=8pA1sᨔ¥ᑁ¦pᦪ/16,0sᨔ¥ᑁ¦pᦪ/24,z§¨◌ªḄᓄ(/MgALCU஺ঝ«¬pᨬḄMg®Ḅ¯/anm,ᵫ5°3anmᓽᨔ¥{w²Ḅ³ᑖ®ᑣᨔ¥´µ)¶nm=·¸nm,¹NA/º»¼½¾¿ᦪḄÀᑣz§¨◌ªÁÂᨔ¥ḄÃÄ/ஹ3,ÅÆ2g-cm-^V33(Ma)xlOXNAÇᫀÉ7⚓ᐳ13⚓

19ᑶ4x10213஺4NaA9.(1)ABDCফ5n?(3)(H,O+)O-H---N(N?)(NH?)N-H…N(N)ভÐÑᡈÒxIO8ÓMMூÕ᪆௃Ñ1HQ]஺qᦪ/3,]|xᵯwᦪ/gxÑ6-l-3xl=l,Øᵯwᦪ/4,ᩖᓄC⍝Ù/sp3,Á{f᪀/²┵?NH]bqᦪ/4,]|xᵯwᦪ/:xÑ5-l-4xl=0,Øᵯwᦪ/4,ᩖᓄC⍝Ù/sp3,Á{f᪀/ݳ☢{?HQ*nNH]ᙳ᩽ឋᐳqnqᦑ¬Þ□ḄàH®ᜐ/AஹBஹD,H®ᜐ/C஺
2ᵫ3]N?Ḅf᪀N]Ḅ஺qᦪ/5?N?]Ḅ5páâᡂᜧᐔqäp]áâᡂᜧᐔqḄᵯᦪ/1
xᵯwáâÓᦑáâᡂᜧᐔqḄᵯᦪ/5+1=6,N?]ᜧᐔqå⊤5/n?஺
3æHâNஹ0ஹFàçèéâàêᑖḄNஹ0ஹFàçᡠéëéᡂḄìqᨵÑHQ+O-H…N
N1n(NH)N-H…N(N)?(4)ᨔ{ḄÃÄ/dg

20(6)N>P>S(7)sp\sp26ூÕ᪆௃প஺0]ᵯwᦪ)4,óᨵxᵯwf᪀/ݳ☢{஺AlBrஹ)AB,ᑖᵯwᦪ)3,óᨵx4ᵯwf᪀)ñ☢²஺(2)AB,ᑖ]]|ôxᵯwḄᕈñ☢²ᨵwxᵯwḄᕈ²┵ᡠéᑖö)CH?ஹCH?.(3)ᵫÉᕜJ÷ørᐗḄ᪀ᡂḄ]ឋᑖ]ᕈ²┵Ḅ)NFj,ᕈñ☢²Ḅ)BFஹᕈݳ☢{Ḅ)CR஺(4)Cu)29ᐗ!᝱CuḄᵯ᣸'(/[[Ar]3d'04slᡈIs22s22P63s23P63d"'4s'஺(5)PO]|PḄᵯwᦪ/ù-4,ôxᵯwᑣ/sp'ᩖᓄPOḄf᪀)ݳ☢{஺(6)HKLMWᑮYᐗḄÉᵯ-⌲TZbú/P᪶᜜3P⍝ᜐsûüf᪀ý/þᡠéPḄÉᵯ-ᜧsS,ᐗÉᵯ-ᵫᜧᑮbḄcd/N>P>S஺(7)⚪ᑖᡂᓫḄspᩖᓄᡂḄsp?ᩖᓄḄ6ᵯḄ᝱ᐳᨵ6᝱஺11.(1)sp3(2)F>O>C1V0F2#CLO$%᪀'Ḅᑖᨔ)CLOḄ*ᑖ+ᜧ-0F2ᑖ./ᵨ1ᜧ-OF2(3)[Ar]3d4s24P,AsḄ4P2⍝45Ḅ6ᐙ8%᪀ᐗ:Ḅ;ᵯ<=ᜧ->ᐗ:(4)2(0,0,-)J—+(--r)2cV22ூ@᪆௃(1)Eᫀ;9⚓ᐳ13⚓

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