Functional Ionic Liquid Crystals - Figures - Unknown - Unknown

《Functional Ionic Liquid Crystals - Figures - Unknown - Unknown》由会员上传分享，免费在线阅读，更多相关内容在学术论文-天天文库。

SupportingFiguresFunctionalIonicLiquidCrystalsKrishnacharySalikolimi,aAchalkumarAmmathnaduSudhakarb*andYasuhiroIshidaa*aRIKENCenterforEmergentMatterScience,2-1Hirosawa,Wako,Saitama351-0198,Japan.bDepartmentofChemistry,IndianInstituteofTechnologyGuwahati,Guwahati781039,Assam,India.E-mail:achalkumar@iitg.ac.in;y-ishida@riken.jpS1

1FigureS1.Schematicillustrationofconventionalandnon-conventionalLCs.S2

2FigureS2.(aandb)SchematicillustrationofvariousthermotropicLCphasescomposedofcalamitic(a)anddiscotic(b)molecules,wherenrepresentsamoleculardirector.(c)SchematicillustrationofvariouslyotropicLCphasescomposedofamphiphilicmolecules.S3

3FigureS3.SchematicillustrationofthepreparationofaColhorderednanoporousframeworkfromaColhILCcomposedofapolymerizableframeunit5andadendritictemplateunit6.Reprintedwithpermissionfromref.31.Copyright2015Wiley-VCH.S4

4FigureS4.SchematicillustrationofthepreparationofaColhorderednanoporousframeworkanditsapplicationtosize-selectivecationadsorption.TheprecursorColhILCwascomposedofa3:1supramolecularcomplexofagallicacidderivative8asapolymerizableframeunitand3,5-tris(1H-benzo(d)-imidazol-2-yl)benzene9asatemplateunit.Reprintedwithpermissionfromref.34.Copyright2016Wiley-VCH.S5

5FigureS5.(a)MolecularstructuresofanLCmonomer12bandacross-linker13.(b)SchematicillustrationofthepreparationofaSmorderednanoporouspolymeranditsapplicationtocationadsorption.Reprintedwithpermissionfromref.39.Copyright2014Wiley-VCH.S6

6FigureS6.(aandb)MolecularstructuresofILC-basedmolecularlyimprintedpolymers(ILCMIPs).Reproducedwithpermissionfromref45.Copyright2005NaturePublishingGroup(a).Reproducedwithpermissionfromref.46.Copyright2007Elsevier(b).S7

7FigureS7.SchematicillustrationofthepreparationofaColhorderednanoporousframeworkbycross-linkingofanILCmonomer23exhibitinganinvertedColhLLCphase.Reproducedwithpermissionfromref.54.Copyright1998AmericanChemicalSociety.S8

8FigureS8.(a)Schematicillustrationofacompositemembranepreparedfromapolymerizableammonium-basedILC27exhibitingaCubbiphase.(bandc)Nanoporousmembranewithdefects(b)andwithorderedanduniformnanopores(c).Reprintedwithpermissionfromref.64.Copyright2012Wiley-VCH.S9

9FigureS9.Schematicillustrationofthepreparationofanalignednanoporouspolymermembrane.(a)MolecularstructuresofsurfactantsHitenol29andNoigenRN-1030.(b)Inversecylindricalmicellesformedbytheself-assemblyofthepolymerizablesurfactants.(c)Domainsoftherandomlyorientedhexagonallypackedcylindricalmicellespriortomagneticalignment.(d)Magneticorienteddomainsofhexagonallypackedcylindricalmicelleswithnegativemagneticanisotropy.(e)Preparationofaverticallyalignednanoporouspolymermembrane.Reprintedwithpermissionfromref.70.Copyright2014AmericanChemicalSociety.S10

10FigureS10.SchematicillustrationofthepreparationofColhorderednanoporouspolymersfromrenewablenaturalfattyacids.(a)Molecularstructuresofcis-andtrans-octadecadienoicacids31a,baspolymerizableframeunitsand1,3,5-tris(1H-benzo(d)-imidazol-2-yl)benzene(9)asatemplateunit.(b)PreparationofthenanoporouspolymersviaLCformation,cross-linking,andtemplateremoval.Reprintedwithpermissionfromref.71.Copyright2017AmericanChemicalSociety.S11

11FigureS11.Schematicillustrationofsoftconfinement-assistedfabricationofanorderedpolymerthinfilmwithverticallyalignednanoporesfromtheself-assemblyofapolymerizablegallatederivative23.Reproducedwithpermissionfromref.72.Copyright2016AmericanChemicalSociety.S12

12FigureS12.(a)MolecularstructureofaphotochromicILC36.(b)Schematicillustrationofthetrans-cisphotoisomerizationofazobenzene(Azo)unitin36inresponsetoUVandVisiblelight.(c)SchematicillustrationofthephotoinducedreorganizationofaSmALCthinfilmof36.Insetsshowingthemolecularself-assemblyof36andthedirectionofionconducting2Dnanochannels.Thedirectionsofionconductionandlinearlypolarizedlightareshowningreenandinblackarrows,respectively.Reprintedwithpermissionfromref.87.Copyright2014AmericanChemicalSociety.S13

13FigureS13.(a)Molecularstructuresofamphiphiliczwitterions42a,banddesignedacids43–46.(b)SchematicillustrationofthepreparationofaCubbiLCwith3Dcontinuousinfiniteporousminimalsurfacebycomplexationofamphiphiliczwitterionsanddesignedacids.Reprintedwithpermissionfromref.96.Copyright2017Wiley-VCH.S14

14FigureS14.(a)Molecularstructuresof4-alkoxybenzoicacids47a,bandimidazole48.(bandc)Schematicillustrationsofprotontransferpathwaysinanetworkofundoped4-alkoxybenzoicacid(b)andinanetworkofimidazole-doped4-alkoxybenzoicacid(c).Reproducedwithpermissionfromref.98.Copyright2015Elsevier.S15

15FigureS15.(a)MolecularstructuresofanLCmonomer50,itsH-bondingcounterpart49,andacross-linker51.(b)SchematicillustrationofthepreparationofaSmorderedprotonconductingpolymerwithcationicnanoporescomposedof49–51andH3PO4.Reprintedwithpermissionfromref.101.Copyright2018RoyalSocietyofChemistry.S16

16FigureS16.(a)Schematicillustrationofthepreparationofaheterogeneouscatalystbythecross-linkingofamixtureofanILCmonomer52,divinylbenzene53,andwaterthatexhibitedaninvertedColhLLCphase.(b)ApplicationoftheheterogeneouscatalystfortheKnoevenagelreaction.Reproducedwithpermissionfromref.108.Copyright1999Wiley-VCH.S17

17FigureS17.(a)Molecularstructuresofthecationicpartsofimidazolium-basedILandILCs96–101.(b)TEMimagesofNinanoparticlessynthesizedfromNi(1,5-cyclooctadiene)2inthereactionmediaof(i)96,(ii)97,(iii)98,(iv)99,(v)100,and(vi)101.Reprintedwithpermissionfromref.138.Copyright2014RoyalSocietyofChemistry.(c)SchematicrepresentationofthegrowthandorganizationofcoordinationpolymernanoparticlesinILCs.Reproducedwithpermissionfromref139.Copyright2009AmericanChemicalSocietyS18

18FigureS18.(a)MolecularstructuresofILCs106–108composedofthesaltsofanthracene-2,6-disulfonate105withvariousammoniumsandimidazoliums.(b)Solid-statefluorescencespectraoftheILCsatroomtemperatureunder360nmexcitation.Reprintedwithpermissionfromref.149.Copyright2009Wiley-VCH.S19

19FigureS19.(a)Molecularstructuresofvarioustris(imidazole-2-yl)benzenederivatives109–112.(b)SchematicillustrationofaH-bondedsupramoleculardiscotic1:3complexesof109–112withtrialkylatedgallicacids113a–c.(c)Fluorescenceemissionspectraofthediscoticcomplexes109-113b(red),110-113b(blue),111-113b(green),and112-113b(orange).Insetshowingtheirfluorescenceemissioncolors.Reprintedwithpermissionfromref.153.Copyright2019RoyalSocietyofChemistryandChineseChemicalSociety.S20